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95 S Saratoga Cir PLRS23-0176 COAB Permit Form with ConditionsOWNER:ADDRESS:CITY:STATE:ZIP: TANNER BRIAN J 95 SARATOGA CIR S ATLANTIC BEACH FL 32233 COMPANY:ADDRESS:CITY:STATE:ZIP: ADVANCED PLUMBING TECHNOLOGY DBA: APT 16207 SESO SUITE 402 CLERMONT FL 34711 TYPE OF CONSTRUCTION: REAL ESTATE NUMBER:ZONING:BUILDING USE GROUP:SUBDIVISION: 171773 0000 ATLANTIC BEACH VILLA # 02 JOB ADDRESS:PERMIT TYPE:DESCRIPTION: VALUE OF WORK: 95 S SARATOGA CIR PLUMBING RESIDENTIAL CIPP PIPELINER RE-PIPE 6 FIXTURES $17525.00 FEES DESCRIPTION ACCOUNT QUANTITY PAID AMOUNT PLUMBING BASE FEE 455-0000-322-1000 0 $55.00 PLUMBING FIXTURES 455-0000-322-1000 0 $0.00 PLUMBING FIXTURES 455-0000-322-1000 7 $49.00 STATE DBPR SURCHARGE 455-0000-208-0700 0 $2.00 LIST OF CONDITIONS Roll off container company must be on City approved list . Container cannot be placed on City right-of-way. NOTICE: In addition to the requirements of this permit, there may be additional restrictions applicable to this property that may be found in the public records of this county, and there may be additional permits required from other governmental entities such as water management districts, state agencies, or federal agencies. WARNING TO OWNER: YOUR FAILURE TO RECORD A NOTICE OF COMMENCEMENT MAY RESULT IN YOUR PAYING TWICE FOR IMPROVEMENTS TO YOUR PROPERTY. A NOTICE OF COMMENCEMENT MUST BE RECORDED AND POSTED ON THE JOB SITE BEFORE THE FIRST INSPECTION. IF YOU INTEND TO OBTAIN FINANCING, CONSULT WITH YOUR LENDER OR AN ATTORNEY BEFORE RECORDING YOUR NOTICE OF COMMENCEMENT. MUST CALL INSPECTION PHONE LINE (904) 247-5814 BY 4 PM FOR NEXT DAY INSPECTION. ALL WORK MUST CONFORM TO THE CURRENT 6TH EDITION (2017) OF THE FLORIDA BUILDING CODE, NEC, IPMC, AND CITY OF ATLANTIC BEACH CODE OF ORDINANCES . ALL CONDITIONS OF PERMIT APPLY, PLEASE READ CAREFULLY. 1 of 2Issued Date: 10/10/2023 PERMIT NUMBER PLRS23-0176 ISSUED: 10/10/2023 EXPIRES: 4/7/2024 PLUMBING RESIDENTIAL PERMIT CITY OF ATLANTIC BEACH 800 SEMINOLE ROAD ATLANTIC BEACH, FL 32233 STATE DCA SURCHARGE 455-0000-208-0600 0 $2.00 TOTAL: $108.00 2 of 2Issued Date: 10/10/2023 PERMIT NUMBER PLRS23-0176 ISSUED: 10/10/2023 EXPIRES: 4/7/2024 PLUMBING RESIDENTIAL PERMIT CITY OF ATLANTIC BEACH 800 SEMINOLE ROAD ATLANTIC BEACH, FL 32233 PLRS23-0176 PICOTE SOLUTIONS RESIN FAMILY Dual Color 100% Solids Epoxy Fiber Bonded Epoxy Mastic Technical Data Sheets, Chemical Resistance Information, ASTM Testing Results, WRc Approval, SDS Sheets, NSF 61.5 Certification www.picotegroup.com 1 PLRS23-0176 TABLE OF CONTENTS Picote Dual Color Epoxy Coating Resin Specs...........................................3 Technical Data Sheet...........................6 NSF Certified Product Listing.............8 WRc Approval....................................10 ASTM Test Results Explained...........13 Chemical Resistance Sheet..............18 SDS Sheet - DC1000E Base..............20 SDS Sheet - DC1000E Catalyst........23 Picote Fiber Bonded Epoxy Mastic Technical Data Sheet.........................35 ASTM Test Results Explained...........37 SDS Sheet - Part B.............................42 SDS Sheet - Part A.............................47 2 Please contact your reseller or Picote at: Picote Solutions Inc., 777 W Pinnacle Peak Rd, Ste B-108 Phoenix, AZ 85027 - USA Tel: +1 864 940 0088 PICOTE DUAL COLOR COATING RESIN TECHNICAL SPECS 1.Extend the life span of the original pipe: The resin can be used to prolong the life of an existing pipe. Clean the pipe well. Apply single (0.5-1mm/coat) or dual coats of the resin. The new slick inner surface will increase the flow inside the pipe minimizing the risk of blockages. 2.Create a new semi-structural pipe: Apply several coats of the resin forming a seamless new pipe with a 2-4mm wall thickness depending on the diameter. Estimated 30-50 year design life when using Semi-Structural Design Specifications based on pipe diameter. PRODUCT FACTS This product has been created to renovate drains, sewers, water pipes, electrical conduits, heat and a/c ducts and more by brush casting a coating. The specially formulated coating resin forms a semi-structural corrosion resistant barrier inside the original pipe that is a tested, safe and environmentally friendly product. The new pipe is corrosion resistant, wear-resistant and non-corrosive. Thanks to a high breaking stretch, it also withstands shocks and bending. The new pipe becomes elastic and antistatic. USES BENEFITS FOR CONTRACTORS Extend the service life of a pipe, stop corrosion, create a new pipe, ”patch” on top of CIPP liner and fortify connections*. Apply to small areas or all drains in multi-story buildings. The Picote Coating™ System is affordable, practical and easily fits in tight places. *Ensure that materials are compatible and the surface is properly prepared. BENEFITS FOR PROPERTY OWNERS Customers can stay at home or keep business open during drain renovation. The Greener Alternative: Eliminating the need to destroy existing walls, gardens or sidewalks, the no-dig solution reduces waste produced at job sites. Interruptions to traffic are also minimized. All materials used are non-toxic. 3 PACKAGE SIZES: 6x 900ml: 2-part cartridge with 6 cartridges in each case SHELF LIFE: 2 years from packaging when kept in accordance with storage instructions included in MSDS and Technical Data Sheet. MIXING RATION: 2:1 2:1 mix ration by volume. No mixing required with prepackaged cartridges and supplied static mixing tip. BASE MATERIALS/ PIPE DIAMETER WORKING METHOD HARDNESS TENSILE STRENGTH ADHESION STRENGTH: METAL ADHESION STRENGTH: CONCRETE PORTIONING POT LIFE HARDENING LEVELING GAS EMISSIONS DRY CONTENT TEMPERATURES GLOSS THINNER COVERAGE SHRINKAGE HUMIDITY UV RESISTANCE FLEXIBILITY ELECTRICAL CONDUCTIVITY Size range 1¼’’ through 12’’ (DN32-DN300) pipes Coating with brush Adjustable Shore is 65+ (flexibility goes up when hardness goes down) 2970 PSI 803 PSI with static mixing tip 100% concrete breakage when pulled away Not applicable Mixed resin about 25 min @ 70ºF/21ºC Recoat: 3hrs @ 70ºF/21ºC Restore flow: 4hrs (24hrs for potable water projects) Final Cure: 24hrs Can be recoated within 12hrs with no prep, side grinding panels must be used after 12hrs Product is self leveling. No harmful VOCs released during mixing or after hardening (VOC free) 100% solids Installation: 50ºF/10ºC - 140ºF/60ºC Storage: Room Temp 60ºF/15.5ºC - 85ºF/29ºC Finished product: up to 180ºF/82ºC Most commercial hot water OK up to 180ºF/82ºC Semi-gloss Not used See Picote Resin Calculator 100% Solids - does not shrink Hydrophobic repels water Direct sunlight can alter color of coating 6,080 PSI Electrical insulating material, does not conduct electricity & is antistatic PICOTE DUAL COLOR COATING RESIN TECHNICAL SPECS 4 For sales information, please contact your reseller or Picote Solutions www.picotegroup.com PICOTE DUAL COLOR COATING RESIN TECHNICAL SPECS STATIC PROPERTIES TESTS DC1000E MECHANICAL TESTING CERTIFICATIONS INDUSTRIAL SAFETY SAFETY DATA SHEET 3RD PARTY APPROVALS SHIPPING TECHNICAL ENQUIRIES For further technical information, please contact: Antistatic NSF/ANSI tested for standard 61-5 ASTM Tested - please see results below: Tensile Strength ASTM D638-14 2979 psi Compression Strength ASTM D695-15 9570 psi Flexural modulus ASTM D790-15e2 430 ksi Flexural strength ASTM D790-14e2 6080 psi Adhesive strength ASTM D4541 Substrate failure Product certified to NSF/ANSI 372 conforms to the requirements for “Lead Free” plumbing products as defined by California, Vermont, Maryland and Louisiana. Standard: NSF/ANSI 61 Section 5 - 2016 Models: DC1000E Color: White Picote’s 100% Solids Epoxy Resin, DC1000E, is certified for potable water pipes DN100 (4’’) and above. The final coat must be in White. Ready-measured product must not be in contact with skin (it adheres) Delivered with resin WRc: Picote Brush Coating™ System is WRc approved for all non-potable & wastewater applications for pipe diameters between DN50-300 (2-12”) diameter for clay, concrete and cast iron pipes and DN32-300 (1¼-12“) for copper, steel and PVC pipes The two part resin is packaged in sealed tubes and ships from USA. Suggested storage at room temperature and in accordance with the guidelines in Technical Data Sheet. Picote Brush Coating™ System How long will the pipe be out of service? Dry to touch in 3 hrs with ambient cure. Light wear 4 hours. Final hardness 24 hours. Full service can be restored 4 hours after last coat has been applied (24hrs for potable). Type of pipe: Suitable for cast iron, PVC, concrete, clay, copper, and stainless steel. Preparation of the coating surface is dependent on the material of the pipe. Other application: if used to coat outside during cold weather, use appropriate heat. The Picote Brush Coating™ System is powered by the Picote Millers The Mini or Maxi Coating Pump is conveniently set on the top of the Miller. The system is practical and easy to keep clean. Picote Millers can also be used for drain cleaning and reinstatements on lateral connections. 5 Ryan Boldan, Global Learning Solutions Director +1 864 940-0088 / ryan@picotesolutions.com or Richard Swan, Director of Client Technical Services +44 (0) 7827 223237 / richard@picotesolutions.com GENERAL DESCRIPTION COLOR USAGE CONCRETE STEEL/DUCTILE IRON STAINLESS STEEL Concrete must be jetted and cleaned removing any loose concrete. Must be free of grease and oil. Near-White SSPC-SP10/NACE 2. Acceptable methods: sand blast, chain flail, or sanding side grinding panel. Remove debris. Nace No. 1/SSPC SP-5 White Metal Blast. Special preparation in addition to Picote’s cleaning tools may be needed. ALL SURFACES MUST BE DRY, CLEAN AND FREE FROM OIL, GREASE, DEBRIS AND OTHER CONTAMINANTS! SOLIDS VOLATILE ORGANIC COMPOUNDS COVERAGE CURE TIME AT 70º F 21º C RECOAT NUMBER OF COMPONENTS 100% (no solvents) None 20 mils per coat Recoat Water Contact Final Cure 3 hours 4 hours 24 hours Can be recoated within 12 hours. After 12 hours must be abraided with side grinding panels 2 11.7 lbs/Gallon (1.2kg/Litre) 60ºF/15.5ºC - 85ºF/29ºC Unopened: 24 months from date of manufacture when stored according to recommended conditions. Opened: up to 6 weeks 392ºF (200ºC) NET WEIGHT STORAGE TEMP SHELF LIFE FLASH POINT 100% SOLIDS EPOXY Contrasting colors (White & Gray or White & Blue) between coats. Plural component epoxy used to rehabilitate concrete, PVC, fiberglass, clay, cast iron and ductile iron pipes. Creating a monolythic semi-structural repair of decayed and damaged pipelines. Designed exclusively for the Picote Brush Coating™ System. SURFACE PREPARATION TECHNICAL DATA DESCRIPTION 6 2110001001 PICOTE DUAL COLOR EPOXY DC1000E TECH DATA SHEET DESCRIPTON Minimum 10 mils (0.3mm) 160 ft2/gal (4m2/litre) 80 ft2/gal (2m2/litre) 20 minutes at 70ºF (21ºC) 2 to 1 in prepackaged cartridge Picote Brush Coating™ System RATE OF COVERAGE POT LIFE MIXING RATIO APPLICATION EQUIPMENT Tensile Strength ASTM D638-14 2979 psi Compression Strength ASTM D695-15 9570 psi Flexural Modulus Flexural Strength ASTM D790-15e2 ASTM D790-14e2 430 ksi 6080 psi Adhesive Strength ASTM D4541 substrate failure 2110001001 PICOTE DUAL COLOR EPOXY DC1000E TECH DATA SHEET APPLICATION ASTM WRc APPROVAL Picote Brush Coating™ System is WRc approved for all non-potable and wastewater applications for pipe diameters between DN50mm (2”) and DN300mm (12”) diameter for clay, concrete and cast iron pipes and DN32mm (1¼”) and DN300mm (12“) for copper, steel and PVC pipes. NSF 61.5 CERTIFICATION Product certified to NSF/ANSI 372 conforms to the requirements or “Lead Free” plumbing products as defined by California, Vermont, Maryland and Louisiana. Standard: NSF/ANSI 61 Section 5 - 2016 Models: DC1000E Color: White Picote’s 100% Solids Epoxy Resin, DC1000E, is certified for potable water pipes (DN100) 4’’ and above. The final coat must be in White. CLEAN UP Clean brush and pump hose fittings using acetone. Dispose of feed and pump hose. REFER TO SAFETY DATA SHEET FOR SAFETY AND HEALTH INFORMATION 7 Maximum 20-40 mils (0.5-1mm) Please contact your reseller or Picote at coating@picotesolutions.com Picote Solutions Inc., 777 W Pinnacle Peak Rd, Ste B-108 Phoenix, AZ 85027 - USA Tel: +1 864 940 0088 WRc APPROVAL Certified Product Listing For: Drinking Water System Components – Health Effects Company: Picote Solutions, Inc. 20810 SE 18th Place Sammamish, WA 98075, United States Plant Location: Sandy, UT, United States Standards: NSF/ANSI/CAN 61 - 2020 Certificate: Issued Date: 03/29/2017 Material/Product: Coatings Contact Temperature: 23 ± 2℃ Models: DC1000E Page 1/2 Material Characteristics: Minimum pipe diameter (inches): 4 Maximum pipe surface area/volume ratio (sq in/L): 61 Minimum tank size (gallons): 50 Maximum tank surface area/volume ratio (sq in/L): 16.8 Maximum dry film thickness per coat (mils): 125 Number of coats: 1 Is additional coating required (e.g. top coat, primer, intermediate coat)? (Y/N): No Total cure time and temperature: 4 days @ 70°F Shortest cure time between coats or layers: 2 hours Final cure time: 4 days @ 70°F Mix ratio: 2:1 Colors: White Is this paint/coating system intended to be applied to a pipe? (Y/N): Yes (1) Certified for use on a new pipe? (Y/N): Yes (2) Certified for use on a pipe intended for immediate return to service? (Y/N): No Additional comments: Flushing or preparation instruction prior to use: a) Flushing Time: General Flush at 15 minutes b) Temperature of Flush: 23 ± 2 °C Powered by TCPDF (www.tcpdf.org) Page 2/2 Product Certificate This is to certify that the following product has met the requirements detailed below Picote Brush Coating™ System Picote Brush Coating™ System as manufactured by Picote Solutions Inc. Applicable to non-potable and wastewater applications for pipe diameters 32mm (1¼”) to 300mm (12”). Picote Solutions Ltd 20810 SE 18th Place Sammamish WA 98075 USA This product meets the requirements set out in WRc Assessment Schedule PT/431/0918-AS. 18th September 2018 31st December 2021 PT/431/0918 10 11 Extended through 12-21Pleasesee newcertificateprecedingthissection Page 1 of 5 ASTM Testing on Picote’s Epoxy Coating System TESTED PRODUCT: Picote Dual Color Epoxy A piece of finished product, with a maximum thickness of .125-inches, is machined into a dog-bone shape. Each end of the test specimen is placed in opposite facing clamps which then attempt to pull it apart. The PSI that it takes to break the specimen is calculated as "Tensile Strength at the Break". The "Tensile Elongation at the Break" is an additional measurement that shows how much the product stretches during this test.The "Tensile Modulus" is a measure taken to test rigidity. All of these measurements make up the “Tensile Strength” test. The D638-14 test would simulate separating pipe joints and the effect that would have on the product in question. TEST 1: ASTM D638-14 “Tensile Strength” TEST 1 RESULTS: Picote Epoxy Coating Tensile Test Test Method: Test Conditions: Conditioning: Preparation: Specimen: Cross Head Speed: ASTM D638-14 23±2°C, 50±10% R.H. 40+ hours, 23±2°C, 50±10% R.H. Machined from sample sent by client Type I tensile bars (2-inch gage length) 0.2-inches per minute Sample Replicate Width (inches) Thickness (inches) Tensile Strength at Break (psi) Tensile Elongation at Break (%) Tensile Modulus at Young’s (ksi) P/N Picote Dual Coat 1000E* 0.5117 0.2209 2970 0.62 586 n/a n/a n/a Requirement *Picote Dual Color Epoxy 2110001001 Force Measurement Constant Rate of Motion Test Specimen Thick- ness 1/8” A total of four tests were performed including: 1. Tensile Strength 2. Compression Strength 3. Flexural Modulus 4. Coating Pull Off Strength. Fixed Head Fixed Head picotesolutions.com TEST 1 Grips for Holding Specimen Firmly 12 Page 2 of 5 ASTM Testing on Picote’s Epoxy Coating System TESTED PRODUCT: Picote Dual Color Epoxy A sample of the product at approximately .25-inches is laid flat and a machine pushes down on the specimen until it be- gins to compress. The PSI it requires to sheer the sample is its “Compression Strength”. The amount it swells when the pressure is applied is also measured. This test will show how well the product can sustain loads. Please note: This test does not measure the Compression Strength of the cylinder that is created by the product inside the pipe. TEST 2: D695-15 “Compression Strength” TEST 2 RESULTS: Picote’s Epoxy Coating Compressive Test Test Method: Test Conditions: Conditioning: Preparation: Specimen: Cross Head Speed: ASTM D695-15 23±2°C, 50±10% R.H. 40+ hours, 23±2°C, 50±10% R.H. Machined from sample sent by client Prism (1.0-inch length) 0.05 inches per minute Sample Replicate Width (inches) Thickness (inches) Compressive Strength at Yield (PSI) P/N Picote Dual Coat 1000E* 0.5260 0.2302 9570 Requirement n/a *Picote Dual Color Epoxy 2110001001 A total of four tests were performed including: 1. Tensile Strength 2. Compression Strength 3. Flexural Modulus 4. Coating Pull Off Strength. picotesolutions.com TEST 2 13 Page 3 of 5 ASTM Testing on Picote’s Epoxy Coating System TESTED PRODUCT: Picote Dual Color Epoxy This test is used to measure the horizontal strength of the material. Supports are placed under the sample at each end, and then a piston drives down at the center. The force to drive down and the amount of deflection are mea- sured to come up with the specimen’s “Flexural Modu- lus”. This test would simulate areas in a coated pipe that are being subjected to uneven stress. TEST 3: D790-15e2 ”Flexural Modulus” TEST 3 RESULTS: Picote’s Epoxy Coating Flexural Test Test Method: Test Conditions: Conditioning: Preparation: Support Span: Cross Head Speed: ASTM D790-15e2, Procedure A 23±2°C, 50±10% R.H. 40+ hours, 23±2°C, 50±10% R.H. Machined from sample sent by client 3.641 inches 0.090 inches per minute Sample Replicate Width (inches) Depth Flexural Strength at Break (PSI) Flexural Modulus (KSI) P/N Picote Dual Coat 1000E* 2 0.5117 0.2142 6080 418 Requirement *Picote Dual Color Epoxy 2110001001 A total of four tests were performed including: 1. Tensile Strength 2. Compression Strength 3. Flexural Modulus 4. Coating Pull Off Strength. picotesolutions.com TEST 3 14 Page 4 of 5 ASTM Testing on Picote’s Epoxy Coating System TESTED PRODUCT: Picote Dual Color Epoxy In this test, a dolly is glued to the epoxy and allowed to cu- re. The sample is then cored using a hole saw. A device with a piston is attached that pulls away from the substrate until it breaks. This test can look for two different outcomes depending upon the substrate used. When a brick or concrete substra- te is used in a real-world application, it is testing whether or not that substrate breaks before the coating (product) does. If steel were to be used, however, the coating will always break before the substrate, so the PSI is also measured at the time of the break. The D4541-09 test simulates a pipe (that has been coated with the product) breaking, failing, or becoming compro- mised in any way and how well the material would hold up and stay adhered under those circumstances. TEST 4: D4541-09 “Coating Pull Off Strength” TEST 4 RESULTS: Picote’s Epoxy Coating Pull-off Strength Test Test Method: Test Conditions: Conditioning: Preparation: Specimen: Instrument: Cross Head Speed: ASTM D4541-09 23±5°C, 50±35% R.H. As sent by client Coating as sent by client. Loading fixture glued to coating Fixed alignment test modified to use a tensile tester 0.2 inches per minute A total of four tests were performed including: 1. Tensile Strength 2. Compression Strength 3. Flexural Modulus 4. Coating Pull Off Strength. picotesolutions.com TEST 4 15 Page 5 of 5 TEST 4 RESULTS: Picote’s Epoxy Coating Pull-off Strength Test continued Sample Replicate Loading Fixure Diameter (inches) Pull-Off Strength (psi) Failure Mode P/N Picote Dual Coat 1000E – Brick Substrate 0.500 >700 1-10% Coating Failure P/N Picote Dual Coat 1000E – Metal Substrate 0.500 >803 1-10% Coating Failure P/N Picote Dual Coat 1000E – Concrete Substrate 0.500 >798 0.1-1% Coating Failure n/a Requirement *Picote Dual Color Epoxy 2110001001 For more information on ASTM testing of Picote products, please contact: Ryan Boldan Global Learning Solutions Director, Picote Solutions Ryan@picotesolutions.com +1 (706) 805-5017 picotesolutions.com 16 Acetic Acid (20%) Excellent Acetone Not Recommended Acetylene Excellent Alcohol - Ethyl Excellent (temperature < 120oF, 50oC) Alcohol - Isopropyl Excellent Alcohol - Methyl Good (temperature < 72oF, 22oC) Aluminum Chloride Excellent (temperature < 72oF, 22oC) Aluminum Fluoride Good (temperature < 72oF, 22oC) Aluminum Hydroxide Good (temperature < 72oF, 22oC) Aluminum Sulfate Excellent (temperature < 72oF, 22oC) Amines Excellent (temperature < 72oF, 22oC) Ammonia - Liquid Excellent (temperature < 72oF, 22oC) Ammonia 10% Excellent (temperature < 72oF, 22oC) Ammonium Carbonate Excellent (temperature < 72oF, 22oC) Ammonium Chloride Excellent (temperature < 72oF, 22oC) Ammonium Hydroxide Excellent (temperature < 72oF, 22oC) Ammonium Nitrate Excellent (temperature < 72oF, 22oC) Ammonium Phosphate Excellent (temperature < 72oF, 22oC) Ammonium Sulfate Excellent (temperature < 72oF, 22oC) Amyl acetate Excellent (temperature < 72oF, 22oC) Aniline Fair (temperature < 72oF, 22oC) Barium Carbonate Excellent (temperature < 72oF, 22oC) Barium Chloride Excellent (temperature < 72oF, 22oC) Barium Hydroxide Excellent (temperature < 72oF, 22oC) Barium Sulfate Fair (temperature < 72oF, 22oC) Barium Sulfide Good (temperature < 72oF, 22oC) Beer Excellent (temperature < 72oF, 22oC) Benzol Excellent (temperature < 72oF, 22oC) Borax Excellent (temperature < 72oF, 22oC) Boric acid Excellent (temperature < 72oF, 22oC) Bromine Excellent (100 ppm) Butadiene gas Excellent (temperature < 72oF, 22oC) Butane gas Excellent (temperature < 72oF, 22oC) Butyl acetate Good (temperature < 72oF, 22oC) Butaric Acid Fair (temperature < 72oF, 22oC) Calcium Bisulfite Excellent (temperature < 72oF, 22oC) Calcium Carbonate Excellent (temperature < 72oF, 22oC) Calcium Chloride Excellent (temperature < 72oF, 22oC) Calcium Hydroxide Excellent (temperature < 72oF, 22oC) Calcium Hypochlorite Excellent (temperature < 72oF, 22oC) Calcium Sulfate Excellent (temperature < 72oF, 22oC) Carbon dioxide gas Excellent (temperature < 72oF, 22oC) Carbon Tetrachloride Excellent (temperature < 72oF, 22oC) Carbonic Acid Good (temperature < 72oF, 22oC) Citric Acid Excellent (temperature < 72oF, 22oC) Copper Chloride Excellent Copper Nitrate Excellent (temperature < 72oF, 22oC) Dichloroethane Good (temperature < 120oF, 50oC) Diesel Fuel Excellent (temperature < 72oF, 22oC) Ethyl acetate Fair (temperature < 72oF, 22oC) Ethyl chloride Excellent (temperature < 72oF, 22oC) Ethylene glycol Fair (temperature < 72oF, 22oC) Fatty Acids Excellent (temperature < 72oF, 22oC) Ferric Chloride Excellent (temperature < 72oF, 22oC) Ferric Sulfate Excellent (temperature < 72oF, 22oC) Ferrous Chloride Excellent (temperature < 72oF, 22oC) Ferrous Sulfate Excellent (temperature < 72oF, 22oC) Fluorine gas Note Recommended Fluosilicic acid Fair Formaldehyde, 40% Excellent (temperature < 72oF, 22oC) Formic Acid Fair (temperature < 72oF, 22oC) Freon Excellent Gasoline Excellent Glucose Good Glycerine Excellent Heptane Excellent Hexane Good Hydraulic Fluid Excellent Hydrobromic Acid, 100% Not Recommended Hydrochloric acid, 20% Good (temperature < 72oF, 22oC) Hydrocyanic Acid Excellent Hydrofluoric Acid, 75% Good (temperature < 72oF, 22oC) Hydrogen Peroxide, 10% Fair (temperature < 72oF, 22oC) Hydrogen Sulfide Excellent Jet Fuel Excellent Kerosene Excellent Lactic Acid Good (temperature < 72oF, 22oC) Lead acetate Excellent Magnesium Carbonate Excellent Magnesium Chloride Excellent Magnesium Hydroxide Excellent Magnesium Nitrate Excellent Magnesium Sulfate Excellent Maleic Acid Excellent Mercury Excellent Methyl Ethyl Ketone Fair (temperature < 72oF, 22oC) Naphtha Excellent Naphthalene Excellent Nickel Chloride Excellent Nickel Sulfate Excellent Nitric Acid 5% Good Oil - Castor Excellent Oleic acid Excellent Oxalic Acid Excellent Phenol Good Phosphoric Acid Good Picric Acid Excellent Potassium Bicarbonate Excellent Potassium Bromide Excellent Potassium Carbonate Excellent Potassium Chloride Excellent Potassium Dichromate Fair Potassium Hydroxide Excellent Potassium Nitrate Excellent Potassium Sulfate Excellent Propane, liquid Excellent CHEMICAL RESISTANCE DC1000E 17 Propane, liquid Excellent Silver Nitrate Excellent Soaps/DETERGENT Excellent Sodium Acetate Excellent Sodium Bicarbonate Excellent Sodium Bisulfate Excellent Sodium Carbonate Fair (temperature < 72oF, 22oC) Sodium Chlorate Excellent Sodium Chloride Excellent Sodium Cyanide Excellent Sodium Fluoride Excellent Sodium Hydroxide, 10% Excellent Sodium Hydroxide, 50% Good (temperature < 120oF, 50oC) Sodium Hypochlorite, 100% Not Recommended Sodium Nitrate Excellent Sodium Silicate Excellent Sodium Sulfate Excellent Sodium Sulfite Excellent Sodium Thiosulfate Excellent Stannic Chloride Excellent Stearic Acid Good Sulfuric Acid, 20% Excellent Sulfuric Acid, 75-100% Fair (temperature < 72oF, 22oC) Sulfur Dioxide Excellent (temperature < 72oF, 22oC) Tannic Acid Excellent Tartaric Acid Excellent Toluene Good (temperature < 72oF, 22oC) Turpentine Good Urine Excellent Vinegar Excellent Water - Distilled Excellent Water - Fresh Excellent Water - Sea, Salt Excellent Xylene Excellent Zinc Chloride Excellent CHEMICAL RESISTANCE DC1000E 18 SECTION 1 IDENTIFICATION SAFETY DATA SHEET PICOTE BRUSH COATING™ EPOXY RESIN DC1000E BASE (COLOR: WHITE, GRAY, OR BLUE) Revision date: 04-2021 SECTION 2 HAZARD(S) IDENTIFICATION 1.1. Product identifier Picote Brush Coating™ Epoxy Resin: DC1000E Base (Color: White, Gray, or Blue) 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture @0102.B010286 1.3. Details of the supplier of the safety data sheet Company name: Street: Place: Telephone: Picote Solutions 20810 SE 18th PL Sammamish, WA 98075 480-622-8314 ryan@picotesolutions.com Ryan Boldan www.picotesolutions.com e-mail: Contact person: Internet: Emergency telephone:800-535-5053 - INFOTRAC 2.1. Classification of the substance or mixtureRegulation (EC) No. 1272/2008Hazard categories: Skin corrosion/irritation: Skin Corr. 2 Serious eye damage/eye irritation: Eye Irrit. 2 Respiratory or skin sensitisation: Skin Sens. 1 Hazardous to the aquatic environment: Aquatic Chronic 3Hazard Statements: Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Harmful to aquatic life with long lasting effects. 2.2. Label elementsRegulation (EC) No. 1272/2008Hazard components for labelling bis-[4-(2,3-epoxipropoxi)phenyl]propane Formaldehyde, oligomeric reaction products with 1-chloro-2,3-epoxypropane and phenol oxirane, mono[(C12-14-alkyloxy)methyl] derivs. Signal word: Warning Hazard statements: H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H412 Harmful to aquatic life with long lasting effects.Precautionary statements: P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 IF ON SKIN: Wash with plenty of water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. 2.3. Other hazards No information available. SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS SECTION 4 FIRST AID MEASURES 3.2. MixturesHazardous components 4.1 Description of first aid measures After inhalation: Provide fresh air. After contact with skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. After contact with eyes: Rinse immediately carefully and thoroughly with eye-bath or water. After ingestion: Rinse mouth immediately and drink plenty of water. 4.2 Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. Full text of H and EUH statements: see section 16. CAS No EC No Chemical Name GHS Classification Index No REACH No Quantity 1675-54-3 216-823-5 bis-[4-(2,3-epoxipropoxi)phenyl] propane Skin Irrit. 2, Eye Irrit. 2, Skin Sens. 1; H315 H319 H317 603-073-00-2 01-2119456619-26 20 - < 50 % 9003-36-5 500-006-8 Formaldehyde, oligomeric reaction products with 1-chloro-2,3- epoxypropane and phenol Skin Irrit. 2, Skin Sens. 1, Aquatic Chronic 2; H315 H317 H411 ———01-2119454392-40 5 - < 20 % 68609-97-2 271-846-8 oxirane, mono[(C12-14-alkyloxy) methyl] derivs. Skin Irrit. 2, Skin Sens. 1; H315 H317 603-103-00-4 01-2119485289-22 5 - < 20 % SECTION 5 FIREFIGHTING MEASURES 5.1 Extinguishing media Suitable extinguishing media: Co-ordinate fire-fighting measures to the fire surroundings. 5.2 Special hazards arising from the substance or mixture Non-flammable. 5.3 Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Additional information Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. SECTION 6 ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Use personal protection equipment. 6.2 Environmental precautions Do not allow to enter into surface water or drains. SECTION 7 HANDLING AND STORAGE SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 6.3 Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal. 6.4 Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 7.1 Precautions for safe handling:Advice on safe handling No special measures are necessary.Advice on protection against fire and explosion No special fire protection measures are necessary. 7.2 Conditions for safe storage, including any incompatibilities:Requirements for storage rooms and vessels Keep container tightly closed.Hints on joint storage No special measures are necessary. 7.3 Specific end use(s) @0102.B010286 8.1 Control parameters 8.2 Exposure controls Protective and hygiene measures Take off contaminated clothing. Wash hands before breaks and after work. When using do not eat or drink. Eye/face protection Wear eye protection/face protection. Hand protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. Skin protection Wear suitable protective clothing. Respiratory protection In case of inadequate ventilation wear respiratory protection. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Physical state: liquid Colour: white, grey Odour: characteristic pH-Value: not determined Changes in the physical state Melting point: not determined Initial boiling point and boiling range: not determined Flash point: 130°C Flammability Solid: not applicable Gas: not applicable Lower explosion limits: not determined Upper explosion limits: not determined Auto-ignition temperature Solid: not applicable Gas: not applicable Decomposition temperature: not determined Oxidizing properties Not oxidising. Vapour pressure: not determined Density (at 20 °C): 1,6 g/cm³ Water solubility: The study does not need to be conducted because the substance is known to be insoluble in water. Solubility in other solvents Not determined Partition coefficient: not determined Vapour density: not determined Evaporation rate: not determined 9.2 Other information Solid content: not determined SECTION 10 STABILITY AND REACTIVITY 10.1 Reactivity No hazardous reaction when handled and stored according to provisions. 10.2 Chemical stability Danger of polymerisation. 10.3 Possibility of hazardous reactions Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions. 10.4 Conditions to avoid none 10.5 Incompatible materials Keep away from: Radical former, Peroxides, Reducing agent. 10.6 Hazardous decomposition products No known hazardous decomposition products. SECTION 11 TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effectsAcute toxicity CAS No Chemical Name Exposure Route Dose Species Source Method 9003-36-5 Formaldehyde, oligomeric reaction products with 1-chloro-2,3- epoxypropane and phenol oral: dermal: LD50 >2000 mg/kg LD50 >400 mg/kg Rat Rat SECTION 12 ECOLOGICAL INFORMATION 12.1 Toxicity The product is not: Ecotoxic. 12.2 Persistence and degradability The product has not been tested. 12.3 Bioaccumulative potential The product has not been tested. 12.4 Mobility in soil The product has not been tested. SECTION 13 DISPOSAL CONSIDERATIONS SECTION 14 TRANSPORT INFORMATION 13.1 Waste treatment methodsAdvice on disposal Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste according to applicable legislation.Contaminated packaging Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the substance itself. Land transport (ADR/RID) 14.1 UN number: UN 3082 14.2 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. bis-[4-(2,3-epoxipropoxi)phenyl]propane 14.3 Transport hazard class(es): 9 14.4 Packing group: III Hazard label: 9 Classification code: M6 Special Provisions: 274 335 375 601 Limited quantity: 5 L Excepted quantity: E1 Transport category: 3 Hazard No: 90 Tunnel restriction code: - Inland waterways transport (ADN) 14.1 UN number: UN 3082 14.2 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. bis-[4-(2,3-epoxipropoxi)phenyl]propane 14.3 Transport hazard class(es): 9 14.4 Packing group: III Hazard label: 9 Classification code: M6 Special Provisions: 274 335 375 601 Limited quantity: 5 L Excepted quantity: E1 Marine transport (IMDG) 14.1 UN number: UN 3082 14.2 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. bis-[4-(2,3-epoxipropoxi)phenyl]propane 12.5 Results of PBT and vPvB assessment The product has not been tested. 12.6 Other adverse effects No information available. Further information Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. 14.3 Transport hazard class(es): 9 14.4 Packing group: III Hazard label: 9 Special Provisions: 274, 335, 969 Limited quantity: 5 L Excepted quantity: E1 EmS: F-A, S-F Air transport (ICAO-TI/IATA-DGR) 14.1 UN number: UN 3082 14.2 UN proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. bis-[4-(2,3-epoxipropoxi)phenyl]propane 14.3 Transport hazard class(es): 9 14.4 Packing group: III Hazard label: 9 Special Provisions: A97 A158 A197 Limited quantity Passenger: 30 kg G Passenger LQ: Y964 Excepted quantity: E1 IATA-packing instructions - Passenger: 964 IATA-max. quantity - Passenger: 450 L IATA-packing instructions - Cargo: 964 IATA-max. quantity - Cargo: 450 L 14.6 Special precautions for user Warning: strongly corrosive. 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code not applicable 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureNational regulatory information: Water contaminating class (D): 2 - clearly water contaminating 15.2 Chemical safety assessment Chemical safety assessments for substances in this mixture were not carried out. Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road ) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% SECTION 15 REGULATORY INFORMATION SECTION 16 OTHER INFORMATION Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP] Classification Classification procedure Skin Irrit. 2; H315 Calculation method Eye Irrit. 2; H319 Calculation method Skin Sens. 1; H317 Calculation method Aquatic Chronic 3; H412 Calculation method Relevant H and EUH statements (number and full text) H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. Further Information @N16.P0000001 @N16.P0000002 (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor’s safety data sheet.) SECTION 1 IDENTIFICATION SAFETY DATA SHEET PICOTE BRUSH COATING™ EPOXY RESIN DC1000E CATALYST (COLOR: CLEAR) Revision date: 04-2021 SECTION 2 HAZARD(S) IDENTIFICATION 1.1. Product identifier Picote Brush Coating™ Epoxy Resin: Picote DC1000E Catalyst (Color: CLEAR) 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture @0102.B010286 1.3. Details of the supplier of the safety data sheet Picote Solutions 20810 SE 18th PL Sammamish, WA 98075 480-622-8314 ryan@picotesolutions.com Ryan Boldan www.picotesolutions.com Company name: Street: Place: Telephone: e-mail: Contact person: Internet: Emergency telephone:800-535-5053 - INFOTRAC 2.1. Classification of the substance or mixtureRegulation (EC) No. 1272/2008Hazard categories: Skin corrosion/irritation: Skin Corr. 1 Serious eye damage/eye irritation: Eye Dam. 1 Respiratory or skin sensitisation: Skin Sens. 1 Reproductive toxicity: Repr. 2 Hazardous to the aquatic environment: Aquatic Chronic 2Hazard Statements: Causes severe skin burns and eye damage. Causes serious eye damage. May cause an allergic skin reaction. Suspected of damaging fertility. Toxic to aquatic life with long lasting effects. 2.2. Label elementsRegulation (EC) No. 1272/2008 Hazard components for labelling 4-tert-butylphenol m-phenylenebis(methylamine) Trimethylhexan-1,6-diamin Reaction products of C18 (unsaturated) fatty acids with tetraethylenediamine Tetraethylenepentamine Signal word: Danger Hazard statements: H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H361f Suspected of damaging fertility. H411 Toxic to aquatic life with long lasting effects. Precautionary statements: P260 Do not breathe dust/fume/gas/mist/vapours/spray. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P391 Collect spillage. 2.3. Other hazards No information available. SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS SECTION 4 FIRST AID MEASURES 3.2. MixturesHazardous components 4.1 Description of first aid measures After inhalation: Provide fresh air. After contact with skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. After contact with eyes: Rinse immediately carefully and thoroughly with eye-bath or water. After ingestion: Rinse mouth immediately and drink plenty of water. 4.2 Most important symptoms and effects, both acute and delayed No information available. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. Full text of H and EUH statements: see section 16. CAS No EC No Chemical Name GHS Classification Index No REACH No Quantity 1477-55-0 216-032-5 m-phenylenebis(methylamine) Acute Tox. 4, Acute Tox. 4, Skin Corr. 1B, Eye Dam. 1, Skin Sens. 1, Aquatic Chronic 3; H332 H302 H314 H318 H317 H412 EUH071 ———01-2119480150-50 5 - < 20 % 98-54-4 202-679-0 4-tert-butylphenol Repr. 2, Skin Irrit. 2, Eye Dam. 1, STOT SE 3, Aquatic Chronic 1; H361f H315 H318 H335 H410 604-090-00-8 01-2119489419-21 5 - < 20 % 25620-58-0 247-134-8 Trimethylhexan-1,6-diamin Acute Tox. 4, Skin Corr. 1A, Eye Dam. 1, Skin Sens. 1, Aquatic Chronic 3; H302 H314 H318 H317 H412 ———01-2119560598-25 5 - < 20 % 100-51-6 202-859-9 benzyl alcohol Acute Tox. 4, Acute Tox. 4; H332 H302 603-057-00-5 01-2119492630-38 1 - < 5 % 1226892-45-0 629-725-6 Reaction products of C18 (unsaturated) fatty acids with tetraethylenediamine Skin Corr. 1, Skin Sens. 1, Aquatic Chronic 1; H314 H317 H410 ———01-2119487006-38 1 - < 5 % 90640-66-7 292-587-7 Tetraethylenepentamine Acute Tox. 4, Acute Tox. 4, Skin Corr. 1, Skin Sens. 1; H312 H302 H314 H317 ———01-2119487290-3 1 - < 5 % SECTION 5 FIREFIGHTING MEASURES SECTION 6 ACCIDENTAL RELEASE MEASURES SECTION 7 HANDLING AND STORAGE SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION 5.1 Extinguishing media Suitable extinguishing media: Co-ordinate fire-fighting measures to the fire surroundings. 5.2 Special hazards arising from the substance or mixture Non-flammable. 5.3 Advice for firefighters In case of fire: Wear self-contained breathing apparatus. Additional information Collect contaminated fire extinguishing water separately. Do not allow entering drains or surface water. 6.1 Personal precautions, protective equipment and emergency procedures Use personal protection equipment. 6.2 Environmental precautions Do not allow to enter into surface water or drains. 6.3 Methods and material for containment and cleaning up Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents). Treat the recovered material as prescribed in the section on waste disposal. 6.4 Reference to other sections Safe handling: see section 7 Personal protection equipment: see section 8 Disposal: see section 13 7.1 Precautions for safe handling: Advice on safe handling No special measures are necessary. Advice on protection against fire and explosion No special fire protection measures are necessary. 7.2 Conditions for safe storage, including any incompatibilities: Requirements for storage rooms and vessels Keep container tightly closed. Hints on joint storage No special measures are necessary. 7.3 Specific end use(s) @0102.B010286 8.1 Control parameters 8.2 Exposure controls Protective and hygiene measures Take off contaminated clothing. Wash hands before breaks and after work. When using do not eat or drink.Eye/face protection Wear eye protection/face protection. Hand protection When handling with chemical substances, protective gloves must be worn with the CE-label including the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the specific working place concentration and quantity of hazardous substances. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.Skin protection Wear suitable protective clothing. Respiratory protection In case of inadequate ventilation wear respiratory protection. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Physical state: liquid Colour: brown Odour: Amines pH-Value: alkaline Changes in the physical state Melting point: not determined Initial boiling point and boiling range: not determined Flash point: not determined Flammability Solid: not applicable Gas: not applicable Lower explosion limits: not determined Upper explosion limits: not determined Auto-ignition temperature Solid: not applicable Gas: not applicable Decomposition temperature: not determined Oxidizing properties Not oxidising. Vapour pressure: not determined Density (at 20 °C): 1,3 g/cm³ ISO 1183 Water solubility: The study does not need to be conducted because the substance is known to be insoluble in water. Solubility in other solvents Not determined Partition coefficient: not determined Vapour density: not determined Evaporation rate: not determined 9.2 Other information Solid content: not determined SECTION 10 STABILITY AND REACTIVITY 10.1 Reactivity No hazardous reaction when handled and stored according to provisions. 10.2 Chemical stability The product is stable under storage at normal ambient temperatures. 10.3 Possibility of hazardous reactions No known hazardous reactions. 10.4 Conditions to avoid none 10.5 Incompatible materials No information available. 10.6 Hazardous decomposition products No known hazardous decomposition products. SECTION 11 TOXICOLOGICAL INFORMATION SECTION 12 ECOLOGICAL INFORMATION 11.1 Information on toxicological effectsAcute toxicity 12.1 Toxicity The product is not: Ecotoxic. 12.2 Persistence and degradability The product has not been tested. 12.3 Bioaccumulative potential The product has not been tested. Partition coefficient n-octanol/water 12.4 Mobility in soil The product has not been tested. 12.5 Results of PBT and vPvB assessment The product has not been tested. 12.6 Other adverse effects No information available. Further information Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. CAS No Chemical Name Exposure Route Dose Species Source Method 1477-55-0 m-phenylenebis(methylamine) oral: dermal: inhalation vapour: inhalation aerosol: LD50 930 mg/kg LD50 >3100 mg/kg ATE 11 mg/l ATE 1,5 mg/l Rat Rabbit —— —— 98-54-4 4-tert-butylphenol oral: dermal: LD50 2951mg/kg LD50 2288 mg/kg Rat Rabbit 25620-58-0 Trimethylhexan-1,6-diamin oral: dermal: LD50 910 mg/kg Data lacking Rat 100-51-6 benzyl alcohol oral: inhalation vapour: inhalation aerosol: LD50 1230 mg/kg ATE 11 mg/l ATE 1,5 mg/l @N11.P0000002 GESTIS 90640-66-7 Tetraethylenepentamine oral: dermal: ATE 500 mg/kg ATE 1100 mg/kg CAS No Chemical Name Aquatic Toxicity Dose [ h ] [ d ]Species Source Method 98-54-4 4-tert-butylphenol Acute fish toxicity LC50 >1 mg/l 96 h LC50: Oryzias latipes (Ricefish)Manufacturer Acute algae toxicity ErC50 14 mg/l 72 h EC50:Pseudokirchneriella subcapitata Manufacturer Acute crustacea toxicity EC50 3,4 mg/l 48 h EC50: Daphnia magna (Big water flea)Manufacturer Fish toxicity NOEC 0,1 mg/l 128 d NOEC Pimephales promelas (fathead minnow)Manufacturer Algea toxicity NOEC 0,32 mg/l 72 d NOEC Pseudokirchneriellasubcapitata Manufacturer Crustacea toxicity NOEC 0,73 mg/l 21 d NOEC Daphnia magna (Big water flea)Manufacturer CAS No Chemical Name Log Pow 100-51-6 benzyl alcohol 1,05 SECTION 13 DISPOSAL CONSIDERATIONS SECTION 14 TRANSPORT INFORMATION 13.1 Waste treatment methodsAdvice on disposal Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of waste according to applicable legislation.Contaminated packaging Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the substance itself. Land transport (ADR/RID) 14.1 UN number: UN 2735 14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. m-phenylenebis(methylamine) 14.3 Transport hazard class(es): 8 14.4 Packing group: III Hazard label: 8 Classification code: C7 Special Provisions: 274 Limited quantity: 5 L Excepted quantity: E1 Transport category: 3 Hazard No: 80 Tunnel restriction code: E Inland waterways transport (ADN) 14.1 UN number: UN 2735 14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. m-phenylenebis(methylamine) 14.3 Transport hazard class(es): 8 14.4 Packing group: III Hazard label: 8 Classification code: C7 Special Provisions: 274 Limited quantity: 5 L Excepted quantity: E1 Marine transport (IMDG) 14.1 UN number: UN 2735 14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. m-phenylenebis(methylamine) 14.3 Transport hazard class(es): 8 14.4 Packing group: III Hazard label: 8 Special Provisions: 223, 274 Limited quantity: 5 L Excepted quantity: E1 EmS: F-A, S-B Air transport (ICAO-TI/IATA-DGR) 14.1 UN number: UN 2735 14.2 UN proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. m-phenylenebis(methylamine) 14.3 Transport hazard class(es): 8 14.4 Packing group: III Hazard label: 8 Special Provisions: A3 A803 Limited quantity Passenger: 1 L Passenger LQ: Y841 Excepted quantity: E1 IATA-packing instructions - Passenger: 852 IATA-max. quantity - Passenger: 5 L IATA-packing instructions - Cargo: 856 IATA-max. quantity - Cargo: 60 L 14.6 Special precautions for user Warning: strongly corrosive. 14.7 Transport in bulk according to Annex II of Marpol and the IBC Code not applicable 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureEU regulatory information: Restrictions on use (REACH, annex XVII): Entry 3: benzyl alcohol 2004/42/EC (VOC): 3,5 % (45,5 g/l)National regulatory information: Water contaminating class (D): 2 - clearly water contaminating 15.2 Chemical safety assessment Chemical safety assessments for substances in this mixture were not carried out. Abbreviations and acronyms ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road ) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service LC50: Lethal concentration, 50% LD50: Lethal dose, 50% Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP] Classification Classification procedure Skin Corr. 1; H314 Calculation method Eye Dam. 1; H318 Calculation method Skin Sens. 1; H317 Calculation method Repr. 2; H361f Calculation method Aquatic Chronic 2; H411 Calculation method SECTION 15 REGULATORY INFORMATION SECTION 16 OTHER INFORMATION Relevant H and EUH statements (number and full text) H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H335 May cause respiratory irritation. H361f Suspected of damaging fertility. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. H412 Harmful to aquatic life with long lasting effects. EUH071 Corrosive to the respiratory tract. Further Information @N16.P0000001 @N16.P0000002 (The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor’s safety data sheet.) PICOTE FIBER BONDED MASTIC TECH DATA SHEET 100% SOLIDS TROWELABLE EPOXY Gloss white Used to protect new infrastructure and to rehabilitate existing damaged infrastructure. GENERAL DESCRIPTION COLOR USAGE CONCRETE/BRICK STEEL Substrate surface must be Hydro Blasted at 3000 psi., removing any loose concrete or other material. Must be free of grease and oil. Sand blast to a Nace No. 1/SSPC SP-5 White Metal Profile. ALL SURFACES MUST BE DRY, CLEAN AND FREE FROM OIL, GREASE, DEBRIS AND OTHER CONTAMINANTS! SOLIDS VOLATILE ORGANIC COMPOUNDS COVERAGE CURE TIME AT 70ºF (21º C) RECOAT NUMBER OF COMPONENTS 100% (no solvents) None 125 to 250 mils per coat (3-6mm) Recoat Water Contact Final Cure 2 hours 4 hours 24 hours Must be abraided with the equivalent of 36 grit sand paper after 24 hrs. 2 2110002001 DESCRIPTION SURFACE PREPARATION TECHNICAL DATA PERFORMANCE • Manholes, wet wells, vaults & septic tanks • Steel substrates • Floor and wall penetrations/cracks • Simple spot repair • Extreme bonding to nearly all substrates • Fast curing • Easy workability • ¼” build capability with no sag • No mixing means faster application 28 2.5lbs (1/1kg) usable material/cartridge 15lbs (6.9kg) usable material/case (6 cartridges) 70ºF (21ºC) 24 months unopened n/a NET WEIGHT STORAGE TEMP SHELF LIFE FLASH POINT DESCRIPTION Sqft/gallon 10 minutes at 70ºF (21ºC) 2 to 1 in prepackaged cartridge. Also available in buckets. Use with Picote Smart Mixer 2.0, a cordless cartridge dispenser. Use only the material that the job requires, leaving virtually no wasted material. Directly applied to substrate from static mixing tip. Use trowel or putty knife to smooth material. RATE OF COVERAGE POT LIFE MIXING RATIO APPLICATION EQUIPMENT Tensile Strength ASTM D638-14 4150 psi Compression Strength ASTM D695-13 9650 psi Flexural Modulus Flexural Strength ASTM D790-15e2 Procedure A 8950 psi 437 ksi Coating Pull Off Strength Test ASTM D4541-09 substrate failure Acetone. REFER TO SAFETY DATA SHEET FOR SAFETY AND HEALTH INFORMATION. ASTM CLEAN UP ENVIRONMENTALLY SAFE: No harmful VOC’s or odors. Disposable packaging and minimal waste. Please Contact your reseller or Picote at coating@picotesolutions.com Picote Solutions Inc., 777 W Pinnacle Peak Rd, Ste B-108 Phoenix, AZ 85027 - USA Tel: +1 864 940 0088 2110002001 PICOTE FIBER BONDED MASTIC TECH DATA SHEET 29 250mils (6mm) 6.4 ft2 (.6 m2) Gallon 125mils (3mm) Gallon (1.2m2) Sqft/case 250mils (6mm) 9.12 ft2 (.8 m2) Case 125mils (3mm) Gallon (1.7m2) Page 1 of 5 ASTM Testing on Fiber Bonded Epoxy Mastic TESTED PRODUCT: Picote Fiber Bonded Mastic A piece of finished product, with a maximum thickness of .125-inches, is machined into a dog-bone shape. Each end of the test specimen is placed in opposite facing clamps which then attempt to pull it apart. The PSI that it takes to break the specimen is calculated as "Tensile Strength at the Break". The "Tensile Elongation at the Break" is an additional measurement that shows how much the product stretches during this test.The "Tensile Modulus" is a measure taken to test rigidity. All of these measurements make up the “Tensile Strength” test. The D638-14 test would simulate separating pipe joints and the effect that would have on the product in question. TEST 1: ASTM D638-14 “Tensile Strength” TEST 1 RESULTS: Picote Fiber Bonded Mastic Tensile Test Test Method: Test Conditions: Conditioning: Preparation: Specimen: Cross Head Speed: ASTM D638-14 23±2°C, 50±10% R.H. 40+ hours, 23±2°C, 50±10% R.H. Machined from sample sent by client Type I tensile bars (2-inch gage length) 0.2-inches per minute Sample Replicate Width (inches) Thickness (inches) Tensile Strength at Break (psi) Tensile Elongation at Break (%) Tensile Modulus at Young’s (ksi) P/N Picote Fiber Bonded Mastic 0.5090 0.3062 4000 0.66 644 n/a n/a n/a Requirement Force Measurement Constant Rate of Motion Test Specimen Thickness 1/8” A total of four tests were performed including: 1. Tensile Strength 2. Compression Strength 3. Flexural Modulus 4. Coating Pull Off Strength. Fixed Head Fixed Head TEST 1 Grips for Holding Specimen Firmly 30 Page 2 of 5 ASTM Testing on Fiber Bonded Epoxy Mastic TESTED PRODUCT: Picote Fiber Bonded Mastic A sample of the product at approximately .25-inches is laid flat and a machine pushes down on the specimen until it be- gins to compress. The PSI it requires to sheer the sample is its “Compression Strength”. The amount it swells when the pressure is applied is also measured. This test will show how well the product can sustain loads. Please note: This test does not measure the Compression Strength of the cylinder that is created by the product inside the pipe. TEST 2: D695-15 “Compression Strength” TEST 2 RESULTS: Picote Fiber Bonded Mastic Compressive Test Test Method: Test Conditions: Conditioning: Preparation: Specimen: Cross Head Speed: ASTM D695-15 23±2°C, 50±10% R.H. 40+ hours, 23±2°C, 50±10% R.H. Machined from sample sent by client Prism (1.0-inch length) 0.05 inches per minute Sample Replicate Width (inches) Thickness (inches) Compressive Strength at Yield (PSI) P/N Picote Fiber Bonded Mastic 0.5142 0.3068 9650 Requirement n/a A total of four tests were performed including: 1. Tensile Strength 2. Compression Strength 3. Flexural Modulus 4. Coating Pull Off Strength. TEST 2 31 Page 3 of 5 ASTM Testing on Fiber Bonded Epoxy Mastic TESTED PRODUCT: Picote Fiber Bonded Mastic This test is used to measure the horizontal strength of the material. Supports are placed under the sample at each end, and then a piston drives down at the center. The force to drive down and the amount of deflection are mea- sured to come up with the specimen’s “Flexural Modu- lus”. This test would simulate areas in a coated pipe that are being subjected to uneven stress. TEST 3: D 790-15e2 ”Flexural Modulus” TEST 3 RESULTS: Picote Fiber Bonded Mastic Flexural Test Test Method: Test Conditions: Conditioning: Preparation: Support Span: Cross Head Speed: ASTM D790-15e2, Procedure A 23±2°C, 50±10% R.H. 40+ hours, 23±2°C, 50±10% R.H. Machined from sample sent by client 5.184 inches 0.150 inches per minute Sample Replicate Width (inches) Depth Flexural Strength at Break (PSI) Flexural Modulus (KSI) P/N Picote Fiber Bonded Mastic 2 0.5172 0.2860 7050 437 Requirement n/a n/a A total of four tests were performed including: 1. Tensile Strength 2. Compression Strength 3. Flexural Modulus 4. Coating Pull Off Strength. TEST 3 32 Page 4 of 5 ASTM Testing on Fiber Bonded Epoxy Mastic TESTED PRODUCT: Picote Fiber Bonded Mastic In this test, a dolly is glued to the epoxy and allowed to cure. The sample is then cored using a hole saw. A device with a piston is attached that pulls away from the substrate until it breaks. This test can look for two different outcomes depending upon the substrate used. When a brick or concrete substra- te is used in a real-world application, it is testing whether or not that substrate breaks before the coating (product) does. If steel were to be used, however, the coating will always break before the substrate, so the PSI is also measured at the time of the break. The D4541-09 test simulates a pipe (that has been coated with the product) breaking, failing, or becoming compro- mised in any way and how well the material would hold up and stay adhered under those circumstances. TEST 4: D4541-09 “Coating Pull Off Strength” TEST 4 RESULTS: Picote Fiber Bonded Mastic Pull-off Strength Test ASTM D4541-09 23±5°C, 50±35% R.H. As sent by client Coating as sent by client. Loading fixture glued to coating Fixed alignment test modified to use a tensile tester 0.2 inches per minute A total of four tests were performed including: 1. Tensile Strength 2. Compression Strength 3. Flexural Modulus 4. Coating Pull Off Strength. Test Method: Test Conditions: Conditioning: Preparation: Specimen: Instrument: Cross Head Speed: TEST 4 33 Page 5 of 5 TEST 4 RESULTS: Picote Fiber Bonded Mastic Pull-off Strength Test continued Sample Replicate Loading Fixure Diameter (inches) Pull-Off Strength (psi) Failure Mode P/N Picote Fiber Bonded Mastic – Brick Substrate 0.500 >502 Substrate P/N Picote Fiber Bonded Mastic – Metal Substrate 0.500 >5 Coating P/N Picote Fiber Bonded Mastic – Concrete Substrate 0.500 >384 .Substrate n/a Requirement For more information on ASTM testing of Picote products, please contact: Ryan Boldan Global Learning Solutions Director, Picote Solutions Ryan@picotesolutions.com +1 (480) 622-8314 www.picotegroup.com 34 SECTION 1 . INDENTIFICATION Product Name: FIBER BONDED EPOXY MASTIC PART B Product Code: PICOTE MASTIC CATALYST PICOTE SOLUTIONS 20810 SE 18TH PL SAMMAMISH, WA 98075 PHONE 800-535-5053 EMERGENCY: INFOTRAC SECTION 2. HAZARD(S) IDENTIFICATION GHS Ratings: Oral Toxicity Acute Tox. 2 Oral>5+<=50mg/kg Skin corrosive 2 Reversible adverse effects in dermal tissue, Draize score: >= 2.3 < 4.0 or persistent inflammation Eye corrosive 1 Serious eye damage: Irreversible damage 21 days after exposure, Draize score: Corneal opacity >= 3, Iritis > 1.5 Skin sensitizer 1 Skin sensitizer Reproductive toxin 2 Human or animal evidence possibly with other information GHS Hazards H300 Fatal if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H318 Causes serious eye damage H361 Suspected of damaging fertility or the unborn child GHS Precautions P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P261 Avoid breathing dust/fume/gas/mist/vapours/spray P264 Wash … thoroughly after handling P270 Do not eat, drink or smoke when using this product P272 Contaminated work clothing should not be allowed out of the workplace P280 Wear protective gloves/protective clothing/eye protection/face protection P281 Use personal protective equipment as required P310 Immediately call a POISON CENTER or doctor/physician P321 Specific treatment (see … on this label) P330 Rinse mouth P362 Take off contaminated clothing and wash before reuse P363 Wash contaminated clothing before reuse P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P302+P352 IF ON SKIN: Wash with soap and water P305+P351+P338 IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing P308+P313 IF exposed or concerned: Get medical advice/attention P332+P313 If skin irritation occurs: Get medical advice/attention P333+P313 If skin irritation or a rash occurs: Get medical advice/attention P405 Store locked up P501 Dispose of contents/container to … Signal Word: Danger SDS for: PICOTE MASTIC CATALYST Page 1 of 535 Avoid breathing vapors Oral: N.D.A. Dermal: N.D.A. Inhalation: N.D.A. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS number Weight Concentration % Paratertiarybutylphenol 98-54-4 30.00% - 40.00% Amine 1477-55-0 20.00% - 30.00% 1,5-Pentanediamine, 2 methyl 15520-10-2 20.00% - 30.00% Silica 67762-90-7 10.00% - 20.00% nonyl phenol 84852-15-3 1.00% - 5.00% SECTION 4. FIRST AID MEASURES If inhaled remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptons Rinse immediately with plenty of water for at least 15 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Remove contacts if present and easy to do. Continue Rinsing. Get medical attention, if irritation or symptoms of overexposure persists. Immediately wash skin with soap and plenty of water. If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person SECTION 5. FIRE FIGHTING MEASURES Flash Point: 134 C (273 F) LEL: UEL: Not applicable Foam, Carbon dioxide (CO2) or dry chemical or water spray (water stream may be ineffective). No information available Not available Firefighters, and others exposed, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Stop leak. Dike or contain spill. Pump into slavage tanks and/or absorb with suitable material. Use sparkless shovel to remove material. Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Use appropriate containment and clean up immediately. Corrosive. Avoid personal contact adn breathing vapor or mist. Stop leak, Dike and contain spill.Prevent spilled material from entering the ground, water and/or air by using appropriate containment methods. SECTION 7. HANDLING and STORAGE Avoid breathing vapor. Avoid contact with eyes, skin and clothing. Keep away from heat and flame. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. Avoid exposure to heat, light, and air for prolonged periods of time. Store in a cool, dry well ventilated area away from sources of heat and incompatable materials. Eliminate all ignition materials and incompatible materials. Collect SDS for: PICOTE MASTIC CATALYST Page 2 of 536 spill with non spark tools. No information available. SECTION 8.EXPOSURE CONTROLS, PERSONAL PROTECTION Other Exposure LimitsACGIH Exposure LimitsOSHA Exposure LimitsChemical Name / CAS No. Paratertiarybutylphenol 98-54-4 Not EstablishedNot Established Not Established Amine 1477-55-0 0.1 mg/m3 CeilingNot Established NIOSH: 0.1 mg/m3 Ceiling 1,5-Pentanediamine, 2 methyl 15520-10-2 Not EstablishedNot Established Not Established Silica 67762-90-7 Not EstablishedNot Established Not Established nonyl phenol 84852-15-3 Not EstablishedNot Established Not Established Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficiant to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which preforms satisfactory and meets OSHA or other recgonized standards. Consult with local procedures for selection, training, and maintenance of the personal protective equipment Always use adaquate ventilation that comply with local regulations. Eye/face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face rotection reulation, or the Europena standard EN 166 Skin Protection: Chemical-resistant gloves and chemical goggles, face-shield and synthetic apron or coveralls should be used to prevent contact with eyes, skin or clothing. Respiratory Protection: A NIOSH air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive presure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known or any other circumstance where air purifyig respirator may not provide adequate protection. SECTION 9. PHYSICAL and CHEMICAL PROPERTIES 247 °CBoiling Point 0.970Specific Gravity (SG) 0.00Lbs VOC/Gallon Less Water 0.00Lbs VOC/Gallon Less Exempt SECTION 10. STABILITY and REACTIVITY Stable, Hazardous polymeraization will not occur. Will react with Epoxy Resins especially at elevated temperatures STABLE Epoxy Resins under uncontrolled conditions. Mineral acids. Organic acid, oxidixers, Reacts with metals until reacted with epoxy. None known Hazardous polymerization will not occur. SECTION 11. TOXICOLOGICAL INFORMATION Mixture Toxicity Oral Toxicity LD50: 8mg/kg Dermal Toxicity LD50: 3,216mg/kg Inhalation Toxicity LC50: 2,901mg/L Component Toxicity 98-54-4 Paratertiarybutylphenol SDS for: PICOTE MASTIC CATALYST Page 3 of 537 Oral LD50: 3,250 µL/kg (Rat) Dermal LD50: 2,318 mg/kg (Rabbit) 1477-55-0 Amine Oral LD50: 660 mg/kg (Rat) Dermal LD50: 2 g/kg (Rabbit) Inhalation LC50: 700 ppm (Rat) 84852-15-3 nonyl phenol Oral LD50: 1,300 mg/kg (Rat) Dermal LD50: 2,031 mg/kg (Rabbit) Eyes: Irritant to the eyes. Corrosive to Eyes Skin: Irritant to the skin. Corrosive to Skin Inhalation: Irritant to respiratory tract. Prolonged or excessive inhalation may cause respiratory tract irritation. Sensitization: Skin sensitization in humans. Eyes Kidneys Liver Skin Respiratory System Effects of Overexposure Carcinogen RatingCAS Number Description % Weight SECTION 12. ECOLOGICAL INFORMATION No ecotoxicity data was found for the product Component Ecotoxicity Paratertiarybutylphenol 96 Hr LC50 Pimephales promelas: 4.71 - 5.62 mg/L [flow-through]; 96 Hr LC50 Cyprinus carpio: 6.9 mg/L [static] 48 Hr EC50 Daphnia magna: 3.9 mg/L; 48 Hr EC50 Daphnia magna: 3.4 - 4.5 mg/L [Static] 72 Hr EC50 Desmodesmus subspicatus: 11.2 mg/L nonyl phenol 96 Hr LC50 Pimephales promelas: 0.135 mg/L [flow-through]; 96 Hr LC50 Lepomis macrochirus: 0.1351 mg/L [flow-through] 48 Hr EC50 Daphnia magna: 0.14 mg/L 96 Hr EC50 Pseudokirchneriella subcapitata: 0.36 - 0.48 mg/L [static]; 72 Hr EC50 Pseudokirchneriella subcapitata: 0.16 - 0.72 mg/L [static]; 72 Hr EC50 Desmodesmus subspicatus: 1.3 mg/L SECTION 13. DISPOSAL INFORMATION Dispose of in accordance with applicable local/municipal, state/provincial and federal regulations. SECTION 14. TRANSPORT INFORMATION UN2735 Amines, Liquid, corrosive, n.o.s. (Benzene-1,3-Dimethanamine,1,5-Pentanediamine, 2-Mthyl). DOT Hazad Class 8 DOT Packaging Class II Hazard ClassPacking GroupUN NumberProper Shipping NameAgency SECTION 15. REGULATORY INFORMATION OSHA:29 CFR 1910.1200 Haxardous Chemical "Irritant", Sensitizer TSCA: Ingredients listed SARA III: Sec311 & 312 Immediate Health Haxard; Sec313 Chemicals above de minimus level: None CA PROP. 65 NOTICE WARNING: CANADIAN REGULATORY INFORMATION WHMIS; Hazard Classification: D2B Skin Sensitizer. Refer to SDS for specific warnings WHMIS Symbols: Stylized T. WHMIS Trade Secret Registry Numbers: None SDS for: PICOTE MASTIC CATALYST Page 4 of 5 38 Hazardous Products Act Informtion: This product SDS contains ingredients which are Controlled and/or on the Ingredient Disclosure List (HPA sections 13 and 14). The following chemicals are classified under SARA 313 Toxic Release Invetnory (TRI): 84852-15-3 nonyl phenol 1 to 5 % All Components ListedRegulationCountry Toxic Substance Control Act (TSCA)Yes EU Risk Phrases Safety Phrase - None SECTION 16. ADDITIONAL INFORMATION Hazardous Material Information System (HMIS)National Fire Protection Association (NFPA) HMIS & NFPA Hazard Rating Legend * = Chronic Health Hazard 0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH Special Instability Flammability Health 0 0 0 0 0 0 Reviewer Revision Date revised: 2017-01-31 Date Prepared: 1/31/2017 SDS for: PICOTE MASTIC CATALYST Page 5 of 539 SECTION 1 . INDENTIFICATION Product Name: FIBER BONDED EPOXY MASTIC PART A Product Code: PICOTE MASTIC PICOTE SOLUTIONS 20810 SE 18TH PL SAMMAMISH, WA 98075 PHONE 800-535-5053 EMERGENCY: INFOTRAC SECTION 2. HAZARD(S) IDENTIFICATION GHS Ratings: Carcinogen 2 Limited evidence of human or animal carcinogenicity GHS Hazards H351 Suspected of causing cancer GHS Precautions P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood P281 Use personal protective equipment as required P308+P313 IF exposed or concerned: Get medical advice/attention P405 Store locked up P501 Dispose of contents/container to … Signal Word: Warning Avoid breathing vapors Oral: N.D.A. Dermal: N.D.A. Inhalation: N.D.A. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS number Weight Concentration % Epoxy Resin 25085-99-8 74.70% Barium Sulfate 7727-43-7 10.00% - 20.00% Silica 67762-90-7 1.00% - 5.00% Titanium Dioxide 13463-67-7 1.00% - 5.00% SECTION 4. FIRST AID MEASURES If inhaled remove to fresh air. If breathing is difficult, give oxygen. Obtain medical advice if there are persistent symptons Rinse immediately with plenty of water for at least 15 minutes. Ensure adequate flushing of the eyes by separating the eyelids with fingers. Remove contacts if present and easy to do. Continue Rinsing. Get medical attention, if irritation or symptoms of overexposure persists. Immediately wash skin with soap and plenty of water. If swallowed, call a physician immediately. Only induce vomiting at the instruction of a physician. Never give anything by mouth to an unconscious person SDS for: PICOTE MASTIC Page 1 of 440 SECTION 5. FIRE FIGHTING MEASURES Flash Point: N/A LEL: UEL: Not applicable Foam, Carbon dioxide (CO2) or dry chemical or water spray (water stream may be ineffective). No information available Not available Firefighters, and others exposed, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Stop leak. Dike or contain spill. Pump into slavage tanks and/or absorb with suitable material. Use sparkless shovel to remove material. Evacuate area and keep unnecessary and unprotected personnel from entering the spill area. Use appropriate containment and clean up immediately. Corrosive. Avoid personal contact adn breathing vapor or mist. Stop leak, Dike and contain spill.Prevent spilled material from entering the ground, water and/or air by using appropriate containment methods. SECTION 7. HANDLING and STORAGE Avoid breathing vapor. Avoid contact with eyes, skin and clothing. Keep away from heat and flame. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. Avoid exposure to heat, light, and air for prolonged periods of time. Store in a cool, dry well ventilated area away from sources of heat and incompatable materials. Eliminate all ignition materials and incompatible materials. Collect spill with non spark tools. No information available. SECTION 8.EXPOSURE CONTROLS, PERSONAL PROTECTION Other Exposure LimitsACGIH Exposure LimitsOSHA Exposure LimitsChemical Name / CAS No. Epoxy Resin 25085-99-8 Not EstablishedNot Established Not Established Barium Sulfate 7727-43-7 5 mg/m3 TWA (inhalable fraction, particulate matter containing no asbestos and <1% crystalline silica) 15 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) NIOSH: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable dust) Silica 67762-90-7 Not EstablishedNot Established Not Established Titanium Dioxide 13463-67-7 10 mg/m3 TWA15 mg/m3 TWA (total dust)Not Established Use appropriate engineering control such as process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Good general ventilation should be sufficiant to control airborne levels. Where such systems are not effective wear suitable personal protective equipment, which preforms satisfactory and meets OSHA or other recgonized standards. Consult with local procedures for selection, training, and maintenance of the personal protective equipment Always use adaquate ventilation that comply with local regulations. Eye/face Protection: Wear appropriate protective glasses or splash goggles as described by 29 CFR 1910.133, OSHA eye and face rotection reulation, or the Europena standard EN 166 Skin Protection: Chemical-resistant gloves and chemical goggles, face-shield and synthetic apron or coveralls should be used to prevent contact with eyes, skin or clothing. Respiratory Protection: A NIOSH air purifying respirator with an organic vapor cartridge or canister may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by air purifying respirators is limited. Use a positive presure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known or any other circumstance where air purifyig respirator may not provide adequate protection. SECTION 9. PHYSICAL and CHEMICAL PROPERTIES SDS for: PICOTE MASTIC Page 2 of 441 2500 to 3000 °CBoiling Range 1.398Specific Gravity (SG) 0.00Lbs VOC/Gallon Less Water 0.00Lbs VOC/Gallon Less Exempt SECTION 10. STABILITY and REACTIVITY Stable, Hazardous polymeraization will not occur. Will react with Epoxy Resins especially at elevated temperatures STABLE Epoxy Resins under uncontrolled conditions. Mineral acids. Organic acid, oxidixers, Reacts with metals until reacted with epoxy. Nitrogen oxides and other toxic and acidic gasses when burned. None known Hazardous polymerization will not occur. SECTION 11. TOXICOLOGICAL INFORMATION Mixture Toxicity Component Toxicity Eyes: Irritant to the eyes. Corrosive to Eyes Skin: Irritant to the skin. Corrosive to Skin Inhalation: Irritant to respiratory tract. Prolonged or excessive inhalation may cause respiratory tract irritation. Sensitization: Skin sensitization in humans. Eyes Respiratory System Effects of Overexposure Carcinogen RatingCAS Number Description % Weight Titanium Dioxide: NIOSH: potential occupational carcinogen IARC: Possible human carcinogen OSHA: listed 13463-67-7 Titanium Dioxide 1 to 5% SECTION 12. ECOLOGICAL INFORMATION No ecotoxicity data was found for the product Component Ecotoxicity SECTION 13. DISPOSAL INFORMATION Dispose of in accordance with applicable local/municipal, state/provincial and federal regulations. SECTION 14. TRANSPORT INFORMATION UN2735 Amines, Liquid, corrosive, n.o.s. (Benzene-1,3-Dimethanamine,1,5-Pentanediamine, 2-Mthyl). DOT Hazad Class 8 DOT Packaging Class II Hazard ClassPacking GroupUN NumberProper Shipping NameAgency SDS for: PICOTE MASTIC Page 3 of 442 SECTION 15. REGULATORY INFORMATION OSHA:29 CFR 1910.1200 Haxardous Chemical "Irritant", Sensitizer TSCA: Ingredients listed SARA III: Sec311 & 312 Immediate Health Haxard; Sec313 Chemicals above de minimus level: None CA PROP. 65 NOTICE WARNING: CANADIAN REGULATORY INFORMATION WHMIS; Hazard Classification: D2B Skin Sensitizer. Refer to SDS for specific warnings WHMIS Symbols: Stylized T. WHMIS Trade Secret Registry Numbers: None Hazardous Products Act Informtion: This product SDS contains ingredients which are Controlled and/or on the Ingredient Disclosure List (HPA sections 13 and 14). State of California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): WARNING! This product contains the following chemicals which are listed by the State of California as carcinogenic or a reproductive toxin: 13463-67-7 Titanium Dioxide 1 to 5 % Carcinogen All Components ListedRegulationCountry Toxic Substance Control Act (TSCA)Yes EU Risk Phrases Safety Phrase - None SECTION 16. ADDITIONAL INFORMATION Hazardous Material Information System (HMIS)National Fire Protection Association (NFPA) HMIS & NFPA Hazard Rating Legend * = Chronic Health Hazard 0 = INSIGNIFICANT 1 = SLIGHT 2 = MODERATE 3 = HIGH Special Instability Flammability Health 0 0 0 0 0 0 Reviewer Revision Date revised: 2017-01-31 Date Prepared: 1/31/2017 SDS for: PICOTE MASTIC Page 4 of 443