275 Sherry Dr soil testing report STOP WORK
CITY OF ATLANTIC BEACH
BUILDING AND ZONING DEPARTMENT (904)247-5826
NOTICE
This building has been inspected and:
P�`6General Construction ❑ Mechanical
❑ Concrete and Masonry ❑ Electrical
❑ Plumbing ❑ Gas Piping
IS NOT ACCEPTED
CORRECT AS NOTED BELOW, BEFORE ANY FURTHER WORK
L f vt� 1
06- T
ADDRESS: _ -2--j
DO NOT REMOVE THIS NOTICE
Inspector: �-t z�, ,� �, I—� 1 Date: v i( 2 S t 1
Failure to respond to this Notice within 10 days will result in this violation being
forwarded to the
CODE ENFORCEMENT BOARD.
The posting of this Placard by its contents shall serve as due notice.
PROJECT NO.: 17-2090
LEGACY REPORT1
LAB NO.:: 1-1000
ENGINEERING, INC DATE: 2/92017
Geotechnical d Materials Engineering and Testing
REPORT OF: Chemical Testing of Existing Soils
PROJECT: 275 Sherry Drive-Atlantic Beach,Florida
CONTRACTOR: Pinnacle Homes Corporation
CLIENT: Pinnacle Homes Corporation
Attn: Mr.Tim Quinn
265 Edge of Woods Road
St.Augustine,FL 32092
SAMPLE LOCATION: House Pad Area-275 Sherry Drive
DATE SAMPLED: February 1,2017
On February 1, 2017, a bulk sample of the soils from the subject building areas was sampled and
delivered to ALS Environmental by our laboratory for chemical analysis and testing to determine if the
existing soils contain fuels and/or fuel/oil contaminants. This report presents the results of the testing
performed.
A bulk sample of the soils was taken in the vicinity of where a previous existing buried fuel tank was
located on the site. The testing performed on the soils included testing for volatile organic compounds,
semi-volatile organic compounds and the FL-Pro (C8 - C40) series. The full test report with results is /
attached for view i_/
The results of the testing performed(when compered to[he State of Florida Soil Cleanup Target Levels)
indicate[hat the soils do not contain any significant levels of fuels or fueVoil contaminants which would
require removal and/or remediation.
Thank you again for allowing Legacy Engineering,Inc.the opportunity to provide testing services for this
project. If you should have any questions regarding this report or its contents,please contact us.
Respectfully submitted:
LEGACY ENGINEERRT"
j ...........•V�GE •...�iP
No.45202 �z
Jo Itis,H,PAL It
Licensed,FL No.43207 STATE OF '2
JEE/meg az%9�F F�OF21OP'� ;�
w/attachments
2cc:client """•""
LEGACY ENGINEERING,INC.
6424 Beach Boulevard - Jacksonville,Florida 32216
Phone:904.721.1100 FAX:904.722.1100
*AL
February 08, 2017 Service Request No:J17OO812
John Ellis II
Legacy Engineering
6424 Beach Blvd
Jacksonville, FL 32216
Laboratory Results for: 275 Sherry Dr
Dear John,
Enclosed are the results of the samples) submitted to our laboratory February 01, 2017
For your reference, these analyses have been assigned our service request number.117OO812.
All analyses were performed according to our laboratory's quality assurance program. The test
results meet requirements of the NELAP standards except as noted in the case narrative report.
All results are intended to be considered in their entirety, and ALS Environmental is not responsible
for use of less than the complete report. Results apply only to the items
submitted to the laboratory for analysis and individual items (samples) analyzed, as listed in the
report. In accordance to the NELAC 2003 Standard, a statement on the estimated uncertainty of
measurement of any quantitative analysis will be supplied upon request.
Please contact me if you have any questions. My extension is 4410. You may also contact me via
email at Jerry.Allen@alsglobal.com.
Respectfully submitted,
ALS Group USA, Corp. dba ALS Environmental
Jerry Allen
Project Manager
ADDRESS 9143 Philips Hi9hxay,Sus,200,Jac "W.FL 32255
PHONE +1904739221)1 FAX 119047392011
AlSG—PUSA,Com,
ELe ALS Erv.hal
Page ] of 37
ALS Environmental
ALS Group USA, Corp
9143 Philips Highway, Suite 200
Jacksonville, FL 32256
T: +1 904 739 2277
A L 5
F: +1 904 739 2011
www.alsglobal.com
Table of Contents
CoverLetter 1
Table of Contents 2
Narrative Documents 4
Narrative Documents 5
Hit Summary List 6
Sample Receipt Information 7
Sample Cross-Reference 8
Chain Of Custody 9
Miscellaneous Forms 11
Qualifiers 12
Acronyms 14
Analyst Summary 15
Sample Results 16
Volatile Organic Compounds by GCMS 17
8260B-Volatile Organic Compounds by GC/MS
House Pad -VolatileOrganic 18
Semivolatile Organic Compounds by GCMS 19
8270D SIM - Base Neutral Semivolatile Organic Compounds by GC/MS SIM
House Pad - Semivoa GCMS 20
Semivolatile Organic Compounds by GC 21
FL-PRO - Petroleum-Range Organics by GC-FID for State of Florida
House Pad - Semivoa GC 22
RIGHT SOLUTIONS I RIGHT PARTNER
Page 2 of 37
Table of Contents (continued)
QC Summary Forms 23
Volatile Organic Compounds by GCMS 24
8260B -Volatile Organic Compounds by GC/MS
VolatileOrganic Surrogate Summary 25
Method Blank-VolatileOrganic 27
JQ1700963-02 - DLCS VolatileOrganic 28
Semivolatile Organic Compounds by GCMS 29
8270D SIM - Base Neutral Semivolatile Organic Compounds by GUMS SIM
Semivoa GCMS Surrogate Summary 30
JQ1700922-04 House Pad - DMS Semivoa GCMS 31
Method Blank- Semivoa GCMS 32
JQ1700922-02 - LCS Semivoa GCMS 33
Semivolatile Organic Compounds by GC 34
FL-PRO -Petroleum-Range Organics by GC-FID for State of Florida
Semivoa GC Surrogate Summary 35
Method Blank- Semivoa GC 36
JQ1700920-06 - DLCS Semivoa GC 37
Page 3 of 37
AlEnuironmental
Aarrative Documents
ALS Environmental—Jacksonville Laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904) 739-2277 Fax (904) 739-2011
www.alsglobal.com
RIGHTSOLUTIONS RIGHT PARTNER
Page 4 of 37
AlEnuironmental 9103 Philips Highway,Suite 200,Jacksonville,FL 32E56 I 5(tC.739-2277 1 www.alsglobal.com
Client: Legacy Engineering Service Request:J1700812
Project: 275 Sherry Or Date Received:2/1/17
Sample Matrix: Soil
CASE NARRATIVE
All analyses were performed consistent with the quality assurance program of ALS Environmental.This report contains analytical
results for samples designated for Tier II data deliverables, including results of QC samples analyzed from this delivery group.
When appropriate to the procedure, method blank results have been reported with each analytical test.Analytical procedures
performed by the lab are validated in accordance with NELAC standards. Parameters that are included in the NELAC Fields of
Testing but are not included in the lab's NELAC accreditation are identified in the discussion of each analytical procedure.
Sample Receipt
One soil sample was received for analysis at ALS Environmental on 2/1/2017.The samples were received in good condition and
consistent with the accompanying chain of custody form. Samples are refrigerated at<6°C upon receipt at the lab except for
aqueous samples designated for metals analyses,which are stored at room temperature.
Volatile Omanic Analyses:
No significant data anomalies were noted with this analysis.
Semi-Volatile Omanic Analyses:
Method 8270D SIM: The Method Blank JO1700922-01 contained low levels of compound benzo(ghi)perylene above the Method
Reporting Limit(MRL).The concentration of this analyte in the associated sample is greater than 10x that in the MB. No further
action was taken.
General Chemistry Analyses:
No significant data anomalies were noted with this analysis.
Approved by —'�--- Date 2/82017
Page 5 of 37
ALS
SAMPLE DETECTION SUMMARY
LIENT ID: House Pad Lab ID:J1700812-001
Analyte Results Flag MDL POL Units Method
_....... ....__ .........
rn j-Xylenes 0.287 1 0.252 12.0 ug/Kg 82608
Toluene 8.07 0.323 5.98 ug/Kg 8260B
Acenaphthylene 32.2 1 22.3 68.8 ug/Kg 8270D SIM
Anthracene 41.4 16.2 34.4 ug/Kg 8270D SIM
Benz(a)anthramne 76.5 19.3 34.4 ug/Kg 8270D SIM
Senzo(a)pyrene 45.8 10.2 34.4 ug/Kg 8270D SIM
Benzo(b)fluoranthene 126 20.3 34.4 ug/Kg 8270D SIM
Senzo(g,h,i)perylene 56.5 22.3 34.4 ug/Kg 8270D SIM
Senzo(k)fluoranthene 56.4 24.3 34.4 ug/Kg 8270D SIM
Chrysene 83.9 19.3 34.4 ug/Kg 8270D SIM
Fluoranthene 99.7 20.3 34.4 ug/Kg 8270D SIM
Indeno(1,2,3-cd)pyrene 47.1 22.3 34.4 ug/Kg 8270D SIM
Pyrene 143 20.3 34.4 ug/Kg 8270D SIM
FL-PRO(C8-C40) 27.6 2.00 2.01 mg/Kg FL-PRO
Page 6 of 37
AlEnutronmental
'Sampie Receipt • •
ALS Environmental—Jacksonville Laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904) 739-2277 Fax (904) 739-2011
www.alsglobal.com
RIGHT SOLUTIONS RIGHT PARTNER
Page 7 of 37
Client: Legacy Engineering Service RequestJ1700812
Project: 275 Sherry Or
SAMPLE CROSS-REFERENCE
SAMPLE# CLIENT SAMPLE ID DATE TIME
J1700812-001 House Pad 2/1/2017 1400
Printed 2182017006:18PM Page 8 of 37 Sample Summary
Cooler Receipt Form
Client: Lp^yc.r.K,C Service Request#:
Project: (DA, O Shipping paid by ALS?
Cooler received on and opened on.1 //h by Yes No N/A
COURIER: ALS UPS FEDEX DH Clien Other Airbill#
1 Were custody seals on outside of cooler? Yes No
If yes,how many and where? n:_ on lid other
2 Were seals intact and signature and date correct? Yea No Z :)
3 Were custody papers properly filled out? Yes No NIA
4 Temperature ofcooler(s)upon receipt fshoaldbeo°Caod<6°C) 01q( _ _ _
5 Thermometer ID T12-Y _ _ _
6 Temperature Blank Present? Yes No
7 Were Ice or Ice Packs present <ce Ice Packs No
8 Did all bottles arrive in good condition(unbroken,etc....)? Yes No N/A
9 Type of packing material present Netting Vial HalderblrWW-
P r Styrofoam Other N/A
10 Were all bottle labels complete(sample ID,preservation,etc....)? No NIA
I I Did all bottle labels and tags agree with custody papers? Yes No N/A
12 Were the correct bottles used for the tests indicated? Yes No N/A
13 Were all of the preserved boules received with the appropriate preservative? Yes No /A
HNO3 pH<2 H2SO4 pHQ ZMc2/NaOH pH>9 NEOH pl4>I2 HCI PH<2
i,ew.ie+damons r beb
14 Were all samples received within analysis holding times? clvasp No N/A
15 Were VOA vials Gee ofair bubbles greater than(mm?Ifpresenl,note below Yes No N/A `
16 Where did the bottles originate? LS - Cliem
Sample ID eagent Lot# ml added Initials Dateflime
Additional comments and/or explanation of all discrepancies noted above:
Client approval to run samples if discrepancies noted: Dale:
SMF-I
Cooler Receipt Form APF48#7 12/6/2016
Ln
awm- !
cm \
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0 °
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§ \ | ( �
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AlEnuironmental
Miscellaneous •
ALS Environmental—Jacksonville Laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904) 739-2277 Fax (904) 739-2011
www.alsglobal.com
RIGHi-SOLUTIONS RIGHT PARTNER
Page 11 of 37
ALS Enuirnnmental
FLORIDA DEP DATA QUALIFIERS
B Results based upon colony cowls outside the acceptable range.
D Measurement was made in the field.
N Value based on field kit detemtination;results may not be accurate.
I The reported value is between the laboratory method detection limit and the laboratory practical
quantitation limit.
1 Estimated value(one ofthe following reasons is discussed in the project case narrative).
1. The result may be inaccurate because the surrogate recovery limits have been exceeded
2. No known quality control criteria exists for the component.
3. The reported value failed to meet the established quality control criteria for either precision or
accuracy.
4. The sample matrix interfered with the ability to make any accurate determination(e.g.,
primary and confirmation results show greater than 40%RPD).
5. The data is questionable because of improper laboratory or field protocols(e.g.,GUMS Time
did not meet method criteria).
K Off scale low. The value is less than the lowest calibration standard but greater than the method
reporting limit(MRL).
L Offscale high. The analyte is above the upper limit ofthe linear calibration range.
M The MDL/MRL has been elevated because the analyte could not be accurately quantified due to
matrix interference.
N Presumptive evidence ofthe analyte. Confirmation wav not performed.
Q Sample held beyond the accepted holding time.
T Value reported is less than the laboratory method detection limit. The value is reported for
informational purposes only.
U Indicates that the compound was analyzed for but not detected.
V Indicates that the analyte was detected in both the sample and the associated method blank.
Y The laboratory analysis was from an improperly preserved sample.
Z Too many colonies were present(TNTC). The numeric value represents the filtration volume.
Page 12 of 37
ALS Enuironmental
a> waaoe
�C
V�a
Jackt.rfu le Lab ID#for Staff Ceriifications'
Amu Number EK intlon Daft
De nt ofDe4nse 66206 7/312018
FlorideO ntmnt of Henld E825m 4ZtMON
Gmrgias Department ofNamN 958 6002017
Resources
Kentucky Division ofWasm 63 6000017
M.,..t
Iuuint—D,toorrentof 02086 61302017
Envi menml Qurtlitt
Maim DePmtuantoffleollhend m150M 2/32017
Human Sv
NOM Caroli-Demorent of 527 IWIV 17
Euvirome,ntand Nammllk me
Peimsylvanin Deparlownt of 68-04835 &312017
Enwrometeal Promlion
South Carolim Depenment of Halts 96m1001 OVIM017
and Environmrml Co..)
Tcau Cammissiun on Eovianmmml TIOq]04197-16-8 5012017
Qtral't,
V,inia Envi..W Aermiefian 060191 INIC2017
Pro
'Analyses were erformal according m our labomory's NELAP-approvW gm4ty msuraue,Memo and anyapplic,ble mor or
a Bencyrequimamis. The test resettle meet requiearenb of m current NELAPIfNI smndmds a amte or agmcy
ranalm ,refrw blue
.a mutl.ct enVurelabommryc Imrntiveprovided. ntQ,a,l2ad louhAmore
nalyms,rererto /hvww.ehlobal.c ceslowd menet sets uh-
p w�nl a�da
Page 13 of 37
ALS encnronmentat
ACRONYMS
ASTM American Society for Testing and Materials
A2LA American Association for Laboratory Accreditation
CARB Califomia Air Resources Board
CAS Number Chemical Abstract Service registry Number
CFC Chlomflumocarbon
CFU Colony-Forming Unit
DEC Department ofEnvironmemal Conservation
DEQ Department of Environmental Quality
DHS Deporhcent ofHcalth Services
DOE Department of Ecology
DOH Department of Health
EPA U.S.Environmental Protection Agency
FLAP Environmental Laboratory Accreditation Program
GC Gas Chromatography
GUMS Gas Chromatogmphy/Mass Spectrometry
LUFT Leaking Underground Fuel Tank
M Modified
MCL Maximum Contentment Level is the highest permissible concentration of a substance allowed in
drinking water as established by the USEPA.
MDL Method Detection Limit
MPN Most Probable Number
MRL Method Reporting Limit
NA Not Applicable
NC Not Calculated
NCASI National Council of the Paper Industry for Air and Stream Improvement
ND Not Detected
NIOSH National Institum for Ocmpalional Safety and Health
PQL Practical Quantitation Limit
RCRA Resource Conservation and Recovery Act
SIM Selected Ion Monitoring
TPH Total Petroleum Hydrocarbons
tr Trace level is the concentration of an analyte(hat is less than the PQL but greater than or equal to the
MDL.
Page 14 of 37
ALS Group USA,Corp.
db.AIS Eoviroomemal
Analyst Summary report
Client: Legacy Engineering Service Request 11700812
Project: 275 Sherry Dr
Sample Name: House Pad Date Collected: 02/1/17
Lab Code: 11700812-001 Dale Received: 02/1/17
Sample Matrix: Soil
Analysis Method Extracted/Digested By Analyzed By
82608 SALLEN SALLEN
8270D SIM KHALBERT SWOOD
FL-PRO KHALBERT NHOWARD
Printed WM174:0620PM Superset Refemme:17-WolulIN83 rev lq
Page 15 of 37
AlEnuironmentall
SampleResults
ALS Environmental—Jacksonville Laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904) 739-2277 Fax (904) 739-2011
www.alsglobal.com
RIGHT SOLUTIONS RIGHT PARTNER
Page 16 of 37
AlEnuironmental
Volatile Organic Compounds by GC/MS
ALS Environmental—Jacksonville Laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904)739-2277 Fax (904)739-2011
www.alsglobal.com
RIGHT SOLUTIONS i RIGHT PARTNER
Page 17 of 37
ALS Group USA,Corp.
db.ALS ErAronnnntd
Analytical Report
Client: Legacy Engineering Service Request: 11700812
Project: 275 Sherry Dr Date Collected: 02/01/17 14:00
Sample Matrix: Soil Dale Received: 02/01/17 16:20
Sample Name: House Pad Units: ug/Kg
Lab Code: 11700812-001 Basis: Adjustment Factor
Volatile Organic Compounds by GC/MS
Analysis Method: 82608
Prep Method: EPA 5035
Analyte Name Result PQL MDL DR. Date Analyzed Date Extracted Q
Benzene 0.204 U 5.98 0.204 1 02/06/1720:27 2/6/17
Ethylbenzene 0.144 U 5.98 0.144 1 02/06/1720:27 2/6/17
m,p-Xylenes 02871 12.0 0.252 1 02/06/1720:27 2/6/17
Methyl tert-Butyl Ether 0.312 U 5.98 0.312 1 02/06/1720:27 2/6/17
o-X leve 0.192 U 5.98 0.192 1 02/06/1720:27 2/6/17
Toluene 8.07 1 20:27 2/6/17
Surrogate Name %Rec Con[rol Lim its Dale Andyyzzeeda Q
1,2-Dichlomethano-d4 1 - iU� 77 LU:L
4-Bromofluorobenzene 99 64- 135 02/06/17 20:27
Dibromofluoromethane 111 74- 125 02/06/17 20:27
Toluene-d8 117 46- 156 02/06/17 20:27
Pdnnd 2M0174:06:21 PM Superset Reference:l 7-0000410083 m 00
Page 18 of 37
AlEnuironmental
• ,
ALS Environmental—Jacksonville laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904)739-2277 Fax (904)739-2011
www.alsglobal.com
RIGHT SOLUTIONS RICHT PARTNER
Page 19 of 37
ALS Group USA,Corp.
dba AlSEsA.m W.l
Analytical Repon
Client: Legacy Engineering Service Request: /1700812
Project: 275 Sherry Dr Date Collected: 02/01/17 14:00
Sample Matrix: Soil Date Received: 02/01/1716:20
Sample Name: House Pad Units: ug/Kg
Lab Code: 11700812-001 Basis: Adjustment Factor
Base Neutral Semivolatile Organic Compounds by GC/MS SIM
Analysis Method: 8270D SIM
Prep Method: EPA 3546
Analyte Name Result PQL MDL Dib Date Analyzed Date Extracted Q
I-Methylnaphthalene 27A U 34.4 27A 10 02/07/1701:26 2/6/17
2-Methy1naphthalene 23.3 U 34.4 233 10 02/07/1701:26 2/6/17
Acenapbthene 31A U 68.8 31.4 10 02/07/1701:26 2/6/17
Acenaphthylene 32.21 68.8 22.3 10 02/07/1701:26 2/6/17
Anthracene 41.4 34.4 16.2 10 02/07/1701:26 2/6/17
Benz(a)anthracene fo.D 34.4 1
Benzo(a)pyrene 45.8 34.4 10.2 10 02/07/1701:26 2/6/17
Benzo(b)fluomnthene 126 34.4 20.3 10 02/07/1701:26 2/6/17
Benzo(g,h,i)perylene 56.5 34.4 22.3 10 02/07/1701:26 2/6/17
Benzo(k)fluomnthene 56.4 34.4 24.3 10 02/07/1701:26 2/6/17
Chrysene 83.9 34.4 19.3 10 02/07/17 01:26 2/6/17
Dibenz(a,h)anthrecene 27.4 U 34.4 27.4 10 02/07/1701:26 2/6/17
Fluoranthene ".7 34.4 20.3 10 02/07/1701:26 2/6/17
Fluorene 223 U 34.4 22.3 10 02/07/1701:26 2/6/17
Indeno(L2,3-cd)pyrene 47.1 34.4 22.3 10 02/07/1701:26 2/6/17
Naphthalene 31.4 U 34.4 31a 10 02/07�2'f/6/17
Phenanthrene 17.3 U 68.8 17.3 10 02/07/1701:26 2/6/17
Pyrene 143 34.4 20.3 10 02/07/1701:26 2/6/17
Surrogate Name %Ree Control Limits Date Analyzed Q
2-Fluorobiphenyl 47 _ 118
02 07 17 01:26
p-Terphenyl-d14 80 41 - 146 02/07/1701:26
Nntcd VOW 74:06 32 PM &i,s, ct Rctcn,a 17-0000410083 rev 00
Page 20 of 37
AlEnuironmental
-)emivolatile Organic Compounds by GC
ALS Environmental—Jacksonville Laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904)739-2277 Fax (904)739-2011
www.alsglobal.conn
RIGHT SOLUTIONS RIGHT PARTNER
Page 21 of 37
ALS Group USA,Corp.
dba AIS Emmironn ental
Analytical Report
Client: Legacy Engineering Service Request: 11700812
Project: 275 Sherry Or Date Collected: 02/01/1714:00
Sample Matrix: Soil - Date Received: 02/01/17 16:20
Sample Name: House Pad Units: mg/Kg
Lab Code: 11700812-001 Basis: Adjustment Factor
Petroleum-Range Organics by GC-FID for State of Florida
Analysis Method: FL-PRO
Prep Method: EPA 3546
Analyte Name Result PQL MDL Dil. Dale Analyzed Date Extracted Q
FL-PRO(C8-C40) 27.6 2.01 2.00 1 02/06/17 20:06 2/6/17
Surrogate Name %Ree Control Limits Date Analyzed Q
o-Terphenyl 73 62-109 0606 17
n-Nonatriacontane 76 60- 118 02/06/17 20:06
Printed Y820174 Nb PM Superset Reference'.17-0000410083 rev 00
Page 22 of 37
AlEnuironmental
FormsQC Summary
ALS Environmental-Jacksonville Laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904) 739-2277 Fax (904) 739-2011
www.alsglobal.com
RIGHT SOLUTIONS RIGHT- PARTNER
Page 23 of 37
AEnuironmental
VolatHe Organic • • • •
ALS Environmental—Jacksonville Laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904)739-2277 Fax (904)739-2011
www.alsglobal.com
RIGHTSOLUFIONS RIGHTPARTNER
Page 24 of 37
ALS Group USA,Corp.
dba AIS Emhromne mal
QNQC Report
Client: Legacy Engineering Service Request: /1700812
Project: 275 Sherry Dr
Sample Matrix: Soil
SURROGATE RECOVERY SUMMARY
Volatile Organic Compounds by GCJMS
Analysis Method: 8260B
Extraction Method: EPA 5035
1,2-Dnh1oroethaoe-d4 4-11mmofluorobenzene mbromo0uorome@ane
Sample Name Lab Code 80-120 64-135 74-125
House Pad 11700812-001 114 99 111
Lab Control Sample JQ1700963-01 97 103 98
Duplicate Lab Control Sample JQ1700963-02 99 101 99
Method Blank JQ1700963-03 109 91 108
Mimed 2B 017406:221`1,1 Page 25 of 37 sove..e Rdere-11-OM410083 moo
ALS Group USA,Corp.
dh ALS Environmental
QAIQC Report
Client: Legacy Engineering Service Request: 11700812
Project: 275 Sherry Or
Sample Matrix: Soil
SURROGATE RECOVERY SUMMARY
Volatile Organic Compounds by GC/MS
Analysis Method: 8260B
Extraction Method: EPA 5035
Toluencd9
Sample Name Lab Code 46-156
House Pad 11700812-001 117
Lab Control Sample JQ1700963-01 115
Duplicate Lab Control Sample JQ1700963-02 117
Method Blank 1Q1700963-03 116
Primed l/820174:06:32 PM Page 26 of 37 S, .n Ref 11-000MINS3re.oo
ALS Group USA,Corp.
dba AIS E.A...emal
Analytical Repou
Client: Legacy Engineering Service Request: /1700812
Project: 275 Sherry Dr Date Collected: NA
Sample Matrix: Soil Date Received: NA
Sample Name: Method Blank Units: ug/Kg
Lab Code: JQ1700963-03 Basis: Dry
Volatile Organic Compounds by GC/MS
Analysis Method: 8260B
Prep Method: EPA 5035
Analyte Name Result PQL MDL Dil. Date Analyzed Date Extracted Q
Benzene 0.170 U 5.00 0.170 1 02/06/1719:39 2/6/17
Ethylbenzene 0.120 U 5.00 0.120 1 02/06/17 19:39 216/17
m,p-Xylenes 0.210 U 10.0 0.210 1 02/06/17 19:39 2/6/17
Methyl tert-Butyl Ether 0.260 U 5.00 0.260 1 02/06/17 19:39 2/6/17
o-X lene 0.160 U 5.00 0.160 1 02/06/17 1939 2/6/17
Toluene 0.270 U 5.00 0.270 1 7 1
Surrogate Name %Rec Control Limits Dele Anal Q
1,2-Dichloroethane-d4 109 0- 1'f��liZlb plq' —
4-Bromofluorobenzene 91 64- 135 02/06/17 19:39
Dibromollumomethane 108 74- 125 02/06/17 19:39
Toluene-d8 116 46- 156 02/06/17 19:39
Printed 2/8/2017 4:06:22 PM Sup,nxt Refere 17-0000610083m00
Page 27 of 37
ALS Group USA,Corp.
4N AIS Enviroummbl
QA/QC Rcpon
Client: Legacy Engineering Service Request: 11700812
Project: 275 Shcny Dr Date Analysed: 02/06/17
Sample Matrix: Soil Date Extracted: 02/06/17
Duplicate Lab Control Sample Summary
Volatile Organic Compounds by GC/MS
Analysis Method: 8260B Units: ug/Kg
Prep Method: EPA 5035 Basis: Dry
Analysis Lot: 533722
Lab Control Sample Duplicate Lab Control Sample
JQ1700963-01 JQ1700963-02
%Bee
Analyte Name Result Spik A t %Rec Result Spike Amount %Rcc Limits RPD RPD Limit
Benzene 41.4 52.0 80 40.1 52.0 77 76-123 3 30
Ethylbenzene 52.3 52.0 101 50.3 52.0 97 71-122 4 30
m,p-Xylenes 111 104 107 106 104 102 71-122 5 30
Methyl tcrt-Butyl Ether 40.4 52.0 78 40.3 52.0 77 72-121 <1 30
0-X leve 54.2 52.0 104 52.5 52.0 101 71-120 3 30
Toluene 53.6 52.0 103 51.7 52.0 99 72-118 4 30
Printed 2/820174:06:22 PM Superset lock.,17-00004 IW83 m 00
Page 28 of 37
AiEnuironmental
,oSernivolatile Organic Compounds by GC/MS
ALS Environmental—Jacksonville laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904)739-2277 Fax (904)739-2011
www.als9lobal.com
RIGHT SOLUTIONS RIUH PARTNER
Page 29 of 37
ALS Group USA,Corp.
dbs AIS Eavimnmemal
QA1QC Repan
Client: Legacy Engineering Service Request: /1700812
Project: 275 Sherry Dr
Sample Matrix: Soil
SURROGATE RECOVERY SUMMARY
Base Neutral Semivolatile Organic Compounds by GCIMS SIM
Analysis Method: 8270D SIM
Extraction Method: EPA 3546
3-Fluembipbenyl p-Terphmyl-dH
Sample Name Lab Code 30-Iis 41-146
House Pad JI700812-001 47 80
Method Blank JQ1700922-01 60 70
Lab Control Sample JQ1700922-02 60 70
House Pad JQ1700922-03 45 176-
House Pad
76-
HousePad JQ1700922-04 60 181 .
Pnnkd 2=0174:0633PM Page 30 of37 Supmd aeremme:11-OOONIN83 mW
ALS Group USA,Corp.
dba ALS Epvio nmmtel
QA/QC Report
Client: Legacy Engineering Service Request: 11700812
Project: 275 Sherry Dr Date Collected: 02/01/17
Sample Matrix: Soil Date Received: 02/01/17
Date Analyzed: 02/7/17
Date Extracted: 02/6/17
Duplicate Matrix Spike Summary
Base Neutral Semivolatile Organic Compounds by GC/MS SIM
Sample Name: House Pad Units: ug/Kg
Lab Code: 11700812-001 Basis: Adjustment Factor
Missing
Analysis Method: 8270D SIM
Prep Method: EPA 3546
Matrix Spike Duplicate Matrix Spike
JQ1700922-03 JQ1700922-04
Sample Spike Spike %Rep RPD
A Ivt N Res It Result Amount a/p Rce Result Amount %Rce Limits RPD Limit
1-Methylnaphthalene 27.4U 33.0 67.5 49 46.9 66.8 70 32-101 35 30
2-Methylnaphthalene 23.3 U 30.1 67.5 45 46.0 66.8 69 32-103 42* 30
Acenaphthene 31.4U 37.9 67.5 56 94.9 66.8 142' 29-122 86* 30
Acenaphthylene 32.21 65.5 67.5 49 85.5 66.8 80 36-114 26 30
Anthracene 41.4 80.9 67.5 58 146 66.8 156- 36-135 57* 30
Benz(a)anthracene 76.5 167 67.5 133 221 66.8 2161 43-139 28 30
Benzo(a)pyrene 45.8 110 67.5 95 132 66.8 129' 43-127 18 30
Benm(b)fluoranthene 126 184 67.5 85 246 66.8 179* 49-139 29 30
Benzo(g,h,i)perylene 56.5 113 67.5 94 119 66.8 94 30-135 5 30
Benzo(k)fluoranthene 564 131 675 111 140 66.6 126 45-132 7 30
Chrysene 83.9 119 67.5 52 140 66.8 84 36-130 16 30
Dibenz(a,h)mthracene 27.4U 84.1 67.5 125 74.6 66.8 112 32-139 12 30
Fluonmhene 99.7 153 67.5 78 289 66.8 284* 42-127 62* 30
Fluorene 22.3U 40.3 67.5 60 70.6 66.8 106 41-118 55* 30
Indenc,(1,2,3-cd)pyrcne 471 103675 82 113 66.8 99 32-133 10 30
Naphthalene 31.4 U 31.4 67.5 37 42.6 66.8 64 29-107 NC 30
Phenanthrene 17.3 U 60.1 67.5 89 219 66.8 327* 34-130 114* 30
Pyrene 143 208 67.5 96 360 66.8 325 * 45-118 54* 30
aeum a...W alts.. ebbs l•)i^dime-...uonide-.1 eraed..
W,i s Monica wiM a Po.^d(f)indicate Me eomrai criteria is lie,applicable.
P--,recd H.and re6me pereem aflaea-(RPD)are dear-e,1b,IM1e Ra_ i,values in Me celculnion which have..bem rowded.
Printed VM017406'.32 PM Superset Ref me:17-0000110083 m 00
Page 31 of 37
ALS Group USA,Corp.
dba ALS Eevimemeetal
Analytical Ocpon
Client: Legacy Engineering Service Request: /1700812
Project 275 Sherry Dr Date Collected: NA
Sample Matrix: Soil Date Received: NA
Sample Name: Method Blank Units: ug/Kg
Lab Code: JQ1700922-01 Basis: Dry
Base Neutral Semivolatile Organic Compounds by GC/MS SIM
Analysis Method: 8270D SIM
Prep Method: EPA 3546
Ansly-te Name Result PQL MDL Dil. Date Analyzed Date Extracted Q
I-Methylnaphthalene 2.70 U 3.40 2.70 1 02/07/1701:02 2/6/17
2-Methylnaphthalene 2.30 U 3.40 2.30 1 02/07/1701:02 2/6/17
Acenaphthene 3.10 U 6.80 3.10 1 02/07/1701:02 2/6/17
Acenaphthylene 2.20 U 6.80 2.20 1 02/07/1701:02 716/17
Anthracene 1.60 U 3.40 1.60 1 02/07/1701:02 2/6/17
Benz(a)anthmcene 1.90 U 3.40 1.
Benw(a)pyrene 1.00 U 3.40 1.00 1 02/07/1701:02 2/6/17
Benw(b)fluomnthene 2.00 U 3.40 2.00 1 02/07/1701:02 2/6/17
Benw(g,h,i)perylene 3.99 3.40 2.20 1 02/07/1701:02 2/6/17
Benin k fluomnthene 2.40 U 3.40 2.40 1 02/07/1701:02 2/6/17
Chrysene 1.90 U 3.40 1.90 1 0717 01:02 2/6/17
Dibenz(a,h)anthmcene 2.791 3.40 2.70 1 02/07/1701:02 2/6/17
Fluoranthene 2.00 U 3.40 2.00 1 02/07/1701:02 2/6/17
Fluorene 2.20 U 3.40 2.20 1 021071170h02 2/6/17
Indeno 123-cd rene 3.01 I 3.40 2.20 1 02/07/1701:02 2/6/17
Naphthalene 3.10 U 3.40 3.10 1 02/07/17
Phenanthrene 1.70 U 6.80 1.70 1 02/07/1701:02 2/6/17
Pyrene 2.00 U 3.40 2.00 1 02/07/1701:02 2/6/17
Surrogate Name %Rec Control Limits Date Analyzed Q
2-Fluorobiphenyl 60 30- I l 02 /17 01.02
p-Terphenyl-dl4 70 41 - 146 02/07/17 01:02
Itintcd L82017406:321'M SupersetttefemnccO-0000410083mv00
Page 32 of 37
I
ALS Group USA,Corp.
db.Ars Envi.unmeut.l
QA/QC Repon
Client: Legacy Engineering Service Request: 31700812
Project: 275 Sherry Or Date Analyzed: 02/07/17
Sample Matrix: Soil Date Extracted: 02/06/17
Lab Control Sample Summary
Base Neutral Semivolatile Organic Compounds by GC/MS SIM
Analysis Method: 8270D SRN Units: ug/Kg
Prep Method: EPA 3546 Basis: Dry
Analysis Lot: 533723
Lab Control Sample
JQ1700922-02
Analyte Name Result Spike Amount %Ret %Rest Limits
1-Methylnaphthalene 45.0 66.7 67 32-101
2-Methylnaphthalene 43.6 66.7 65 32-103
Acenaphthene 42.6 66.7 64 29-122
Acenaphthylene 42.1 66.7 63 36-114
Anthracene 40.4 66.7 61 36-135
Benz(a)anthracene 47.2 66.7 71 43-139
Benzo(a)pymne 52.5 66.7 79 43-127
Benzo(b)Ouomnthene 52.4 66.7 79 49-139
Benzo(g,h,i)perylene 57.5 66.7 86 30-135
Benw(k)fluomthene 54.0 66.7 81 45-132
Chrysene 51.4 66.7 77 36-130
Dibenz(a,h)anthracene 54.4 66.7 82 32-139
Fluoranthcne 42.7 66.7 64 42-127
Fluorcne 43.6 66.7 65 41-118
[ d o(123- d)pv 55.0 66.7 83 32-133
Naphthalene 37.0 66.7 55 29-107
Phenanthrene 41.6 66.7 62 34-130
Pyrene 45.9 66.7 69 45-118
Primed VM0174:06:32PM Superset Refemn<c.17-0000410083rev00
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AlEnuironmental
# semivolatile Organic Compounds by GC
ALS Environmental—Jacksonville Laboratory
9143 Philips Highway, Suite 200,Jacksonville, FL 32256
Phone (904)739-2277 Fax (904)739-2011
www.alsglobal.com
RIGHT SOLUTIONS RIGHT PARTNER
Page 34 of 37
ALS Group USA,Corp.
dM ALS Emi.ssa alal
QA/QC Report
Client: Legacy Engineering Service Request: J1700812
Project: 275 Sherry Dr
Sample Matrix: Soil
SURROGATE RECOVERY SUMMARY
Petroleum-Range Organics by GC-FID for State of Florida
Analysis Method: FL-PRO
Extraction Method: EPA 3546
o-Terphenyl n-Naoatriamntane
Sample Name Lab Code 62-109 0-118
House Pad 11700812-001 73 76
Method Blank JQ1700920-01 65 77
Lab Control Sample JQ1700920-05 73 82
Duplicate Lab Control Sample JQ1700920-06 70 82
Printed 21820174:06:44 PM Page 35 of 37 S.p v,Re&—c u-0000410063 m W
ALS Group USA,Corp.
db.AIS Emironmenml
Analytical Report
Client: Legacy Engineering Service Request: /1700812
Project: 275 Sherry Dr Date Collected: NA
Sample Matrix: soil Date Received: NA
Sample Name: Method Blank Units: mg/Kg
Lab Code: JQ1700920-01 Basis: Dry
Petroleum-Range Organics by GC-FID for State of Florida
Analysis Method: FL-PRO
Prep Method: EPA 3546
Analyte Name Result PQL MDL Dil. Date Analyzed Date Extracted Q
FL-PRO(CS-C40) 2.00 U 2.00 2.00 1 02/06/1717:49 2/6/17
Surrogate Name Rce Control Limits Date Anal ed Q
o-Terphenyl 65 - 109 0 7 17.4
n-Nonatriacontane 77 60- 118 02/06/17 17:49
Printcd 2I8Q017406.44 PM Superset Reference:17-0000410083 rm 00
Page 36 of 37
ALS Group USA,Corp.
Oha AIS Envireamental
QA/QC Report
Client: Legacy Engineering Service Request: /1700812
Project: 275 Sherry Dr Date Analyzed: 02/06/17
Sample Matrix: Soil Date Extracted: 02/06/17
Duplicate Lab Control Sample Summary
Petroleum-Range Organics by GC-FID for State of Florida
Analysis Method: FLPRO Units: mg/Kg
Prep Method: EPA 3546 Basis: Dry
Analysis Lot: 533738
Lab Control Sample Duplicate Lab Control Sample
JQ1700920-05 JQ1700920-06
Ree
Analyte Ne Result Spike Amount % Ree Result Spike Amount %Ree Limits RPD RPD Limit
FL-PRO(C8-C40) 8.12 11.3 72 9.28 11.3 82 63-143 13 20
Printed 2/8/101 7 4.0644 PM Superse[Reference:17-000O IN83 my 00
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