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461 Atlantic Blvd. ROOF19-0003 Revision ti'51-EM F1 �oZL'J- �ZI) Revision Request/Correction to Comments **ALL INFORMATION sr HIGHLIGHTED IN '� City of Atlantic Beach Building Department GRAY IS REQUIRED. - n r 800 Seminole Rd, Atlantic Beach, FL 32233 Phone: (904) 247-5826 Email: Building-Dept@coab.us PERMIT#:?CSO[= (9-0003 ❑ Revision to Issued Permit OR ❑ Corrections to Comments Date: 3�9/10q Project Address: %/ R174-kifiL 6L-vU 41.41477C- C F&_ Contractor/Contact Name: Pie- 'DAD iN 5E2U« S Contact Phone 04) 2/If _O74/5 Email: n fir'► -roFroPern Services , CG/"/ `/ Description of Proposed Revision/Corrections: rLS r u I -�E-,-� FL ! U 2 C, 4 - R 14- 1 ot_ct \. 0, t--e L-c,4 ty7 - T- Z- ( 1 gPo PENp( TUB✓ affirm the revision/correction to comments is inclusive of the proposed changes. (printed name) • Will proposed revision/corrections add additional square footage to original sul?ini#tal, 1]No Yes(additional s.f.to be added: NT9 2019 • Will proposed revision/corrections add additional increase in building value to original submittal? ❑No ❑*Yes(additional increase in building value:$ )(Contractor must sign if increase in valuation) *Signature of Contractor/Agent: (Office Use Only) V-Approved ❑ Denied ❑ Not Applicable to Department Permit Fee Due$ '� �-00 Revision/Plan Review Comments De ment Review Required: Buildin • -&Zoning Reviewed By Tree Administrator Public Works Public Utilities A co 4 t Public Safety Date Fire Services Updated 10/17/18 Firestone Firestone Building Products Firestone Building Products Submittal Package Created for: Metro Property Services, Inc. Date: 3/15/2019 Project Number: 3347684 Project Name: ABBQ Resurant Address: 461 Atlantic Blvd City, State, Zip: Atlantic Beach, FL 32233-4021 REVISION BP# 'Roor 1 1 - 000 '? DATE Lfj / 04 / q SIGNED 'N It is the contractor's responsibility to ensure that they are utilizing the current, up-to-date technical documents at the time of installation. $>1 OA Project: 3347684 Page 1 of 11 Project Name: ABBQ Resurant Created: 3/15/2019, 08:54 AM 'Firestone Firestone Building Products Table of Contents Cover Page 1 Table Of Contents 2 Letter Of Good Standing 3 Sample Warranty 4 Roof Drawing 7 Technical Library Documents 9 TPO 10 Front Awning 11 Fc oo Project: 3347684 Page 2 of 11 Project Name: ABBQ Resurant Created: 3/15/2019, 08:54 AM rirestone Firestone Building Products Company,LLC 200 4th Avenue South Nashville,TN 37201 Phone 800-428-4442 3/15/2019 0040008556 Metro Property Services, Inc. 3530 Saint Augustine Rd Jacksonville, FL 32207-5525 To Whom It May Concern: Please be advised that Metro Property Services, Inc. is a Firestone applicator in good standing with Firestone. Metro Property Services, Inc. is authorized with Firestone for: FS Licensed Metal Roof Coating effective Tuesday, October 19, 2010 FS Licensed Garden Roof effective Tuesday, October 19, 2010 FS Licensed Daylighting effective Tuesday, October 19, 2010 FS Licensed SkyPavers effective Tuesday, October 19, 2010 FS Licensed Asphalt Roofing effective Tuesday, October 19, 2010 FS Licensed EPDM Roofing effective Tuesday, October 19, 2010 FS Licensed TPO Roofing effective Tuesday, October 19, 2010 Firestone is proud to include Metro Property Services, Inc. in our family of approved applicators. If I may be of further assistance, please feel free to call my office. Sincerely, Jeff Henegar Executive Director, Technical Services OIC+ y Project: 3347684 Page 3 of 11 Project Name: ABBQ Resurant Created: 3/15/2019, 08:54 AM NOTES: METAL ROOF PANEL UNDERLAYMENT 1. REFER TO FIRESTONE WEBSITE FOR MOST CURRENT INFORMATION. 1-1/4"HOT DIPPED GALVANIZED ROOF 2. REFER TO DETAIL UT-LS-1 OR 2 FOR WELD WIDTH. NAILS @ 12"(305 mm)O.C.MAX. %%11.11 3. MAXIMUM 6"(152 mm)LONG FASTENERS. CONTINUOUS BEAD OF (NOTE: WOOD BLOCKING MAY BE SUBSTITUTED FIRESTONE WATERBLOCK FOR INSULATION TO REDUCE FASTENER LENGTH REQUIREMENT). \ =�� 4. BONDING ADHESIVE REQUIRED BETWEEN MEMBRANE \\ METAL ROOF PANEL AND INSULATION FOR FULLY ADHERED SYSTEMS. \\ 5. CONTACT FIRESTONE ROOFING SOLUTIONS FOR \\ \ BALLASTED ROOF SYSTEMS. \ 6.TPO 18"CURB FLASHING OR MEMBRANE 6. WHEN REINFORCEMENT OF TPO MEMBRANE IS \ EXPOSED,REFER TO UT-LS-14 FOR CUT EDGE \ SEALANT APPLICATION. \ ULTRAPLY TPO BONDING ADHESIVE --E- \ FIRESTONE FASTENER AND HD OR E \ N HD PLUS SEAM PLATE@12" ,-.,i \ (305 mm)0.C.MAX.(SEE NOTE#3) ao \ ULTRAPLY TPO MEMBRANE \ 1/4"MIN. WELDED SPLICE ULTRAPLY TPO BONDING \ (6 mm) (SEE NOTE#2) ADHESIVE(SEE NOTE#6) z \\ co r‘ \ Jr ....) FIRESTONE INSULATION II O SUBSTRATE c":-.1 4.-4......; kp Acre_6.-t) �O 14+ Z_ MAXIMUM WARRANTY: 20 YEARS ISSUE/REVISION DETAIL NO. 'Firestone TERMINATION AT METAL ROOF PANEL DATE: BUILDING PRODUCTS ' 7/22/2014 UT-T-21 NOBODY COVERS YOU BETTER:" ULTRAPLY'"TPO ACCEPTABLE SYSTEMS: ALL (SEE NOTES) www.firestonebpco.com NOT TO SCALE • Cf f, TECHNICAL INFORMATION SHEET 'Firestone I.S.O. Twin PackTM Adhesive Item Description Item Number Insulation Adhesive W56RACINTA • Product Information Description: I.S.O. Twin Pack Insulation Adhesive is a two-component low-rise polyurethane adhesive designed for anchoring acceptable roof insulation and cover boards to acceptable substrates, as well as for adhering multiple layers of insulation. I.S.O. Twin Pack is a solvent free and VOC free insulation adhesive that contains no harmful HCFC or CFCs. I.S.O. Twin Pack Insulation Adhesive is suitable for cold weather applications when stored properly. I.S.O. Twin Pack Insulation Adhesive is dispensed using I.S.O. Twin Pack Hand Dispenser (TIS 1519) I.S.O. Twin Pack Four Bead Dispenser (TIS 1520); Multi-Bead Plus Dispenser; Battery Powered Single Bead Applicator or a Pneumatic Single Bead Applicator. The dispensers extrude I.S.O. Twin Pack Part A and B simultaneously to the static mixer, which results in a mixed adhesive in bead form. Firestone Building Products standard warranties are available up to 30-year warranty period. Please refer to the Firestone Technical Database www.firestonebpco.corn for specific warranty requirements. Method of Application: 1. I.S.O. Twin Pack Insulation Adhesive can be installed at temperatures as low as 20 °F (-7 °C) and rising when the material is stored between 60 °F (16 °C) and 80 °F (27°C). 2. For best results, use power actuated dispensers (battery; pneumatic) to dispense I.S.O. Twin Pack. Hand powered dispensers may not offer the continuous force necessary to insure uniform mixing of large quantities. 2. The substrate must be clean, smooth, dry, and free of sharp edges, loose and foreign materials, oil, grease, and other contaminants. 3. To mix and dispense I.S.O. Twin Pack Insulation Adhesive from kits, remove plugs and apply the static mixer over plug end of kit by hand tightening static mixer to kit with plug end facing up. Keep plug end facing up until you are ready to dispense I.S.O. Twin Pack Insulation Adhesive to the deck substrate. 4. Properly mixed I.S.O. Twin Pack will be amber, with no marbling. Part A and B will be extruded simultaneously through dispensing equipment. 5. To stop dispensing I.S.O. Twin Pack Insulation Adhesive, stop the dispenser plunger from advancing and point the mixing end up to stop Part A and Part B from entering static mixer. This stopped position of the kit can only be maintained for several minutes, as Part A and Part B already in the static mixer will continue to react, set up, and block the static mixer. If the static mixer becomes blocked during stopped period, replace static mixer in order to mix and dispense the remaining Part A and Part B in kit. 6. Apply I.S.O. Twin Pack Insulation Adhesive in a bead 1/2 (12.7 mm) wide to deck substrate in spacing as specified for the project and immediately set the insulation or cover boards, 4' x 4' (1.22 m x 1.22 m) maximum, in fresh I.S.O. Twin Pack insulation adhesive before a skim coat develops. The adhesive will rise to a bead of 3/4"- 1" (19.0 mm — 25.4 mm) within minutes after placement. Rise time will depend on the ambient conplft'i s: warmer=faster; cooler=slower. 7. To ensure that the insulation makes continuous contact with the adhesive during the critt* t-up period, immediately weight each board after setting in place, using full pails of Bonding Adhesive or other av�source of weight that will not damage the roof insulation. OA Firestone Building Products I Sales:(800)428-44421 Technical(800)428-45111 www.flrestonebpco.Com TIS#812 11/07/2016 Page 1 of 4 rt TECHNICAL INFORMATION SHEET B i'Q S BUILDING PRODUCTS I.S.O. Twin Pack. "' Adhesive Storage: • Store in original containers at temperatures between 60 °F (16 °C) and 80 °F (27 °C). Do not allow I.S.O. Twin Pack to freeze. • Store cartons with kits on their side. • DO NOT store kits with plunger or plugged end down to avoid the possibility of leakage. • Keep plugs on kits tightly closed during storage. DO NOT expose to moisture. • When I.S.O. Twin Pack is stored in original unopened container indoors away from direct sunlight between 60 °F (16 °C) and 80 °F (27 °C) shelf life is twelve months. • For optimum results, rotate your stock to ensure stored material has not exceeded the shelf life of one year. Precautions: 1. Review applicable Safety Data Sheets prior to use. 2. Store in original containers at temperatures between 60 °F (16 °C) and 80 °F (27 °C). Do not allow I.S.O. Twin Pack to freeze. 3. Personnel who are sensitive/allergic to isocyanate or polyurethane should not work with I.S.O. Twin Pack Insulation Adhesive. 4. At the start of each workday, and prior to beginning work, perform a trial application using I.S.O. Twin Pack Insulation Adhesive and a sample piece of insulation or cover board to verify the product's suitability for use that day. Verify that proper mixing, set-up and overall adhesion of insulation to substrate is being achieved before proceeding. Use only when conditions allow, and daily trials indicate successful adhesion. 5. Install only as much roof insulation with I.S.O. Twin Pack Insulation Adhesive as can be covered and made watertight during that working day. The performance of I.S.O. Twin Pack should be periodically monitored during the workday to verify that sufficient rise, adhesion, and mating of the insulation using I.S.O. Twin Pack is occurring. 6. Review dispensing equipment instructions prior to use. Ensure dispensing equipment is in good working order. 7. It is the responsibility of the Roofing Contractor to maintain dispensing equipment in good working order to deliver and thoroughly mix, meter, and dispense this adhesive in a 1:1 (Part A:Part B) ratio. 8. Avoid contact with eyes. Wear safety glasses with side shields. 9. Avoid breathing of vapors. A Self-Contained Breathing Apparatus (SCBA) or Respirator should be used in areas of limited ventilation. 10. Avoid contact with skin. Wear gloves when dispensing. Wash hands thoroughly after handling. 11. Set insulation boards immediately into wet I.S.O Twin Pack Insulation Adhesive. Insulation boards shall not exceed 4' x 4' (1.2 m x 1.2 m). 12. It is imperative that freshly installed insulation is continuously weighted until I.S.O. Twin Pack Insulation Adhesive sets up and the board is held in place by the adhesive. 13. Use caution when removing plugs from kits 14. Do not burn empty kit containers. Dispose in accordance with local, federal, and state regulations. LEED® Information: Post Consumer Recycled Content: 0% Post Industrial Recycled Content: 0% Manufacturing Location: Chagrin Falls, OH 'NOTE:LEED®is a registered trademark of the U.S.Green Building Council. Or,It* N"""-DADE COUNTY C US APPROVED APPROVED Firestone Building Products I Sales:(800)428-44421 Technical(800)420-4511 I www.firestonebpco.com TIS#812 11/07/2016 Page 2 of 4 ,1 'Firestone TECHNICAL INFORMATION SHEET BUILDING PRODUCTS I.S.O. Twin Pack"' Adhesive Packaging Property Value Kit Contents: I.S.O.Twin Pack Insulation Adhesive is packaged as a kit consisting of one 750 ml Part A cartridge fastened together with one 750 ml Part B cartridge. Each Case Contains: 4 Part A—Part B Kits,4 Static Mixers, Instruction Sheet Weight of Case: 20 lb(9 kg) Number per Pallet: 48 NOTE: Coverage rates of each I.S.O.Twin Pack kit,when properly mixed,dispenses 150'(45.7 m)of mixed adhesive in a bead /2 (12.7 mm)wide. This bead will rise'/:'-1"(19.0 mm—25.4 mm). This equates to a coverage area of 600 ft2(55.74 m2)per carton when installed in beads 12"(304.8 mm)on center(typical spacing). NOTE: Coverage rate may be reduced due to irregularities in substrates. Beads Despensed at - Coverage per Carton 4"o.c. (102 mm) 200 ft2(27.87 m2) 6"o.c. (152 mm) 300 ft2(18.58 m2) Typical Set Up Times At 60°F(16°C)to 90°F(32°C): 5-8 minutes At 20°F(-7°C)to 60°F(16°C): 8-15 minutes Typical Properties PromnLomax Minimum Performance Color: Part A Amber Color: Part B Off-White Composition Part A Isocyanate pre-polymer Composition Part B Polyol Mix Ratio of A:B 1:1 by volume Specific Gravity Part A 1.18+0.06 Specific Gravity Part B 1.02+0.05 Viscosity Part A/Part B 3,000-24,000 cps,#52 spindle at 5 RPM, 77°F(25°C) V.O.C. Content: 0 f/L(0 lb/gal) Firestone Building Products I Sales:(800)428-44421 Technical(800)428-4511 I www.flrestonebpco.com TIS#812 11107/2016 Page 3 of 4 TECHNICAL INFORMATION SHEET rB CQ S BUILDING PRODUCTS O h Q I.S.O. Twin PackTM Adhesive Acceptable Substrates Property Notes Structural Concrete(New) New poured decks must have a minimum 28 day cure time Structural Concrete(Existing) Positive adhesion test required Steel New steel decks may require cleaning to remove processing oils IGypsum Decks Positive adhesion test required Cementitious Woodfiber Modified Bitumen Roofs Plywood and OSB SBS Base Sheets V-Force Membrane Positive adhesion test required Lightweight Concrete Acceptable Lightweight concrete substrates include cellular or air-entrained concrete. Existing Asphalt and Modified Bitumen Existing substrates containing residual asphalt must be cleaned and scraped smooth Roofs(mineral or Smooth Surfaced) as possible. Coal Tar Pitch Positive adhesion test required. Primer may be required. Insulation IS095+TM GL HD, RESISTATM FiberTopT"'Woodfiber, Dens-Deck® Non-Firestone brand insulations require a positive adhesion test. Product, Expanded Polystyrene, Extruded Polystyrene NOT ACCEPTABLE : Single Ply membrane, Fibers lass insulation, Perlite insulation NOTE: Dens-Deck is a registered Trademark of Georgia-Pacific. Necessary Equipment: The following equipment is necessary to dispense I.S.O. Twin Pack Insulation Adhesive: • Static Mixer: Supplied with I.S.O. Twin Packs. Static mixer tubes are bolted onto the plugged end of kit after plugs removed. As Part A and B are simultaneously extruded through the tube, the static mixer properly and thoroughly mixes Part A and Part B. The tip at the end of the static mixer (opposite bolt end) dispenses mixed I.S.O. Twin Pack Insulation Adhesive in a 1/2' (12.7 mm)wide bead. • I.S.O. Twin Pack 4 Bead (Firestone Item No. W56RACINT4) and 13 Bead MBA+ Multi Bead Dispenser(sold separately): Cart and wheel mounted, hand maneuverable, with battery driven plungers, these dispensers mix and dispense multiple beads of I.S.O. Twin Pack Insulation Adhesive simultaneously from 12" (304.8 mm) on center all the way up to full coverage on open, unobstructed roof areas. Pre-marked cartridge slots provide consistent application for desired bead spacing of the I.S.O. Twin Pack. • I.S.O. Twin Pack Single Bead Hand Dispenser (Firestone Item No. W56RACINTG); Battery Powered Single Bead Applicator and Pneumatic Single Bead Applicator(sold separately): Mixes and dispenses one bead of I.S.O. Twin Pack Insulation Adhesive and are necessary for dispensing I.S.O. Twin Pack Insulation Adhesive on roof areas where Multi Bead Dispensers cannot be maneuvered. Please contact Quality Building Services Technical Department at 1-800-428-4511 for further information. This sheet is meant to highlight Firestone products and specifications and is subject to change without notice. Firestone takes responsibility for furnishing quality materials which meet published Firestone product specifications or other technical documents, subject to normal roof manufacturing tolerances. Neither Firestone nor its representatives practice architecture. Firestone offers no opinion on and expressly disclaims any responsibility for the soundness of any structure.Firestone accepts no liability for structural failure or resultant damages. Consult a competent structural engineer prior to installation if the structural soundness or structural ability to properly support a planned installation is in question. No Firestone representative is authorized to vary this disclaimer. Firestone Building Products' Sales:(800)428-44421 Technical(800)428-45111 www.firestonebpco.com TIS#812 1110712016 Page 4 of 4 ;.S.0 Twin PackT'f Insulation Adhesive Part B Safety Data Sheet Firestone Building Products Company Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name • I.S.O. Twin PackTM Insulation Adhesive Part B 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) • Construction 1.3 Details of the supplier of the safety data sheet Manufacturer • Firestone Building Products Company 200 4th Avenue S Nashville, TN 37201-2208 United States firestonemsds@bfdp.com Telephone (General) • 800-428-4442 1.4 Emergency telephone number Manufacturer . (800) 424-9300 - CHEMTREC Manufacturer . (703) 527-3887 - CHEMTREC - International Section 2: Hazards Identification EU/EEC According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP • Skin Irritation 2 - H315 Skin Sensitization 1 - H317 Eye Irritation 2 - H319 DSD/DPD • Irritant (Xi) R36/38, R43 2.2 Label Elements CLP WARNING A Hazard statements • H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319 - Causes serious eye irritation Precautionary statements Prevention • P261 - Avoid breathing mists, vapours, and/or spray. P264 - Wash thoroughly after handling. Preparation Date: 13/ApriV2009 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 EU DSD/DPD.EU CLP,OSHA HCS 2012,WHMIS Page 1 of 15 I.S.O.Twin Packm',Insulation Adhesive Part B P272 - Contaminated work clothing should not be allowed out of the workplace. P280-Wear protective gloves and eye/face protection , . Response • P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362 -Take off contaminated clothing and wash before reuse. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P321 - Specific treatment, see supplemental first aid information. Storage/Disposal • P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. DSD/DPD Risk phrases • R36/38 - Irritating to eyes and skin. R43 - May cause sensitisation by skin contact. Safety phrases • S24 -Avoid contact with skin. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 -Wear suitable gloves. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 2.3 Other Hazards CLP • According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous. DSD/DPD • This product is considered dangerous according to the European Directive 67/548/EEC. United States (US) According to: OSHA 29 CFR 1910.1200 HCS 2.1 Classification of the substance or mixture OSHA HCS 2012 • Skin Irritation 2 Skin Sensitization 1 Eye Irritation 2A 2.2 Label elements OSHA HCS 2012 WARNING O Hazard statements • Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation Precautionary statements Prevention • Avoid breathing mists, vapours, and/or spray. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves and eye/face protection , . Response . If on skin: Wash with plenty of water . If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, Preparation Date: 13/April/2009 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 20(15 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS ' I.S.O.Twin Pack''Insulation Adhesive Part B if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment, see supplemental first aid information. Storage/Disposal • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. 2.3 Other hazards OSHA HCS 2012 • Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Canada According to: WHMIS 2.1 Classification of the substance or mixture WHMIS • Other Toxic Effects - D2B 2.2 Label elements WHMIS • 9 WHMIS • Other Toxic Effects - D2B 2.3 Other hazards WHMIS • In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS). Section 3 - Composition/Information on Ingredients 3.1 Substances • Material does not meet the criteria of a substance. 3.2 Mixtures Composition Chemical Name Identifiers % LD50/LC50 Classifications According to Comments Regulation/Directive Siloxanes and Silicones,di-Me, CAS:67762- <= EU DSD/DPD: Not Classified reaction products with silica 90-7 2.5% NDA EU CLP: Not Classified NDA OSHA HCS 2012: Not Classified CAS:1760 24- EU DSD/DPD: Self Classified:Xi; Ethylenediamine, N-(3- 3 <= Ingestion/Oral-Rat LD50• R36 trimethox sil I ro I EINECS:217- 2.5% 2413 mg/kg EU CLP: Self Classified: Eye Irrit. NDA ( Y Y)P PY) 2,H319 164-6 OSHA HCS 2012: Eye Irrit.2 _ _ CAS:25265- Ingestion/Oral-Rat 71-8 <= LD50• 14850 mg/kg EU DSD/DPD: Not Classified Propanol,oxybis- EU CLP: Not Classified NDA EINECS:246- 2.5% Skin-Rabbit LD50•>20 OSHA HCS 2012: Not Classified 770-3 m L/kg Section 4 - First Aid Measures 1 Preparation Date: 13/ApriV2009 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 3 of 15 EU DSD/DPD,EU CLP,OSHA HCS 2012.WHMIS • • I.S.O,.Tien Pack"'Insulation Adhesive Part B r . 4.1 Description of first aid measures Inhalation • Move victim to fresh air. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. If signs/symptoms continue, get medical attention. Skin • Wash skin with soap and water. If irritation develops and persists, get medical attention. Eye • In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. If eye irritation persists: Get medical advice/attention. Ingestion • Rinse mouth. Drink 1 -2 glasses of water. Do NOT induce vomiting. Do not give anything by mouth to an unconscious person. Get medical attention immediately. 4.2 Most important symptoms and effects, both acute and delayed • Refer to Section 11 -Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician • All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media • Use fire extingusihing media as appropriate for surrounding conditions. Unsuitable Extinguishing • No data available Media 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion • Dried solids can burn and release toxic fumes and vapors. Hazards Hazardous Combustion • No data available Products 5.3 Advice for firefighters • Structural firefighters' protective clothing will only provide limited protection. Wear positive pressure self-contained breathing apparatus (SCBA). SMALL FIRES: Move containers from fire area if you can do it without risk. LARGE FIRES: Cool containers with flooding quantities of water until well after fire is out. Section 6 -Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions • Ventilate enclosed areas. Do not walk through spilled material. Wear appropriate personal protective equipment, avoid direct contact. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Emergency Procedures • As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. Keep unauthorized personnel away. Keep out of low areas. Stay upwind. 6.2 Environmental precautions • Prevent entry into waterways and sewers. 6.3 Methods and material for containment and cleaning up Containment/Clean-up • Absorb or cover with dry earth, sand or other non-combustible material and transfer to Measures containers. Preparation Date: 13/ApriV2009 Format EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 W Page 4 of 15 EU DSDIDPD,EU CLP,OSHA HCS 2012, HMIS O.'Twin Pad.'Insulation Adhesive Part B Dike to collect large liquid spills. 6.4 Reference to other sections • Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. Section 7 - Handling and Storage 7.1 Precautions for safe handling Handling • Use only in well ventilated areas. Wear appropriate personal protective equipment, avoid direct contact. Avoid breathing mist, vapours, spray. Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. 7.2 Conditions for safe storage, including any incompatibilities Storage • Keep container tightly closed. Store in a cool, dry, well-ventilated place. 7.3 Specific end use(s) • Refer to Section 1.2 - Relevant identified uses. Section 8 - Exposure Controls/Personal Protection 8.1 Control parameters Exposure Limits/Guidelines Result Germany DFG Germany TRGS 100 mg/m3 TWA AGW(The risk of damage to the TWAs Not established embryo or fetus can be excluded when AGW and BGW Propanol, oxybis- values are observed, inhalable fraction,exposure (25265-71-8) factor 2) Ceilings 200 mg/m3 Peak(inhalable fraction) Not established MAKs 100 mg/m3 TWA MAK(inhalable fraction) Not established Exposure Control Notations Germany TRGS •Propanol, oxybis-(25265-71-8):Skin: (skin notation) Germany DFG •Propanol,oxybis-(25265-71-8): Pregnancy: (no risk to embryo/fetus if exposure limits adhered to)I Skin: (skin notation(inhalable fraction)) 8.2 Exposure controls Engineering - This material is designed to be used outdoors, in roofing applications. Good general Measures/Controls ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Personal Protective Equipment Respiratory • In case of insufficient ventilation, wear suitable respiratory equipment. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH or European Standard EN 149 approved respirator if exposure limits are exceeded or symptoms are experienced. Eye/Face • Wear chemical splash safety goggles. Skin/Body • Wear appropriate chemical resistant clothing and chemical resistant gloves. Environmental Exposure • In case of spills, keep product clear of sewers, waterways or land areas. Dispose of Controls waste product in accordance with national and local laws and regulations. Key to abbreviations Preparation Date: 13/Apri1/2009 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS Page 5of15 I.S'O.Twin Pack"'Insulation Adhesive Part B MAK=Maximale Arbeitsplatz Konzentration is the maximum permissible concentration TWA=Time-Weighted Averages are based on 8h/day,40h/week exposures Section 9 - Physical and Chemical Properties 9.1 Information on Basic Physical and Chemical Properties Material Description Physical Form Liquid Appearance/Description Colorless liquid with polyether odor. Color Colorless Odor Polyether Odor Threshold Data lacking General Properties Boiling Point Data lacking Melting Point/Freezing Point Data lacking Decomposition Temperature Data lacking pH 9 to 10 Specific Gravity/Relative Density =0.98 @ 20°C(68°F)Water=1 Water Solubility Data lacking Viscosity Data lacking Explosive Properties Product does not present an explosion hazard. Oxidizing Properties: Data lacking Volatility Vapor Pressure Data lacking Vapor Density Data lacking Evaporation Rate Data lacking _ Flammability Flash Point >350°C(>662°F) UEL Data lacking LEL Data lacking Autoignition Data lacking . Flammability(solid,gas) Not determined. Environmental Octanol/Water Partition coefficient 'Data lacking I 9.2 Other Information • No additional physical and chemical parameters noted. Section 10: Stability and Reactivity 10.1 Reactivity • No dangerous reaction known under conditions of normal use. 10.2 Chemical stability • Stable 10.3 Possibility of hazardous reactions • Hazardous polymerization will not occur. 10.4 Conditions to avoid • High temperatures. 10.5 Incompatible materials • Oxidizing agents. 10.6 Hazardous decomposition products • Carbon monoxide, carbon dioxide, tin oxide. Preparation Date: 13/ApriL2009 Format EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 W P 6 of 15 EU DSD/DPD,EU CLP,OSHA HCS 2012, HMIS age I.S.O.Twin Pack Insulation Adhesive Part B Section 11 -Toxicological Information 11.1 Information on toxicological effects Components Siloxanes and Silicones,di-Me, _ Multi-dose Toxicity: Inhalation-Rat TCLo•30 mg/kg 6 Hour(s)4 Week(s)-Intermittent; Lungs, reaction products with silica(<= 67762 Thorax, or Respiration:Other changes;Blood:Hemorrhage;Related to Chronic Data:Death in 2.5%) 90-7 the Other Multiple Dose data type field Acute Toxicity: Ingestion/Oral-Rat LD50.2413 mg/kg;Behavioral:Tremor; Ethylenediamine,N-(3- 1760- Gastrointestinal:Hypermotility,diarrhea; Gastrointestinal:Other changes;Skin-Rat LD50• (trimethoxysilyl)propyl)-(<=2.5%) 24-3 >2009 mg/kg; Irritation: Eye-Rabbit•15 mg•Severe irritation;Skin-Rabbit•500 mg-Open•Mild irritation 25265- Propanol,ox bis-(<=2.5%) Acute Toxicity: Ingestion/Oral-Rat LD50•14850 mg/kg;Skin-Rabbit LD50•>20 mLk 971-8 GHS Properties Classification Acute toxicity EU/CLP•Data lacking OSHA HCS 2012•Data lacking EU/CLP•Skin Irritation 2 Skin corrosion/Irritation OSHA HCS 2012•Skin Irritation 2 EU/CLP•Eye Irritation 2 Serious eye damage/Irritation OSHA HCS 2012•Eye Irritation 2A EU/CLP•Skin Sensitizer 1 Skin sensitization OSHA HCS 2012•Skin Sensitizer 1 Respiratory sensitization EUICLP•Data lacking OSHA HCS 2012•Data lacking Aspiration Hazard EU/CLP•Data lacking OSHA HCS 2012•Data lacking Carcinogenicity EU/CLP•Data lacking OSHA HCS 2012•Data lacking Germ Cell Mutagenicity EU/CLP•Data lacking OSHA HCS 2012•Data lacking Toxicity for Reproduction EU/CLP•Data lacking OSHA HCS 2012•Data lacking STOT-SE EU/CLP•Data lacking OSHA HCS 2012•Data lacking STOT-RE EU/CLP•Data lacking OSHA HCS 2012•Data lacking Potential Health Effects Inhalation Acute (Immediate) • May cause irritation. Chronic (Delayed) • No data available Skin Acute (Immediate) • Causes skin irritation. May cause skin sensitization. Symptoms include redness, and skin rash. Chronic (Delayed) • No data available Preparation Date: 13/April/2009 Format EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 7 of 15 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS I.S.O.Twin PackT"Insulation Adhesive Part B Eye Acute (Immediate) • Causes serious eye irritation. Chronic (Delayed) • No data available Ingestion Acute (Immediate) • Although swallowing this product is an unlikely means of exposure, irritation of the mouth, pharynx, esophagus and stomach can develop following ingestion. Chronic (Delayed) • No data available Key to abbreviations LD=Lethal Dose TC=Toxic Concentration Section 12 - Ecological Information 12.1 Toxicity • Material data lacking. 12.2 Persistence and degradability • Material data lacking. 12.3 Bioaccumulative potential • Material data lacking. 12.4 Mobility in Soil • Material data lacking. 12.5 Results of PBT and vPvB assessment • No PBT and vPvB assessment has been conducted. 12.6 Other adverse effects • No studies have been found. Section 13 - Disposal Considerations 13.1 Waste treatment methods Product waste . Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 -Transport Information 14.1 UN 14.2 UN proper 14.3 Transport hazard 14.4 Packing 14.5 Environmental number shipping name class(es) group hazards DOT NDA Not Regulated NDA NDA NDA TDG NDA Not Regulated NDA NDA NDA IMO/IMDG NDA Not Regulated NDA NDA NDA ADN NDA Not Regulated NDA NDA NDA ADR/RID NDA Not Regulated NDA NDA NDA Preparation Date: 13/April/2009 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS Page 8of15 I.S.O Twin Pada'•Insulation Adhesive Part A Safety Data Sheet Firestone Building Products Company Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name • I.S.O. Twin PackTM Insulation Adhesive Part A 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) • Construction 1.3 Details of the supplier of the safety data sheet Manufacturer • Firestone Building Products Company 200 4th Avenue S Nashville, TN 37201-2208 United States firestonemsds@bfdp.com Telephone (General) . 800-428-4442 1.4 Emergency telephone number Manufacturer • (800) 424-9300 - CHEMTREC Manufacturer • (703) 527-3887 - CHEMTREC - International Section 2: Hazards Identification EU/EEC According to: Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to: EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP • Skin Irritation 2 - H315 Skin Sensitization 1 - 1-1317 Eye Irritation 2- H319 Acute Toxicity Inhalation 3 - H331 Respiratory Sensitization 1 - H334 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation - H335 Carcinogenicity 2- H351 Specific Target Organ Toxicity Repeated Exposure 2 - H373 DSD/DPD • Harmful (Xn) Irritant (Xi) Carcinogenic Substances - Category 3 R20, R36/37/38, R40, R42/43, R48/20 2.2 Label Elements CLP DANGER Preparation Date: 18/October/2011 Format EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 W Page 1 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012, HMIS I.S.O.Twin Perim Insulation Adhesive Part A Hazard statements • H315 - Causes skin irritation H317 - May cause an allergic skin reaction H319- Causes serious eye irritation H331 - Toxic if inhaled H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H335- May cause respiratory irritation H351 - Suspected of causing cancer. H373 - May cause damage to organs through prolonged or repeated exposure. Precautionary statements Prevention • P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe mist/vapours/spray. P264 -Wash thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing should not be allowed out of the workplace. P280 - Wear protective gloves and eye/face protection , . P281 - Use personal protective equipment as required. P285 - In case of inadequate ventilation wear respiratory protection. Response • P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P302+P352 - IF ON SKIN: Wash with plenty of soap and water. P321 - Specific treatment, see supplemental first aid information. P333+P313- If skin irritation or rash occurs: Get medical advice/attention. P362 -Take off contaminated clothing and wash before reuse. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P308+P313 - IF exposed or concerned: Get medical advice/attention. P314- Get medical advice/attention if you feel unwell. Storage/Disposal • P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. DSD/DPD Risk phrases • R20 - Harmful by inhalation. R36/37/38 - Irritating to eyes, respiratory system and skin. R40 - Limited evidence of a carcinogenic effect. R42/43 - May cause sensitisation by inhalation and skin contact. R48/20- Harmful: danger of serious damage to health by prolonged exposure through inhalation. Safety phrases • S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 -Wear suitable protective clothing. S37 -Wear suitable gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S53-Avoid exposure- obtain special instructions before use. 2.3 Other Hazards CLP • According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous. DSD/DPD • According to European Directive 1999/45/EC this preparation is considered dangerous. United States (US) Preparation Date: 18/OctoberI2011 Format EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 2 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS I.S.O.Twin Pack:"Insulation Adhesive Part A According to: OSHA 29 CFR 1910.1200 HCS 2.1 Classification of the substance or mixture OSHA HCS 2012 • Skin Irritation 2 Skin Sensitization 1A Eye Irritation 2 Acute Toxicity Inhalation 2 Respiratory Sensitization 1A Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation Specific Target Organ Toxicity Repeated Exposure 1 2.2 Label elements OSHA HCS 2012 DANGER A • Hazard statements • Causes skin irritation May cause an allergic skin reaction Causes serious eye irritation Fatal if inhaled May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause respiratory irritation Causes damage to organs- Lungs through prolonged or repeated exposure via Inhalation Precautionary statements Prevention • Do not breathe mist/vapours/spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. Response . IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. If on skin: Wash with plenty of water . If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Specific treatment is urgent, see supplemental first aid information. Get medical advice/attention if you feel unwell. Storage/Disposal • Store in a well-ventilated place. Keep container tightly closed. Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Supplemental information • 75 percent of this product consists of an ingredient of unknown toxicity. 2.3 Other hazards OSHA HCS 2012 • Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Canada According to: WHMIS Preparation Date: 18/October/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 3 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS I.S.O.Twin Pack^'Insulation Adhesive Part A 2.1 Classification of the substance or mixture WHMIS . Very Toxic- DIA Other Toxic Effects - D2A Other Toxic Effects - D2B 2.2 Label elements WHMIS O WHMIS • Very Toxic- D1A Other Toxic Effects- D2A Other Toxic Effects- D2B 2.3 Other hazards WHMIS • In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS). Section 3 -Composition/Information on Ingredients 3.1 Substances • Material does not meet the criteria of a substance. 3.2 Mixtures Composition Chemical Name identifiers % LD50/LC50 Classifications According to Comments Regulation/Directive EU DSD/DPD: Self Classified:Xn, R20-48/20;Xn, Ingestion/Oral-Rat R42/43,Xi, R36/37/38;Carc.3,R40 LD50.49 g/kg EU CLP: Self Classified:Acute Tox.2(mist),H330; Polymethylene CAS:9016-87- 25% Inhalation-Rat STOT RE 2,H373;Eye Irrit.2,H319;STOT SE 3: polyphenyl TO LC50.490 mg/m' Resp.Irrit.,H335;Skin brit.2,H315;Resp. Sens. 1, NDA isocyanate 9 50% 4 Hour(s) H334;Skin Sens. 1,H317;Carc.2,11351 Skin-Rabbit LD50• OSHA HCS 2012: Eye brit.2;Skin Irrit.2;Skin >9400 mg/kg Sens. 1A:STOT SE 3:Resp. brit.;Resp.Sens. 1A; STOT RE 1(Lung);Acute Tox.2(inhl,mist) EU DSD/DPD: Annex VI,Table 3.2:Carc.Cat.3; CAS:101 68 8 R40;Xn;R20-48/20;Xi; R36/37/38,R42/43 EC o Ingestion/Oral-Rat EU CLP: Annex VI,Table 3.1: Carc.2,H351; Isocyanic acid, 25% Acute Tox.4,H332;STOT RE 2•,H373;Eye brit.2, methylenedi-p- Number:202- TO LD50.9200 mg/kg H319;STOT SE 3:Resp.brit.,H335;Skin Irrit.2, NDA phenylene ester 966-0 50% Inhalation Rat H319;Resp.Sens. 1,H334;Skin Sens. 1,H317 EU Index:615- LC50. 178 mg/m3 OSHA HCS 2012: Skin brit.2,Eye Init.2,Skin 005-00-9 Sens. 1,Resp.Sens. 1,STOT SE 3:Resp.Irrit.; STOT RE 1(Lungs); EU DSD/DPD: Annex VI,Table 3.2:Carc.Cat.3; CAS:26447-40 R40;Xn;R20-48/20;Xi; R36/37/38;R42/43 -5 EU CLP: Annex VI,Table 3.1: Carc.2,H351; Diphenylmethane EC 2.5% Acute Tox.4, H332;STOT RE 2,H373;Eye Irrit.2, diisocyanate Number:247- TO NDA H319;STOT SE 3:Resp.brit.,H335;Skin Irrit.2, NDA 714-0 10% H315;Resp.Sens. 1,H334;Skin Sens. 1,H317 EU Index:615- OSHA HCS 2012: Eye brit.2;STOT SE 3:Resp. 005-00-9 Irrit.;Skin Irrit.2;Resp.Sens. 1A;Skin Sens. 1A; STOT RE 1 Preparation Date: 18/October/2011 Format EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 4 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS I.S.O.Twin Pack"'Insulation Adhesive Part A See Section 16 for full text of H-statements and R-phrases. Section 4 - First Aid Measures 4.1 Description of first aid measures Inhalation • Move victim to fresh air. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. Keep patient warm. Get medical attention immediately if symptoms occur. Skin • Wash skin with soap and water. Take off contaminated clothing and wash before reuse. If irritation develops and persists, get medical attention. Eye • In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. If eye irritation persists: Get medical advice/attention. Ingestion • Rinse mouth. Drink 1 - 2 glasses of water. Do NOT induce vomiting. Get medical attention immediately. 4.2 Most important symptoms and effects, both acute and delayed • Refer to Section 11 -Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician • All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media • CO2, extinguishing powder or water spray. Fight larger fires with water spray. Unsuitable Extinguishing • Do not use a direct stream of water. Media 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion • Dried solids can bum and release toxic fumes and vapors. Hazards Hazardous Combustion • No data available Products 5.3 Advice for firefighters • Structural firefighters' protective clothing provides limited protection in fire situations ONLY; it is not effective in spill situations where direct contact with the substance is possible. Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Wear positive pressure self-contained breathing apparatus (SCBA). Move fire exposed containers if safe to do so. Cool fire exposed containers with water spray. Dike contaminated fire-control water for later disposal. Section 6 -Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions • Ventilate enclosed areas. Do not walk through spilled material. Wear appropriate personal protective equipment, avoid direct contact. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Emergency Procedures • As an immediate precautionary measure, isolate spill or leak area in all directions for Preparation Date: 18/October/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 p 5 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHAAIS I.S.O.Twin Pack I'Insulation Adhesive Part A at least 50 meters (150 feet)for liquids and at least 25 meters (75 feet)for solids. Stay upwind. Keep out of low areas. Keep unauthorized personnel away. Ventilate closed spaces before entering. 6.2 Environmental precautions • Avoid release to the environment. 6.3 Methods and material for containment and cleaning up Containment/Clean-up • Stop leak if you can do it without risk. Measures Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. LARGE SPILLS: Dike far ahead of spill for later disposal. 6.4 Reference to other sections • Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. Section 7 - Handling and Storage 7.1 Precautions for safe handling Handling • Use only with adequate ventilation. Prevent formation of aerosols. Keep away from water as reaction can be initiated by water exposure. Persons with sensitivity to isocyanate should not handle/use this product. Wear appropriate personal protective equipment, avoid direct contact. Do not breath mist/vapours/spray. Avoid contact with skin, eyes, and clothing. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. 7.2 Conditions for safe storage, including any incompatibilities Storage • Store in a cool, dry, well-ventilated place. Keep container tightly closed. Protect from atmospheric moisture. Keep away from heat, sparks and flame. 7.3 Specific end use(s) • Refer to Section 1.2 - Relevant identified uses. Section 8 - Exposure Controls/Personal Protection 8.1 Control parameters Exposure Limits/Guidelines Result ACGIH Canada Alberta Canada British Canada Manitoba Canada New Columbia Brunswick 0.005 ppm TWA (listed under 0.005 ppm TWA 0.005 ppm TWA 0.005 ppm TWA Methylene bisphenyl TWAs (listed under 0.005 ppm TWA;0.05 (listed under (listed under isocyanate);0.051 lsocyanic acid, Methylene bisphenyl mg/m3 TWA Methylene bisphenyl Methylene bisphenyl mg/m3 TWA(listed methylenedi-p- isocyanate(MDI)) isocyanate(MDI)) isocyanate(MDI)) under Methylene phenylene ester bisphenyl (101-68-8) isocyanate) 0.01 ppm Ceiling Ceilings Not established Not established (listed under Not established Not established Methylene bisphenyl isocyanate(MDI)) Polymethylene polyphenyl TWAs Not established 0.005 ppm TWA;0.07 Not established Not established Not established isocyanate mg/m3 TWA (9016-87-9) Preparation Date: 18/October/2011 Format EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS Page 6 of 18 I.S.O.Twin Pack""Insulation Adhesive Part A Ex'aosure Limits/Guidelines (Con't.) Result Canada Northwest Canada Nova Canada Nunavut Canada Ontario Canada Quebec Territories Scotia Diphenylmethane 0.02 ppm Ceiling;0.2 0.02 ppm Ceiling;02 diisocyanate Ceilings Not established . Not established Not established (26447-40-5) mg/m3 Ceiling mg/m3 Ceiling 0.005 ppm TWA (designated substances regulation,listed under Isocyanates, organic compounds 0.005 ppm TWA (Methylene bisphenyl (listed under isocyanate(MDI))); 0.005 ppm TWAEV; TWAs Not established Methylene bisphenyl Not established 0.005 ppm TWA 0.051 mg/m3 TWAEV isocyanate(MDI)) (applies to workplaces to which Isocyanic acid, the designated methylenedi-p- substances phenylene ester (101-68-8) regulation does not apply,listed under Methylene bisphenyl isocyanate(MDI)) 0.02 ppm Ceiling (designated substances Ceilings Not established Not established Not established regulation,listed Not established under Isocyanates, organic compounds (Methylene bisphenyl isocyanate(MDI))) Exposure Limits/Guidelines (Con't.) Result Canada Canada Yukon Denmark Germany DFG Germany TRGS Saskatchewan 0.05 mg/m3 TWA AGW(The risk of 0.005 ppm TWA damage to the (listed under 0.005 ppm TWA; embryo or fetus can TWAs Methylene bisphenyl Not established 0.05 mg/m3 TWA Not established be excluded when AGW and BGW isocyanate(MDI)) values are observed, ceiling factor 2, Isocyanic acid, exposure factor 1) methylenedi-p- ' phenylene ester 0.02 ppm Ceiling (101-68-8) (Methylene bisphenyl isocyanate(MDI)); 0.05 mg/m3 Peak Ceilings Not established 0.2 mg/m3 Ceiling Not established (inhalable fraction) Not established (Methylene bisphenyl isocyanate(MDI)) 0.05 mg/m3 TWA MAKs Not established Not established Not established MAK(see also Not established polymeric MDI, inhalable fraction) 0.05 mg/m3 TWA AGW(The risk of damage to the embryo or fetus can Preparation Date: 18/October/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 7 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHAMS I.S.O.Twin Pack"'Insulation Adhesive Part A TWAs Not established Not established Not established Not established be excluded when AGW and BGW Polymethylene values are observed, polyphenyl inhalable fraction,as isocyanate MDI,exposure factor (9016-87-9) 1) Ceilings Not established Not established Not established 0.05 mg/m3 Peak Not established (inhalable fraction) 0.05 mg/m3 TWA MAKs Not established Not established Not established MAK(inhalable Not established fraction) Exposure Limits/Guidelines (Con't.) Result NIOSH OSHA Diphenylmethane diisocyanate (26447-40-5) Ceilings Not established 0.02 ppm Ceiling;0.2 mg/m3 Ceiling Ceilings 0.02 0.020 ppm Ceiling(10 min);0.2 mg/m3 Isocyanic acid,methylenedi-p- Ceiling(10 min) ppmCeiling;0.2 mg/m3 Ceiling phenylene ester (101-68-8) TWAs 0.005 ppm TWA(listed under Methylene Not established bisphenyl isocyanate);0.05 mg/m3 TWA Exposure Control Notations Germany TRGS •Isocyanic acid,methylenedi-p-phenylene ester(101-68-8):Carcinogens: (Category 3(as inhalable aerosol,alveola fraction))I Developmental Toxins: (Based on current data,this substance cannot be classified in categories 1-3(as inhalable aerosol,alveoli fraction))I Reproductive Toxins: (Based on current data,this substance cannot be classified in categories 1-3(as inhalable aerosol,alveola fraction))I Germ Cell Mutagens: (Based on current data,this substance cannot be classified in categories 1-3(as inhalable aerosol,alveola fraction)) •Polymethylene polyphenyl isocyanate(9016-87-9):Carcinogens: (Category 3(as inhalable aerosol,alveola fraction))I Developmental Toxins: (Based on current data,this substance cannot be classified in categories 1-3(as inhalable aerosol,alveoli fraction))I Reproductive Toxins: (Based on current data,this substance cannot be classified in categories 1-3(as inhalable aerosol,alveola fraction))I Germ Cell Mutagens: (Based on current data,this substance cannot be classified in categories 1-3(as inhalable aerosol,alveola fraction))I Skin: (skin notation(calculated as MDI)) Germany DFG •Isocyanic acid,methylenedi-p-phenylene ester(101-68-8):Carcinogens: (Category 4(no significant contribution to human cancer))I Pregnancy: (no risk to embryo/fetus if exposure limits adhered to(inhalable fraction,see also polymeric MDI))I Sensitizers: (respiratory and skin sensitizer(inhalable fraction))I Skin:(skin notation) •Polymethylene polyphenyl isocyanate(9016-87-9):Carcinogens: (Category 4(no significant contribution to human cancer))I Pregnancy: (no risk to embryo/fetus if exposure limits adhered to(inhalable fraction))I Sensitizers: (respiratory and skin sensitizer(inhalable fraction))I Skin: (skin notation) Exposure Limits Supplemental ACGIH •Isocyanic acid,methylenedi-p-phenylene ester(101-68-8):TLV Basis-Critical Effects: (respiratory sensitization(listed under Methylene bisphenyl isocyanate(MDI))) 8.2 Exposure controls Engineering • This material is designed to be used outdoors, in roofing applications. Good general Measures/Controls ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Personal Protective Equipment Respiratory • In case of insufficient ventilation, wear suitable respiratory equipment. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH or European Standard EN 149 approved respirator if exposure limits are exceeded or symptoms are experienced. Eye/Face • Wear chemical splash safety goggles. Preparation Date: 18/October/2011 Format EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 8 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS I.S.O.Twin Padcnolnsulation Adhesive Part A Skin/Body • Wear appropriate gloves. Chloroprene rubber, CR. Nitrile rubber, NBR. Butyl rubber, BR Wear appropriate chemical resistant clothing. Environmental Exposure • In case of spills, keep product clear of sewers, waterways or land areas. Dispose of Controls waste product in accordance with national and local laws and regulations. Key to abbreviations ACGIH =American Conference of Governmental Industrial Hygiene MAK =Maximale Arbeitsplatz Konzentration is the maximum permissible concentration TWAEV=Time-Weighted Average Exposure Value NIOSH=National Institute of Occupational Safety and Health TWA =Time-Weighted Averages are based on 8h/day,40h/week OSHA =Occupational Safety and Health Administration exposures Section 9 - Physical and Chemical Properties 9.1 Information on Basic Physical and Chemical Properties Material Description Off Physical Form Liquid Appearance/Description white to light amber liquid with faint aromatic odor. Color Off White-Light Amber. Odor Faint Aromatic. Odor Threshold Data lacking General Properties Boiling Point Data lacking Melting Point/Freezing Point Not relevant Decomposition Temperature Data lacking pH Data lacking Specific Gravity/Relative Density =1.12 @ 20°C(68°F)Water=1 Water Solubility Insoluble Viscosity Data lacking Explosive Properties Data lacking Oxidizing Properties: Data lacking Volatility Vapor Pressure 0 mmHg(torr) Vapor Density Data lacking Evaporation Rate Data lacking Flammability Flash Point 176°C(348.8°F) UEL Data lacking LEL 0.4% Autoignition >482°F(>250°C) Flammability(solid,gas) Data lacking Environmental Octanol/Water Partition coefficient (Data lacking I 1 9.2 Other Information • No additional physical and chemical parameters noted. Section 10: Stability and Reactivity 10.1 Reactivity • There is a potential for violent reaction if contaminated with water. 10.2 Chemical stability • Stable under normal temperatures and pressures. 10.3 Possibility of hazardous reactions • Danger of polymerization. Reacts violently with water. 10.4 Conditions to avoid • Contact with moisture, other materials that react with isocyanates, or temperatures Preparation Date: 18/October/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 9 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS • I.S.O.Twin Padc"'.Insulation Adhesive Part A above 350°F (177°C), may cause polymerization. 10.5 Incompatible materials • Reacts with amines, caustic alkali solutions, alcohols, ammonia, oxidizers, acids, polyols. Reacts with water forming carbon dioxide-may rupture sealed containers if contaminated with water. May produce violent reactions with bases and numerous organic substances including alcohols and amines. 10.6 Hazardous decomposition products • Carbon dioxide, carbon monoxide, oxides of nitrogen, dense black smoke, hydrogen cyanide, isocyanic acid, other undeterminated compounds. Section 11 -Toxicological Information 11.1 Information on toxicological effects Components Acute Toxicity: Ingestion/Oral-Rat LD50•9200 mg/kg; Behavioral:Somnolence(general depressed activity);Behavioral:Ataxia;Nutritional and Gross Metabolic:Changes in Chemistry or Temperature:Body Isocyanic acid, temperature decrease;Inhalation-Rat LC50.178 mg/m'; methylenedi-p- 101- Irritation: Eye-Rabbit•100 mg•Moderate irritation;Skin-Rabbit•500 mg 24 Hour(s); phenylene ester(25% 68-8 Mutagen: DNA adduct•Inhalation-Rat•2 mg/m3 52 Week(s)-Intermittent;Micronucleus test•Inhalation-Rat•7.1 TO 50%) mg/m'3 Hour(s);DNA adduct•Inhalation-Rat•0.002 mg/L 17 Hour(s)1 Year(s); Reproductive: Inhalation-Rat TCLo•9 mg/m'6 Hour(s)(6-15D preg);Reproductive Effects:Matemal Effects:Other effects;Reproductive Effects:Specific Developmental Abnormalities:Musculoskeletal system Acute Toxicity: Ingestion/Oral-Rat LD50•49 g/kg; Behavioral:Somnolence(general depressed activity); Gastrointestinal:Hypermotility,diarrhea; Nutritional and Gross Metabolic:Changes in Chemistry or Temperature:Body temperature decrease;Inhalation-Rat LC50•490 mg/m'4 Hour(s); Sense Organs and Polymethylene 9016- Special Senses:Eye:Other;Lungs, Thorax, or Respiration:Respiratory depression;B/ood:Hemorrhage;Skin polyphenyl isocyanate87-9 -Rabbit LD50•>9400 mg/kg; (25%TO 50%) Irritation: Eye-Rabbit•100 mg•Mild irritation; Reproductive: Inhalation-Rat TCLo• 12 mg/m'6 Hour(s)(6-15D preg);Reproductive Effects:Matemal Effects:Other effects;Reproductive Effects:Effects on Embryo or Fetus:Extra embryonic structures; Reproductive Effects:Specific Developmental Abnormalities:Musculoskeletal system GHS Properties Classification EUICLP•Acute Toxicity-Inhalation 3-ATEmix(inhI)=0.748 mg/L Acute toxicity OSHA HCS 2012•Acute Toxicity-Inhalation 2-ATEmix(inhl)=0.49 mg/L EU/CLP•Skin Irritation 2 Skin corrosion/Irritation OSHA HCS 2012•Skin Irritation 2 EU/CLP•Eye Irritation 2 Serious eye damage/Irritation OSHA HCS 2012.Eye Irritation 2 EU/CLP•Skin Sensitizer 1 Skin sensitization OSHA HCS 2012•Skin Sensitizer 1A Respiratory sensitization EU/CLP•Respiratory Sensitizer 1 OSHA HCS 2012.Respiratory Sensitizer 1A EU/CLP•Classification criteria not met Aspiration Hazard OSHA HCS 2012•Classification criteria not met Carcinogenicity EU/CLP•Carcinogenicity 2 OSHA HCS 2012•Classification criteria not met Germ Cell Mutagenicity EU/CLP•Classification criteria not met OSHA HCS 2012.Classification criteria not met Preparation Date: 18/October/2011 Format EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 Page 10 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS I.S.O.T4vin Pack^"Insulation Adhesive Part A EU/CLP•Classification criteria not met Toxicity for Reproduction OSHA HCS 2012•Classification criteria not met EU/CLP•Specific Target Organ Toxicity Single Exposure 3:Respiratory Tract Irritation STOT-SE OSHA HCS 2012•Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation STOT-RE EU/CLP•Specific Target Organ Toxicity Repeated Exposure 2 OSHA HCS 2012•Specific Target Organ Toxicity Repeated Exposure 1 Potential Health Effects Inhalation Acute (Immediate) • Toxic if inhaled. May cause respiratory irritation. Chronic (Delayed) • May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin Acute (Immediate) • Causes skin irritation. May cause skin sensitization. Symptoms include redness and skin rash. Chronic (Delayed) . No data available. Eye Acute (Immediate) • Causes serious eye irritation. Chronic (Delayed) • No data available. Ingestion Acute (Immediate) • Although swallowing this product is an unlikely means of exposure, irritation of the mouth, pharynx, esophagus and stomach can develop following ingestion. Chronic (Delayed) • No data available Other Chronic (Delayed) • Causes damage to the lungs through prolonged or repeated exposure via Inhalation. Long-term effect of Isocyanic acid, methylenedi-p-phenylene ester on the respiratory system of 318 workers suggests that such workers may develop fibrosis. Long-term exposure tends to restrict pulmonary function and cause decrease in CO single breath transfer factor. Carcinogenic Effects • May cause cancer. Key to abbreviations LC=Lethal Concentration LD=Lethal Dose TC=Toxic Concentration Section 12 - Ecological Information 12.1 Toxicity • Material data lacking. 12.2 Persistence and degradability • Material data lacking. 12.3 Bioaccumulative potential • Material data lacking. 12.4 Mobility in Soil • Material data lacking. 12.5 Results of PBT and vPvB assessment Preparation Date: 18/October/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 19/January/2018 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS Page 11 of 18 I.S.O.Twan PadOil Insulation Adhesive Part A • No PBT and vPvB assessment has been conducted. 12.6 Other adverse effects • No studies have been found. Section 13 - Disposal Considerations 13.1 Waste treatment methods Product waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 -Transport Information 1 14.1 UN 14.2 UN proper 14.3 Transport hazard 14.4 Packing 14.5 Environmental number shipping name class(es) group hazards DOT NDA Not Regulated NDA NDA NDA TDG NDA Not Regulated NDA NDA NDA IMO/IMDG NDA Not Regulated NDA NDA NDA IATA/ICAO NDA Not Regulated NDA NDA NDA 14.6 Special precautions for • None specified. user 14.7 Transport in bulk . Data lacking. according to Annex II of Marpol and the IBC Code Section 15 - Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications • Acute, Chronic State Right To Know Component CAS MA NJ PA Diphenylmethane diisocyanate 26447-40-5 Yes Yes No Isocyanic acid, methylenedi-p- 101-68-8 No No Yes phenylene ester Polymethylene polyphenyl 9016-87-9 No Yes No isocyanate Inventory Component CAS Canada DSL Canada NDSL EU EINECS EU ELNICS TSCA Diphenylmethane diisocyanate 26447-40-5 Yes No Yes No Yes Isocyanic acid, Preparation Date: 18/October/2011 Revision Date: 19/January/2018 Format EU CLP/REACH Language:English(US) Page 12 of 18 EU DSD/DPD,EU CLP,OSHA HCS 2012,WHMIS • 'Firestone TECHNICAL INFORMATION SHEET BUILDING PRODUCTS Splice Wash SW-100 Item Description Item Number Splice Wash W563587066 �Q�ttOhe erucEw + wee.aiwoes Product Information Description: Splice Wash SW-100 is designed to clean and prepare Firestone single-ply membranes to receive adhesives as specified by Firestone Specifications and Details. Method of Application: 1. Apply Splice Wash to the splicing area using a clean, white, natural fiber rag. Use a scrubbing motion until the splicing surface is clean of dirt and debris. Additional attention must be given to factory seams and where other excess accumulations of dusting agent occur. 2. Allow the washed surfaces to dry until the solvent's sheen is gone. This is usually between 10-30 minutes and may vary with ambient weather conditions. Membrane is clean when it is uniform in color without streaks, and any contaminate is gone. 3. Contact your Firestone Building Systems Advisor at 1-800-428-4511 for specific application information. Storage: • Store in original unopened pails indoors at temperatures between 60 °F -80 °F (16 °C-27 °C)away from all sources of direct heat and ignition -this is a flammable liquid. • When exposed to lower temperatures, restore to room temperature prior to use. • Keep the material out of direct sunlight until ready for immediate use. Shelf Life: Although there is no shelf life for Splice Wash, it's best to use within two years. Coverage Rate: 200-250 ft2/gallon (4.9-6.1 m2/L) on one side Precautions: • Review Safety Data Sheet (SDS) prior to use. • Flammable liquid. Store and use away form all sources of direct heat and ignition. • Cover tightly when not in use. • Thinning is not allowed. • Use of solvent-resistant Neoprene gloves is required when applying Splice Wash. Dot allow Splice Wash to come in direct contact with skin. IA n� • Avoid breathing vapors. • Do not use as a primer for any QuickSeamTM Tape products. Single-Ply QuickPrimeTM ' ri •- , Single-Ply LVOC Primer, QuickPrime Plus or QuickPrime Plus LVOC must be used for QuickSeam Tape pro••• AA Firestone Building Products I Sales:(800)428-4442 I Technical(800)428-4511 I www.firestonebpco.con0A TIS#807 611212016 Page 1 of 2 'Firestone TECHNICAL INFORMATION SHEET BUILDING PRODUCTS Splice Wash SW-100 LEED® Information: Post Consumer Recycled Content: 0% Post Industrial Recycled Content: 0% Manufacturing Location: South Bend, IN *NOTE:LEED®is a registered trademark of the U.S.Green Building Council. Packaging: 5 gallon (18.9 L) pail; about 35 lb (13.6 kg) per pail Typical Properties Property Test Method Solvents: Aliphatic Hydrocarbon Mixture Viscosity: Very thin, free flowing Weight per Gallon: 6.3 lb/gal(0.75 kg/L)(nominal) Specific Gravity: 0.75(nominal) Boiling Point: 247°F(119.4°C) V.O.C. Content: 6.21 lb/gal (745 g/L) Please contact the Quality Building Services Technical Department at 1-800-428-4511 for further information. This sheet is meant to highlight Firestone products and specifications and is subject to change without notice. Firestone takes responsibility for furnishing quality materials which meet published Firestone product specifications. Neither Firestone nor its representatives practice architecture. Firestone offers no opinion on and expressly disclaims any responsibility for the soundness of any structure. Firestone accepts no liability for structural failure or resultant damages. Consult a competent structural engineer prior to installation if the structural soundness or structural ability to properly support a planned installation is in question.No Firestone representative is authorized to vary this disclaimer. Firestone Building Products I Sales:(800)428-4442 I Technical(800)428-4511 I www.firestonebpco.com TIS#807 6/12/2016 Page 2 of 2 t` 'Firestone Firestone Building Products TECHNICAL INFORMATION SHEET UltraPly TM TPO Cut Edge Sealant Item Description Item Number Ultr4Piy"' TPO CulWhite W56TPO3001 C Sealant voc Gray W56TPOGOO1C Gray Tan W56TPOT001 C W TP00001C 1 gal(3.78 L) Product Information Description: Firestone UltraPly TPO Cut Edge Sealant is a polymer based sealant used to seal all cut edges of UltraPly TPO Membrane where the polyester reinforcement is exposed. It is available in white, gray and tan. Product Packaging Can: 1 gallon (3.78 L) Carton: Two 1 gallon (3.78 L)cans and 4 squeeze bottles Carton Weight: 46 lb(6.4 kg) Method of Application: 1. Surfaces to receive UltraPly TPO Cut Edge Sealant must be clean, dry, and free of loose and foreign materials, oil and grease. 2. Allow the welded seam to cool prior to application of UltraPly TPO Cut Edge Sealant. Seam should be cool to the touch. 3. Clean seam area with Firestone Splice Wash SW-100 prior to treating the cut edge with sealant. 4. Transfer the UltraPly TPO Cut Edge Sealant from the one gallon can into a squeeze bottle, using the attached spout. Trim the tip of the bottle to provide approximately a 1/8" (3.2 mm)opening. 5. Apply an approximate 1/8" to 1/4" (3.2 to 6.4 mm) diameter bead of sealant to all exposed recut edges of UltraPly TPO Membrane with exposed reinforcement. Storage: • Store in original unopened containers at temperatures between 60 °F and 80 °F (15.6 °C and 26.7 °C) until ready for use. • When exposed to lower temperatures, restore to room temperature prior to use. • For optimum results, rotate stock to ensure stored material has not exceeded the shelf life of one (1)year. Shelf Life: • Shelf life of one (1) year can be expected when stored in original, sealed contain r temperatures between 60 °F and 80 °F (15.6 °C and 26.7 °C). • Shelf life will be shortened if exposed to elevated temperatures for a prolonged period f Coverage Rate: VC • Ye" (3.2 mm)diameter bead: 1,500 ft/gal (457 m/3.8 L). OA • 1/4' (6.4 mm)diameter bead:400 ft/gal (122 m/3.8 L). Firestone Building Products I Sales:(800)428-44421 Technical(800)428-45111 www.flrestonebpco.com TIS#1306 08/13/2018 Page 1 of 2 'Firestone Firestone Building Products TECHNICAL INFORMATION SHEET UltraPly TM TPO Cut Edge Sealant Clean-Up: Recommended cleaner is rubbing alcohol followed by soap and water. Precautions: • Review Safety Data Sheets (SDS) prior to use. • Flammable. Keep away from fire and open flames during storage and use. Do not smoke when using. • Use only in well ventilated areas. • Cover tightly when not in use. • Do not contaminate with foreign materials. • Do not thin. • UltraPly TPO Cut Edge Sealant is not to be used for splicing or as a general purpose caulking. LEED® Information: Post-Consumer Recycled Content: 0% Post Industrial Recycled Content: 0% Manufacturing Location: South Bend, IN *NOTE:LEED®is a registered trademark of the U.S.Green Building Council. Typical Properties Property Tvolcal Performance Base: Synthetic Rubber Color: White, Gray, or Tan Solvents: Aromatic and Aliphatic Solids 24-31% Viscosity: 2,000 to 3,000 cps Weight/Gallon: _ 7.94 lb/gal (0.952 kg/L) Specific Gravity: 0.952 V.O.C. Content: 6.12 lb/gal (734 g/L) _ Please contact Firestone Technical Services Department at 1-800-428-4511 for further information. This sheet is meant to highlight Firestone products and specifications and is subject to change without notice. Firestone takes responsibility for furnishing quality materials which meet published Firestone product specifications or other technical documents, subject to normal roof manufacturing tolerances. Neither Firestone nor its representatives practice architecture. Firestone offers no opinion on and expressly disclaims any responsibility for the soundness of any structure.Firestone accepts no liability for structural failure or resultant damages. Consult a competent structural engineer prior to installation if the structural soundness or structural ability to properly support a planned installation is in question. No Firestone representative is authorized to vary this disclaimer. Firestone Building Products I Sales:(800)428-4442 I Technical(800)428-46111 www.fireatonebpco.com TIS#1306 08/13/2018 Page 2 of 2 UltraPlyTM TPO Cut Edge Sealant Mrhite Safety Data Sheet Firestone Building Products Company Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name • UltraPlyTM TPO Cut Edge Sealant White 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) . Construction 1.3 Details of the supplier of the safety data sheet Manufacturer . Firestone Building Products Company 250 West 96th Street Indianapolis, IN 46260 United States firestonemsds(a�bfdp.com Telephone (General) . 800-428-4442 1.4 Emergency telephone number Manufacturer . (800) 424-9300 - CHEMTREC Manufacturer . (703) 527-3887 - CHEMTREC - International Section 2: Hazards Identification EU/EEC According to Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP . Flammable Liquids 3 - H226 Aspiration 1 - H304 Acute Toxicity Dermal 4 - H312 Skin Irritation 2 - H315 Acute Toxicity Inhalation 4 - H332 Germ Cell Mutagenicity 1B - H340 Carcinogenicity 1B - H350 DSD/DPD . Flammable Harmful (Xn) Irritant (Xi) Mutagenic Substances - Category 2 Carcinogenic Substances - Category 2 R10, R20/21, R38, R45, R65 2.2 Label Elements CLP DANGER Preparation Date: 11/January/2012 Format:EU CLP/REACH Language:English(US) Revision Date: 09/December/2013 Page 1 of 16 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 UltraPly"'TPO Cut Edge Sealant White • Hazard statements • H226 - Flammable liquid and vapour H304- May be fatal if swallowed and enters airways H312 - Harmful in contact with skin H315- Causes skin irritation H332 - Harmful if inhaled H340 - May cause genetic defects. H350 - May cause cancer. Precautionary statements Prevention • P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. P233 - Keep container tightly closed. P240 - Ground and/or bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/equipment. P242 - Use only non-sparking tools. P243 -Take precautionary measures against static discharge. P261 -Avoid breathing mist/vapours/spray. P264 -Wash thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 -Wear protective gloves/protective clothing/eye protection/face protection. P281 - Use personal protective equipment as required. Response• P370+P378 - In case of fire: Use appropriate media for extinction. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P321 - Specific treatment, see supplemental first aid information. P362 -Take off contaminated clothing and wash before reuse. P363-Wash contaminated clothing before reuse. P332+P313- If skin irritation occurs: Get medical advice/attention. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P331 - Do NOT induce vomiting. P308+P313 - IF exposed or concerned: Get medical advice/attention. Storage/Disposal • P403+P233- Store in a well-ventilated place. Keep container tightly closed. P235 - Keep cool. P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Supplemental information • 5 percent of this product consists of an ingredient of unknown oral toxicity. 20 percent of this product consists of an ingredient of unknown inhalation toxicity. DSD/DPD Risk phrases • R10 - Flammable. R20/21 - Harmful by inhalation and in contact with skin. R38- Irritating to skin. R45 - May cause cancer. R65 - Harmful: may cause lung damage if swallowed. Safety phrases • S23 - Do not breathe gas/fumes/vapour/spray. S36 -Wear suitable protective clothing. S53 -Avoid exposure- obtain special instructions before use. 2.3 Other Hazards CLP • According to Regulation (EC) No. 1272/2008 (CLP)this material is considered hazardous. Preparation Date: 11/January/2012 Format EU CLPIREACH Language:English(US) Revision Date: 09/December/2013 Page 2 of 16 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 UltraPly"'TPO Cut Edge Sealant White DSD/DPD . According to European Directive 1999/45/EC this material is considered dangerous. United States (US) According to OSHA 29 CFR 1910.1200 HCS 2.1 Classification of the substance or mixture OSHA HCS 2012 . Flammable Liquids 3 - H226 Aspiration 1 - H304 Acute Toxicity Dermal 4 - H312 Skin Irritation 2 - H315 Eye Irritation 2 - H319 Acute Toxicity Inhalation 4 - H332 Specific Target Organ Toxicity Single Exposure 3: Respiratory Tract Irritation - H335 Specific Target Organ Toxicity Single Exposure 3, Narcotic Effects - H336 Carcinogenicity 2 - H351 Reproductive Toxicity 2 - H361 Specific Target Organ Toxicity Repeated Exposure 1 - H372 2.2 Label elements OSHA HCS 2012 DANGER i> 4 * Hazard statements . Flammable liquid and vapour- H226 May be fatal if swallowed and enters airways- H304 Harmful in contact with skin - H312 Causes skin irritation - H315 Causes serious eye irritation - H319 Harmful if inhaled - H332 May cause respiratory irritation - H335 May cause drowsiness or dizziness - H336 Suspected of causing cancer. - H351 Suspected of damaging fertility or the unborn child. - H361 Causes damage to organs- liver/kidney through prolonged or repeated exposure - H372 Precautionary statements Prevention . Obtain special instructions before use. - P201 Do not handle until all safety precautions have been read and understood. - P202 Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. - P210 Keep container tightly closed. - P233 Ground and/or bond container and receiving equipment. - P240 Use explosion-proof electrical/ventilating/lighting/equipment. - P241 Use only non-sparking tools. - P242 Take precautionary measures against static discharge. - P243 Do not breathe mist/vapours/spray. - P260 Wash thoroughly after handling. - P264 Do not eat, drink or smoke when using this product. - P270 Use only outdoors or in a well-ventilated area. - P271 Wear protective gloves/protective clothing/eye protection/face protection. - P280 Response . In case of fire: Use appropriate media for extinction. - P370+P378 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. - P304+P340 Call a POISON CENTER or doctor/physician if you feel unwell. - P312 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. - P303+P361+P353 Specific treatment, see supplemental first aid information. - P321 If skin irritation occurs: Get medical advice/attention. - P332+P313 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, Preparation Date: 11/January/2012 Format:EU CLP/REACH Language:English(US) Revision Date: 09/December/2013 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 3 of 16 UttraPly*r TPO Cut Edge Sealant White if present and easy to do. Continue rinsing. - P305+P351+P338 If eye irritation persists: Get medical advice/attention. - P337+P313 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. - P301+P310 Do NOT induce vomiting. - P331 IF exposed or concerned: Get medical advice/attention. - P308+P313 Get medical advice/attention if you feel unwell. - P314 Storage/Disposal . Store in a well-ventilated place. Keep container tightly closed. - P403+P233 Keep cool. - P235 Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. - P501 Supplemental information e 5 percent of this product consists of an ingredient of unknown toxicity. 2.3 Other hazards OSHA HCS 2012 . Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Canada According to WHMIS 2.1 Classification of the substance or mixture WHMIS . Flammable Liquids- B2 Other Toxic Effects- D2A Other Toxic Effects - D2B 2.2 Label elements WHMIS . Flammable Liquids- B2 Other Toxic Effects- D2A Other Toxic Effects- D2B 2.3 Other hazards WHMIS . In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS). Section 3 -Composition/Information on Ingredients 3.1 Substances . Material does not meet the criteria of a substance in accordance with Regulation (EC) No 1272/2008. 3.2 Mixtures Composition Chemical Identifiers % LDSOILC50 Classifications According to Comments Name Regulation/Directive Ingestion/Oral-Rat EU DSD/DPD:Annex I: R10 Xn;R20/21 Xi;R38 CAS:1330-20-7 LD50.4300 mg/kg EU CLP: Annex VI: Flam.Liq.3, H225;Acute Tox. Xylene EC 50%TO Inhalation-Rat LC50• 4, H332;Acute Tox.4, H312;Skin Irrit.2,H315 NDA Number:215- 100% 5000 ppm 4 Hour(s) OSHA HCS 2012: Flam Liq.3;Acute Tox.4 Preparation Date: 11/January/2012 Format EU CLP/REACH Language:English(US) Revision Date: 09/December/2013 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 4 of 16 UttraPly",TPO Cut Edge Sealant Mite 535 7 Skin-Rabbit LD50• (Skin);Eye brit.2;Skin Init.2;Repr.2;STOT SE 3: >1700 mg/kg Resp. brit.&Narc. EU DSDIDPD:Annex I:Carc.Cat.2; R45 Muta.Cat.2; CAS:8052-41-3 R46 Xn;R65 Stoddard EC 5%TO Inhalation Rat LC50• EU CLP: Annex VI: Muta. 1B, H340;Carc. 1B, solvent Number:232- 20% >1400 ppm 8 Hour(s) H350;Asp.Tox. 1, H304 NDA 489-3 OSHA HCS 2012: Flam.Liq. 3;Eye brit.2A;Skin Irrit.2;STOT RE 1 (Liver,Kidney);STOT SE 3: Narc.;Asp.Tox. 1 Ingestion/Oral-Rat EU DSD/DPD:Annex I: F;R11 Xn;R20 CAS:100-41-4 LD50•3500 mg/kg EU CLP: Annex VI: Flam. Liq.2, H225;Acute Tox. EC 5%TO Skin-Rabbit LD50• 4, 1-1332 Ethylbenzene NDA Number:202- 20% 17800 NL/kg OSHA HCS 2012: Flam.Liq.2;Eye Irrit.2A,Repr. 849-4 Inhalation-Rat LC50• 2.;Carc.2;STOT SE 3:Resp. Writ.;STOT SE 3: 55000 mg/m'2 Hour(s) Narc. Section 4 - First Aid Measures 4.1 Description of first aid measures Inhalation . IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. If signs/symptoms continue, get medical attention. Skin . In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Wash skin with soap and water. If skin irritation occurs: Get medical advice/attention. Eye . In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. If eye irritation persists: Get medical advice/attention. Ingestion . Get medical attention. 4.2 Most important symptoms and effects, both acute and delayed . Refer to Section 11 -Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician . All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media . LARGE FIRES: Water spray, fog or alcohol-resistant foam. SMALL FIRES: Dry chemical, CO2, water spray or alcohol-resistant foam. Unsuitable Extinguishing . Do not use a direct stream of water. Media 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion . HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Hazards Containers may explode when heated. Vapor explosion hazard indoors, outdoors or in sewers. Many liquids are lighter than water. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Runoff to sewer may create fire or explosion hazard. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Dried solids can burn and release toxic fumes and vapors. Preparation Date: 11/January/2012 Format EU CLP/REACH Language:English(US) Revision Date: 09/December/2013 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 5 of 16 UltraPlyn TPO Cut Edge Sealant White Hazardous Combustion . No data available Products 5.3 Advice for firefighters No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if you can do it without risk. Structural firefighters' protective clothing will only provide limited protection. Wear chemical protective clothing that is specifically recommended by the manufacturer. It may provide little or no thermal protection. Wear positive pressure self-contained breathing apparatus (SCBA). Section 6 -Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions . Do not walk through spilled material. Wear appropriate personal protective equipment, avoid direct contact. Do not breathe mist/vapours/spray. Avoid contact with skin, eyes, and clothing. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Emergency Procedures . ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet) Keep out of low areas. Stay upwind. Keep unauthorized personnel away. Ventilate closed spaces before entering. 6.2 Environmental precautions . Prevent entry into waterways, sewers, basements or confined areas. 6.3 Methods and material for containment and cleaning up Containment/Clean-up . Stop leak if you can do it without risk. Measures A vapor suppressing foam may be used to reduce vapors. Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use clean non-sparking tools to collect absorbed material. All equipment used when handling the product must be grounded. 6.4 Reference to other sections . Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. Section 7 - Handling and Storage 7.1 Precautions for safe handling Handling . Keep away from fire, sparks and heated surfaces. Use only in well ventilated areas. Wear appropriate personal protective equipment, avoid direct contact. Avoid contact with skin, eyes, and clothing. Do not breathe mist/vapours/spray. All equipment used when handling the product must be grounded. Prevent formation of aerosols. Bond and ground all transfer containers and equipment. Take precautionary measures against static charges. Containers, even those that have been emptied, can contain explosive vapors. Do not cut, drill, grind, weld or perform similar operations near container. Do not eat, drink or smoke when using this product. After handling wash hands thoroughly. 7.2 Conditions for safe storage, including any incompatibilities Storage . Store in a cool/low-temperature, well-ventilated place away from heat and ignition sources. Keep container tightly closed. Store away from oxidizing agents. 7.3 Specific end use(s) . Refer to Section 1.2 - Relevant identified uses. Preparation Date: 11/January/2012 Format:EU CLP/REACH Language:English(US) Revision Date: 09/December/2013 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 6 of 16 'Firestone Firestone Building Products TECHNICAL INFORMATION SHEET UltraPlyTM TPO Membrane Item Description Item Number 1 Roll Various Meets or exceeds ASTM D 6878. Product Information Description: Firestone UltraPly TPO is a flexible Thermoplastic Polyolefin roofing membrane that is produced with polyester weft- inserted reinforcement. UltraPly TPO membrane meets or exceeds all requirements for ASTM D 6878 Specification. This heat weldable TPO membrane is available in 45 mil (1.14 mm) and 60 mil (1.52 mm) thicknesses. This reflective membrane is suitable for a variety of low-slope applications. Method of Application: 1. Substrates must be clean, dry, smooth, and free of sharp edges, fins, loose or foreign materials, oil, grease, and other materials that may damage the membrane. 2. All roughened surfaces that can damage the membrane shall be repaired as specified to offer a smooth substrate. 3. All surface voids greater than 'A" (6.3 mm)wide shall be properly filled with an acceptable fill material. 4. Firestone UltraPly TPO membrane is installed as continuous roofing or waterproofing layer on the roof. Rolls are overlapped (side laps and end laps) prior to the heat welding of the seam areas. 5. Install the UltraPly TPO Roofing System in accordance with current Firestone UltraPly TPO specifications, details and workmanship requirements. Storage: • Store away from sources of punctures and physical damage. • Assure that structural decking will support the loads incurred by material when stored on rooftop. The deck load limitations should be specified by the project designer. • Store away from ignition sources as membrane will burn when exposed to open flame. Precautions: • Refer to Safety Data Sheets (SDS)for safety information. • Exercise caution when lifting, moving, transporting, storing or handling mie rolls to avoid sources of punctures and possible physical damage. • Contact your Building Systems Advisor at 1-800-428-4511 for specific recomn'tens regarding chemical or waste product compatibility with Firestone UltraPly TPO Membrane. " LEED® Information: ki �pss�f�� Post Consumer Recycled Content: 0% ® •)4=i v APPROVED Pre-Consumer Recycled Content: 15% cViej US Manufacturing Location: Wellford, SC APPROVED Tuscumbia, AL ICC-ES NOTE:LEED®is a registered trademark of the U.S. Green Building Council. ESR-2831 CCMC 13348-R Firestone Building Products I Sales:(800)428-4442 I Technical(800)428-4511 I www.firestonebpco.com TIS#201 4/23/2018 Page 1 of 3 'Firestone Firestone Building Products TECHNICAL INFORMATION SHEET UltraPlyTM TPO Membrane Typical Properties (Meets or exceeds ASTM D 6878 Specification) Property ASTM Performance Typical Performance Typical Performance Standard Minimum 45 mil 60 mil Overall Thickness: D 751 0.039"(1 mm) 0.045"(1.14 mm)± 10% 0.060"(1.52 mm)± 10% Coating over Scrim: D 7635 0.015"(0.38 mm) 0.017"(0.43 mm) 0.021"(0.53 mm) Breaking Strength: D 751, Grab 245 lbf(979 N) 340 lbf(1,512 N) 390 lbf(1,735 N) Method Elongation of Reinforcement Break: D 751, Grab 15% 25% 25% Method Tearing Strength: D 751 55 lbf(245 N) 120 lbf(534 N) 120 lbf(534 N) Brittleness Point: D 2137 -40°F(-40°C) Pass Pass Ozone Resistance, No Cracks: D 1149 Pass(No Cracks) Pass Pass Properties After Heat Aging (Retained Values) (ASTM D 573-5376 h (224 days or 32 weeks)at 240 °F (116°C)): Breaking Strength: D 751, Grab 90%Minimum >90% >90% . Method • Elongation at Break: D 751, Grab 90%Minimum >90% >90% Method Tearing Strength: D 751 60% Minimum >60% >60% Weight of Change: ± 1%Maximum < 1% < 1% Linear Dimension Change: D 1204,6 h at ±1%Maximum < 1% < 1% 158°F(70°C) • Water Absorption: D 471 ±3%Maximum <3% <3% Weather Resistance, 80°C Black Panel, no cracking,crazing when wrapped G 155 10,080 kJ/m2 >60,000 kJ/m2 >60,000 kJ/m2 around a 3"mandrel and inspected at 7X Minimum magnification: Puncture Resistance: FTM 101C, --- 265(1,180) 300(1,300) . Method 2031 Dynamic Puncture Resistance MD: D 5635 --- Pass(20 J) Pass(40 J) Dynamic Puncture Resistance CD: D 5635 --- Pass(35 J) Pass(50 J) • Static Puncture Resistance: D 5602 --- Pass(25 kg) Pass(25 kg) Air Permeance(Material): E 2178* <0.004 ft'/ft2 Pass Pass (0.02 U(s*m2) *The ASTM 2178 values listed are for the air permeance of the UltraPly TPO Membrane component only. For use of the product as a component in an air barrier assembly, please consult your Firestone Building Systems Advisor(BSA), Code Agency or Authority having Jurisdiction(AHJ)for the acceptable air barrier assembly details. Firestone Building Products I Sales:(800)428-4442 I Technical(800)428-4511 I www.firestonebpco.com TIS#201 4/23/2018 Page 2 of 3 Firestone Firestone Building Products TECHNICAL INFORMATION SHEET UltraPlyTM TPO Membrane Product Sizes Membrane Thickness:0.045"(1.14 mm) Membrane Thickness: 0.060"(1.52 mm) Membrane Weight: 0.23 lb/ft2(1.1 kg/m2) Membrane Weight:0.31 lb/ft2(1.5 kg/m2) Available Sizes Available Colors Available Sizes Available Colors 5'x 100' (1.5 x 30.5 m) White,Tan, Gray 5'x 100' (1.5 x 30.5 m) White, Tan, Gray 5'x 200' (1.5 x 61 m) White 5'x 200' (1.5 x 61 m) White 6'2"x 100' (1.9 x 30.5 m) White, Tan, Gray 6'2"x 100' (1.9 x 30.5 m) White, Tan, Gray 8'x 100' (2.4 x 30.5 m) White, Tan, Gray 8'x 100' (2.4 x 30.5 m) White,Tan, Gray 8'x 200' (2.4 x 61 m) White 8'x 200' (2.4 x 61 m) White 10'x 100' (3.0 x 30.5 m) White,Tan, Gray 10'x 100' (3.0 x 30.5 m) White, Tan, Gray 10'x 200' (3.0 x 61 m) White 10'x 200' (3.0 x 61 m) White 12'4"x 100' (3.8 x 30.5 m) White,Tan, Gray 12'4"x 100' (3.8 x 30.5 m) White,Tan, Gray 12'4"x 200' (3.8 x 61 m) White 12'4"x 200' (3.8 x 61 m) White Radiative Properties Cool Roof Rating Council(CRRC): Initial 13 yr White Tan Gray Solar Reflectance 0.79/0.68 0.61 /0.55 0.34/0.34 Thermal Emittance 0.85/0.83 0.81 /0.84 0.89/0.88 Solar Reflectance Index(SRI) 98/81 71 /63 37/36 Rated Product ID 0008 0015 0032 Licensed Manufacturer ID 0608 0608 0608 Classification Production Line Production Line Production Line ENERGY STAR®: Initial/3 yr White Solar Reflectance 0.79/0.78* --- --- Thermal Emittance 0.85 *White membrane sample cleaned prior to age test. LEED® White Tan Gray Solar Reflectance-ASTM E 903 0.81 0.63 0.37 Thermal Emittance-ASTM E 408 0.95 0.95 0.95 Solar Reflectance Index(SRI)-ASTM E 1980 102 77 43 /� Tarestone 1:- ENERGY STAR is only CHARTER ENERGY STAR valid in the United States Please contact Firestone Technical Services Department at 1-800-428-4511 for further information. This sheet is meant to highlight Firestone products and specifications and is subject to change without notice. Firestone takes responsibility for furnishing quality materials which meet published Firestone product specifications. Neither Firestone nor its representatives practice architecture. Firestone offers no opinion on and expressly disclaims any responsibility for the soundness of any structure. Firestone accepts no liability for structural failure or resultant damages. Consult a competent structural engineer prior to installation if the structural soundness or structural ability to properly support a planned installation is in question. No Firestone representative is authorized to vary this disclaimer. Firestone Building Products I Sales:(800)428-4442 I Technical(800)428-4511 I www.firestonebpco.com TIS#201 4/23/2018 Page 3 of 3 UltraPlyTM TPO Membrane&Flashing Series Safety Data Sheet Firestone Building Products Company Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name • UltraPlyTM TPO Membrane & Flashing Series Synonyms . UltraPlyTM TPO 18" Curb Flashing, UltraPlyTM TPO Custom Accessories, UltraPlyTM TPO Reinforced Split Pipe Boot, UltraPlyTM TPO Walkway Pad, UltraPlyTM TPO T- Joint Cover; UltraPlyTM TPO Inside/Outside Molded Corner, UltraPlyTM TPO Universal Pipe Flashing, UltraPlyTM TPO Large Pipe Flashing, UltraPlyTM TPO Unsupported Flashing, UltraPlyT'" TPO Coated Metal; UltraPlyT"" TPO Membrane, UltraPlyTM TPO XR T Membrane, UltraPlyTM TPO Platinum TM Membrane, UltraPlyTM TPO Reinforced Cover Strip, UltraPlyTM TPO Reinforced Curb Corner 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) . Construction:Roofing Material 1.3 Details of the supplier of the safety data sheet Manufacturer . Firestone Building Products Company 250 West 96th Street Indianapolis, IN 46260 United States firestonemsds@bfdp.com Telephone (General) . 800-428-4442 1.4 Emergency telephone number Manufacturer . (800) 424-9300 - CHEMTREC Manufacturer . (703) 527-3887 - CHEMTREC - International Section 2: Hazards Identification EU/EEC According to EU Directive 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP . Not classified DSD/DPD . Not classified 2.2 Label Elements CLP Hazard statements . No label element(s) required DSD/DPD Risk phrases . No label element(s) required 2.3 Other Hazards Preparation Date: 15/August/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 07/May/2013 WHMIS,EU DSD/DPD,EU CLP,OSHA HCS 2012 Page 1 of 12 UltraPly"'TPO Membrane&Flashing Series CLP . This material is exempt from CLP/REACH obligations as an article as specified in REACH (1907/2006) and related ECHA guidance. DSD/DPD . Under European Directive 1999/45/EC these product(s) are exempt and considered manufactured article(s) under stated normal conditions of use. United States (US) According to OSHA 29 CFR 1910.1200 HCS 2.1 Classification of the substance or mixture OSHA HCS 2012 . Not classified 2.2 Label elements OSHA HCS 2012 Hazard statements . No label elements(s) required 2.3 Other hazards OSHA HCS 2012 . Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard) this product is exempt as an article under stated normal conditions of use. Canada According to WHMIS 2.1 Classification of the substance or mixture WHMIS . Not classified 2.2 Label elements WHMIS . No label element(s) required 2.3 Other hazards WHMIS . Under Canadian regulations (Workplace Hazardous Materials Information System (WHMIS) - Hazardous Products Act (HPA), Section 11(1)), these product(s) are exempt and considered manufactured article(s) under stated normal conditions of use. 2.4 Other information . This material, as an article, does not legally require an SDS. See Section 12 for Ecological Information. Section 3 - Composition/Information on Ingredients 3.1 Substances . Material does not meet the criteria of a substance in accordance with Regulation (EC) No 1272/2008. 3.2 Mixtures Non-Hazardous Components Chemical Name Identifiers %(weight) LD50/LC50 Classifications According to Regulation/Directive Comments EU DSD/DPD: None Nonhazardous Components NDA 100% NDA EU CLP: None NDA Preparation Date: 15/August/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 07/May/2013 WHMIS,EU DSD/DPD,EU CLP,OSHA HCS 2012 Page 2 of 12 UltraPIyTM TPO Membrane&Flashing Series I OSHA HCS 2012: None I I See Section 11 for Toxicological Information. Section 4 - First Aid Measures 4.1 Description of first aid measures Inhalation . First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. If signs/symptoms develop, move person to fresh air. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. If signs/symptoms continue, get medical attention. Skin . First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. Wash skin with soap and water. If signs/symptoms develop, get medical attention. Eye . First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. If contact with material occurs flush eyes with water. If signs/symptoms develop, get medical attention. Ingestion . First aid is not expected to be necessary if material is used under ordinary conditions and as recommended. If signs/symptoms develop, get medical attention. 4.2 Most important symptoms and effects, both acute and delayed . Refer to Section 11 - Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician . All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media . Water, foam, dry chemical, carbon dioxide (CO2). Unsuitable Extinguishing . None known. Media 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion . Does not present any special fire or explosive hazards. Hazards Hazardous Combustion . Upon reaching temperatures of combustion, produces corrosive and/or toxic fumes. Products 5.3 Advice for firefighters . Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA)with a full face-piece operated in positive pressure mode. Structural firefighters' protective clothing will only provide limited protection. Section 6 -Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions . No special precautions expected to be necessary if material is used under ordinary conditions and as recommended. Emergency Procedures . No emergency procedures are expected to be necessary if material is used under ordinary conditions as as recommended. Use normal clean up procedures. Preparation Date: 15/August/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 07/May/2013 WHMIS,EU DSD/DPD,EU CLP,OSHA HCS 2012 Page 3 of 12 UltraPly,"TPO Membrane&Flashing Series 6.2 Environmental precautions . No special precautions necessary. 6.3 Methods and material for containment and cleaning up Containment/Clean-up . Pick up pieces and place in container or bag for disposal. Measures 6.4 Reference to other sections . Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. Section 7 - Handling and Storage 7.1 Precautions for safe handling Handling . Use good safety and industrial hygiene practices. 7.2 Conditions for safe storage, including any incompatibilities Storage . Store in a cool, dry, well-ventilated place. 7.3 Specific end use(s) . Refer to Section 1.2 - Relevant identified uses. Section 8 - Exposure Controls/Personal Protection 8.1 Control parameters Exposure Limits/Guidelines . No exposure limits/guidelines available for the material or the components. 8.2 Exposure controls Engineering . Under normal conditions of use, special ventilation is not required. Measures/Controls Personal Protective Equipment Respiratory . No respiratory protection is required under normal conditions of use. Eye/Face . Under normal conditions of use, eye protection is not required. Skin/Body . No skin protection is ordinarily required under normal conditions of use. Environmental Exposure . Follow best practice for site management and disposal of waste. Controls Key to abbreviations STEL =Short Term Exposure Limits are based on 15-minute exposures ACGIH=American Conference of Governmental Industrial Hygiene STEV =Short Term Exposure Value NIOSH=National Institute of Occupational Safety and Health TWAEV=Time-Weighted Average Exposure Value OSHA =Occupational Safety and Health Administration TWA _Time-Weighted Averages are based on 8h/day,40h/week exposures Section 9 - Physical and Chemical Properties 9.1 Information on Physical and Chemical Properties Material Description Black and white sheet,white and I (gray sheet,tan and gray sheet, Preparation Date: 15/August/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 07/May/2013 WHMIS,EU DSD/DPD,EU CLP,OSHA HCS 2012 UltraPIyTM TPO Membrane&Flashing Series Physical Form Solid Appearance/Description gray and gray sheet,white sheet with fleece back membrane,white sheet, grey sheet,or tan sheet. Essentially no odor. Color _Black,white,gray,and tan. Odor None • Odor Threshold None General Properties Boiling Point Not relevant Melting Point Data lacking Decomposition Temperature Data lacking pH Not relevant Specific Gravity/Relative Density 0.94 Water=1 Water Solubility Insoluble Viscosity Not relevant Explosive Properties Not relevant. Oxidizing Properties: Not relevant. Volatility Vapor Pressure Not relevant Vapor Density Not relevant Evaporation Rate Not relevant _ Flammability Flash Point ...Not relevant UEL Not relevant LEL Not relevant Autoignition Not relevant Flammability(solid,gas) Not flammable. Environmental Octanol/Water Partition coefficient 'Data lacking I I 9.2 Other Information . No additional physical and chemical parameters noted. Section 10: Stability and Reactivity 10.1 Reactivity . No dangerous reaction known under conditions of normal use. 10.2 Chemical stability . Stable under normal temperatures and pressures. 10.3 Possibility of hazardous reactions . Hazardous polymerization will not occur. 10.4 Conditions to avoid . No data available 10.5 Incompatible materials . No data available. 10.6 Hazardous decomposition products . Thermal decomposition could produce CO, CO2, and Oxides of Nitrogen. Section 11 -Toxicological Information 11.1 Information on toxicological effects Other Material Information . This material is an article that does not release or otherwise result in exposure to a hazardous chemical under normal use. The information provided below is for components only and is not expected to be applicable to the material as a whole. Preparation Date:15/August/2011 Format:EU CLP/REACH Language:English(US) Revision Date:07/May/2013 WHMIS,EU DSD/DPD,EU CLP,OSHA HCS 2012 Page 5 of 12 • UltraPly"'TPO Membrane&Flashing Series GHS Properties Classification EU/CLP•Not relevant Acute toxicity OSHA HCS 2012•Not relevant EU/CLP•Not relevant Aspiration Hazard OSHA HCS 2012•Not relevant Carcinogenicity EU/CLP•Not relevant OSHA HCS 2012•Not relevant Germ Cell Mutagenicity EU/CLP•Not relevant OSHA HCS 2012•Not relevant EU/CLP•Not relevant Skin corrosion/Irritation OSHA HCS 2012•Not relevant Skin sensitization EU/CLP•Not relevant OSHA HCS 2012•Not relevant EU/CLP•Not relevant STOT-RE OSHA HCS 2012•Not relevant EU/CLP•Not relevant STOT-SE OSHA HCS 2012•Not relevant EU/CLP•Not relevant Toxicity for Reproduction OSHA HCS 2012•Not relevant EU/CLP•Not relevant Respiratory sensitization OSHA HCS 2012•Not relevant Serious eye damage/Irritation EU/CLP•Not relevant OSHA HCS 2012•Not relevant Potential Health Effects Inhalation Acute (Immediate) . Under normal conditions of use, no health effects are expected. Chronic (Delayed) . Under normal conditions of use, no health effects are expected. Skin Acute (Immediate) . Under normal conditions of use, no health effects are expected. Chronic (Delayed) • Under normal conditions of use, no health effects are expected. Eye Acute (Immediate) • Under normal conditions of use, no health effects are expected. Chronic (Delayed) . Under normal conditions of use, no health effects are expected. Ingestion Acute (Immediate) . Under normal conditions of use, no health effects are expected. Chronic (Delayed) • Under normal conditions of use, no health effects are expected. Section 12 - Ecological Information 12.1 Toxicity . Material data lacking. 12.2 Persistence and degradability Preparation Date: 15/August/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 07/May/2013 WHMIS,EU DSD/DPD,EU CLP,OSHA HCS 2012 Page 6 of 12 UltraPIyTM TPO Membrane&Flashing Series . Material data lacking. 12.3 Bioaccumulative potential . Material data lacking. 12.4 Mobility in Soil . Material data lacking. 12.5 Results of PBT and vPvB assessment . PBT and vPvB assessment has not been carried out. 12.6 Other adverse effects . Material data lacking. Section 13 - Disposal Considerations 13.1 Waste treatment methods Product waste . Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste . Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 -Transport Information 14.1 UN 14.2 UN proper 14.3 Transport hazard 14.4 Packing 14.5 Environmental number shipping name class(es) group hazards DOT NDA Not Regulated NDA NDA NDA TDG NDA Not Regulated NDA NDA NDA IMO/IMDG NDA Not Regulated NDA NDA NDA ADN NDA Not Regulated NDA NDA NDA ADR/RID NDA Not Regulated NDA NDA NDA IATA/ICAO NDA Not Regulated NDA NDA NDA 14.6 Special precautions for . None known. user 14.7 Transport in bulk . Not relevant. according to Annex II of MARPOL 73/78 and the IBC Code Section 15 - Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications . None Preparation Date: 15/August/2011 Format:EU CLP/REACH Language:English(US) Revision Date:07/May/2013 WHMIS,EU DSD/DPD,EU CLP,OSHA HCS 2012 Page 7 of 12 Firestone Firestone Building Products TECHNICAL INFORMATION SHEET UltraPlyTM Bonding Adhesive Item Description Item Number Bonding Adhesive W56TP03005 rtri . :ir e UltraPly gaodimg Adhewve 'V56 TPO-3005 Product Information Description: Firestone UltraPly Bonding Adhesive is a solvent based contact adhesive designed specifically for bonding Firestone UltraPly TPO membranes to approved insulations in addition to wood, metal, masonry and other acceptable substrates. NOTE: Not for use in adhering UltraPly TPO XR membranes. Method of Application: 1. Surfaces to receive Firestone UltraPly Bonding Adhesive must be clean, smooth, dry, and free of sharp edges, loose and foreign materials, oil, grease, and other contaminants. 2. Stir the adhesive thoroughly to achieve a uniform mix with no sediment on the bottom and no marbling evident before and during use. 3. Apply UltraPly Bonding Adhesive at about the same time to both the exposed underside of the sheet and the substrate to which it will be adhered so as to allow approximately the same drying time. Apply UltraPly Bonding Adhesive evenly avoiding areas of accumulation. 4. Apply the UltraPly Bonding Adhesive with a solvent resistant paint roller, and roll the adhesive onto the mating surfaces. When applying UltraPly Bonding Adhesive, ensure complete uniform coverage of both surfaces that will be adhered. Care must be taken not to apply Bonding Adhesive over seam areas. 5. UltraPly Bonding Adhesive can be dispensed by means of power rollers or industrial spray equipment. Other equipment may be used as recommended by the manufacturer for application of this adhesive. NOTE: Spray applied bonding adhesive requires back-rolling with 9" (228.6 mm)wide solvent resistant roller(medium nap)to insure 100% coverage of the adhesive on the substrate and membrane. 6. Allow Bonding Adhesive to flash off until tacky. Touch down on the Bonding Adhesive surface with a clean, dry finger to be certain that the adhesive does not string. As you are touching the adhesive, pushing straight down to check for stringing, also push forward on the adhesive at an angle to ensure that the adhesive solvents have flashed off and are ready throughout its thickness. If either motion exposes wet areas or sticking when the finger is lifted, then it is not ready for mating. Flash off time will vary depending on ambient conditions. 7. Starting at the fold, roll the previously coated portion of the sheet into the coated substrate slowly and evenly so as to maintain position and minimize wrinkles. 8. To ensure proper contact, compress the bonded half of the sheet to the substrate withAstiff push broom using heavy pressure immediately after mating. 9. Contact your Firestone Technical Services Advisor at 1-800-428-4511 for specific application i ation. Storage: • Store in original unopened containers at temperatures between 60 °F - 80 °F (16 °C -27 °C) until reidyf)r use. • For optimum results, rotate stock to ensure stored material has not exceeded the shelf life of one year. #,OL. Firestone Building Products I Sales:(800)428-4442 I Technical(800)428-4511 !www.flrestonebpco.com TIS#808 0811312018 Page 1 of 3 'Firestone Firestone Building Products TECHNICAL INFORMATION SHEET UltraPlyTM Bonding Adhesive Shelf Life: Shelf life of one year can be expected if stored in original sealed container at temperatures between 60 °F - 80 °F (16 °C - 27 °C). If exposed to lower temperatures, restore to room temperature prior to use. Shelf life will be shortened if exposed to elevated temperatures for a prolonged period of time. Coverage: A coverage rate of 45 - 60 ft2 per gallon (1.10 — 1.47 m2 per liter) may be obtained depending on the substrate. Some insulation surfaces are more uneven and porous and will result in a lower coverage rate while smooth non-porous substrates will result in higher coverage rates. Rates are based on roller application to both mating surfaces. Very porous substrates (rough wood, concrete block) may require two coats of UltraPly Bonding Adhesive, to ensure proper adhesion. This can be determined by testing a small area. Check by adhering a small piece of membrane to the porous substrate to verify the bonding strength. Precautions: • Review applicable Safety Data Sheet(SDS) prior to using. • Flammable. Keep away from fire and open flame and other possible ignition sources during storage and use. Do not smoke when using. • Harmful or fatal if swallowed. • Avoid prolonged inhalation. • Avoid prolonged contact with skin. Gloves should be worn (OSHA approved). • Avoid eye contact by wearing safety goggles with side shields. • Thinning is not allowed. • Do not use for splicing. • Do not use with EPDM or XR membranes. • Use only in well ventilated areas. • Cover tightly when not in use. • Recommended cleaner is Toluene (while fluid). Typical Properties Promrty Minimum Performance Base A blend of Polychloroprene and SBR rubbers Color Yellow Solvents A blend of Acetone, Hexane, Toluene and Xylene Solids >_ 23 Viscosity 3,300-3,800 cps,with R.V.F. spindle @ 10 rpm Weight/Gallon 6.6-7.4 lb/gal Specific Gravity 0.7909-0.8868 V.O.C. Content 5.282 lb/gal (633 g/L) Firestone Building Products I Sales:(800)428-44421 Technical(800)428-4511 i www.firestonebpco.com TIS#808 08/13/2018 Page 2 of 3 Firestone Firestone Building Products TECHNICAL INFORMATION SHEET UltraPlyTM Bonding Adhesive NAssipb. LEED® Information: 11> MANMADE COUNTY APPROVED C US Post-Consumer Recycled Content: 0% APPROVED Post Industrial Recycled Content: 0% Manufacturing Location: South Bend, IN 'NOTE: LEED®is a registered trademark of the U.S.Green Building Council. Packaging: • Available in 5 gallon (18.9 L) pail • Each pail weighs about 41 lb (18.6 kg) Approved Power Equipment: Garlock 25ST Roller Boss Power Roller LI* l 1 4 hp Honda Engine, 4 CFM Compressor, 25 gal pressurized supply tank (20 gal for material; 60-80 psi), Up to 100 psi rating, 4, ;. •' 2 — 3/4" x 30' supply hoses with swivels, 2 — 18" roller head assemblies Garlock 2120 Commander Sprayer 18 hp Kohler Engine, 4500 psi Rating, 5 Gallon per Minute Flow, 1200 psi Pressure (minimum), Pump Displacement 45:1, GPM - Rating: up to 5 gpm, 1/2' x 100' hose, 2" Intake pipe with screen, .. i 5 or 55 gal drum containers, Graco Spray Tip: .023 to .031 diameter hose Garlock Twin Gun Airless Sprayer 6.5 hp Honda Engine, 3000 psi Rating, Pump Displacement 30:1, GPM Rating: up to 1 gpm, Up to 400' of single 1/2" diameter hose, Up to 200' of dual 1/2' diameter hose, 3/4" Intake pipe with 1:11t screen, 5 or 55 gal drum containers, Bulk tank containers, Graco 17'--Ad. Spray Tip: .019 to .025 diameter hose (1850 psi operating pressure) • s Graco Spray Equipment: P7OEC4-70 — 70:1 Xtreme Sprayer Package w/Heavy Duty car, Hopper package, w/NXT motor and Data Track, Xtreme-Duty high pressure hose, %" x 50', 7250 psi, with 1/4" x 6' whip hose, XTR-7 applicator with XHD821-825 tip 1111 Please contact Firestone Technical Services Department at 1-800-428-4511 for further information. This sheet is meant to highlight Firestone products and specifications and is subject to change without notice. Firestone takes responsibility for furnishing quality materials which meet published Firestone product specifications. Neither Firestone nor its representatives practice architecture Firestone offers no opinion on and expressly disclaims any responsibility for the soundness of any structure. Firestone accepts no liability for structural failure or resultant damages. Consult a competent structural engineer prior to installation if the structural soundness or structural ability to properly support a planned installation is in question.No Firestone representative is authorized to vary this disclaimer. Firestone Building Products I Sales:(800)428-4442 I Technical(800)428-4511 I www.firestonebpco.com TIS#808 08/13/2018 Page 3 of 3 UltraPly Bonding Adhesive Safety Data Sheet Firestone Building Products Company Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name • UltraPly Bonding Adhesive Synonyms . TPO Bonding Adhesive 5G; UltraPly TPO Bonding Adhesive SDS Number/Grade . FS-025 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) . Adhesive 1.3 Details of the supplier of the safety data sheet Manufacturer . Firestone Building Products Company 250 West 96th Street Indianapolis, IN 46260 United States firestonemsds@bfdp.com Telephone (General) . 800-428-4442 1.4 Emergency telephone number Manufacturer . (800) 424-9300 - CHEMTREC Manufacturer . (703) 527-3887 - CHEMTREC - International Section 2: Hazards Identification EU/EEC According to Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP . Flammable Liquids 2 - H225 Skin Irritation 2 - H315 Eye Irritation 2 - H319 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects - H336 Reproductive Toxicity 2 - H361d Specific Target Organ Toxicity Repeated Exposure 2 - H373 Hazardous to the aquatic environment Chronic 3 - H412 DSD/DPD . Highly Flammable (F) Irritant (Xi) Harmful (Xn) Substances Toxic To Reproduction - Category 3 R11, R38, R48/20, R63, R65, R67, R52, R53 2.2 Label Elements CLP DANGER Preparation Date: 07/February/2013 Format:EU CLP/REACH Language:English(US) Revision Date 30/December/2014 WHMIS.EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 1 of 16 UltraPly Bonding Adhesive 4 Hazard statements • H225 - Highly flammable liquid and vapour H315 - Causes skin irritation H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H361d - Suspected of damaging the unborn child. H373 - May cause damage to organs- Central Nervous System (CNS) through prolonged or repeated exposure via Inhalation H412 - Harmful to aquatic life with long lasting effects Precautionary statements Prevention • P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. P233 - Keep container tightly closed. P240 - Ground and/or bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting/equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe mist, vapours, spray. P264 - Wash thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P273 - Avoid release to the environment. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P281 - Use personal protective equipment as required. Response • P370+P378 - In case of fire: Use appropriate media for extinction. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P321 - Specific treatment, see supplemental first aid information. P332+P313 - If skin irritation occurs: Get medical advice/attention. P362 -Take off contaminated clothing and wash before reuse. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337+P313 - If eye irritation persists: Get medical advice/attention. P314 - Get medical advice/attention if you feel unwell. P308+P313 - IF exposed or concerned: Get medical advice/attention. Storage/Disposal • P235 - Keep cool. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P501 - Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Supplemental information • 25-35 percent of this product consists of an ingredient of unknown toxicity. DSD/DPD X X, gym Risk phrases • R11 - Highly flammable. R38 - Irritating to skin. R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation. R50 - Very toxic to aquatic organisms. R51 - Toxic to aquatic organisms. R52 - Harmful to aquatic organisms. R53 - May cause long-term adverse effects in the aquatic environment. R62 - Possible risk of impaired fertility. R63 - Possible risk of harm to the unborn child. R65- Harmful: may cause lung damage if swallowed. Preparation Date: 07/Februaryl2013 Format:EU CLP/REACH Language:English(US) Revision Date: 30/December/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 2 of 16 UltraPly Bonding Adhesive R67 - Vapours may cause drowsiness and dizziness. Safety phrases • S9 - Keep container in a well ventilated place S16 - Keep away from sources of ignition - No Smoking. S37 - Wear suitable gloves. S57 - Use appropriate containment to avoid environmental contamination. 2.3 Other Hazards CLP • According to Regulation (EC) No. 1272/2008 (CLP) this material is considered hazardous. DSD/DPD . According to European Directive 1999/45/EC this preparation is considered dangerous. United States (US) According to OSHA 29 CFR 1910.1200 HCS 2.1 Classification of the substance or mixture OSHA HCS 2012 • Flammable Liquids 2 - H225 Acute Toxicity Oral 4 - H302 Skin Irritation 2 - H315 Eye Irritation 2A - H319 Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects - H336 Carcinogenicity 2 - H351 Reproductive Toxicity 2 - H361 Specific Target Organ Toxicity Repeated Exposure 2 - H373 2.2 Label elements OSHA HCS 2012 DANGER 0 4 Hazard statements • Highly flammable liquid and vapour- H225 Harmful if swallowed - H302 Causes skin irritation - H315 Causes serious eye irritation - H319 May cause drowsiness or dizziness - H336 Suspected of causing cancer. - H351 Suspected of damaging fertility or the unborn child. - H361 May cause damage to organs (Central Nervous System/CNS) through prolonged or repeated exposure - H373 Precautionary statements Prevention • Obtain special instructions before use. - P201 Do not handle until all safety precautions have been read and understood. - P202 Keep away from heat, sparks, open flames and/or hot surfaces. - No smoking. - P210 Keep container tightly closed. - P233 Ground and/or bond container and receiving equipment. - P240 Use explosion-proof electrical/ventilating/lighting/equipment. - P241 Use only non-sparking tools. - P242 Take precautionary measures against static discharge. - P243 Do not breathe mist, vapours, spray. - P260 Wash thoroughly after handling. - P264 Do not eat, drink or smoke when using this product. - P270 Use only outdoors or in a well-ventilated area. - P271 Wear protective gloves/protective clothing/eye protection/face protection. - P280 Response • In case of fire: Use appropriate media for extinction. - P370+P378 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. - P304+P340 Call a POISON CENTER or doctor/physician if you feel unwell. - P312 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with Preparation Date: 07/February/2013 Format:EU CLP/REACH Language:English(US) Revision Date: 30/December/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 3 of 16 UltraPly Bonding Adhesive water/shower. - P303+P361+P353 Specific treatment, see supplemental first aid information. - P321 Take off contaminated clothing and wash before reuse. - P362 If skin irritation occurs: Get medical advice/attention. - P332+P313 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. - P305+P351+P338 If eye irritation persists: Get medical advice/attention. - P337+P313 Rinse mouth. - P330 Get medical advice/attention if you feel unwell. - P314 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. - P309+P311 Storage/Disposal . Keep cool. - P235 Store in a well-ventilated place. Keep container tightly closed. - P403+P233 Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. - P501 Supplemental information . 25-35 percent of this product consists of an ingredient of unknown toxicity. 2.3 Other hazards OSHA HCS 2012 . Under United States Regulations (29 CFR 1910.1200 - Hazard Communication Standard), this product is considered hazardous. Canada According to WHMIS 2.1 Classification of the substance or mixture WHMIS • Flammable Liquids - B2 Other Toxic Effects - D2A Other Toxic Effects - D2B 2.2 Label elements WHMIS 42) 0 . Flammable Liquids - B2 Other Toxic Effects - D2A Other Toxic Effects - D2B 2.3 Other hazards WHMIS . In Canada, the product mentioned above is considered hazardous under the Workplace Hazardous Materials Information System (WHMIS). 2.4 Other information NFPA F.r nstlnrf I2 0 I M;a,1h SpaVai See Section 12 for Ecological Information. Section 3 - Composition/Information on Ingredients 3.1 Substances Preparation Date: 07/February/2013 Format:EU CLP/REACH Language:English(US) Revision Date: 30/December/2014 _ WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Wage4uf1S UltraPly Bonding Adhesive • Material does not meet the criteria of a substance in accordance with Regulation (EC) No 1272/2008. 3.2 Mixtures Composition Chemical Name Identifiers % LD50/LC50 Classifications According to Comments Regulation/Directive EU DSDIDPD: Annex I:F, R11;Repr.Cat.3,R63; Ingestion/Oral-Rat Xn,R48/20-65;Xi,R38, R67 CAS:108-88-3 LD50.636 mg/kg EU CLP: Annex VI: Flam. Liq.2, H226; Repr.2, 0 Toluene EC TO Inhalation-Rat LC50• H361d;Asp.Tox. 1,H304;STOT RE 2*, H373; NDA Number:203- % 49 g/m'4 Hour(s) Skin Irrit.2,H315;STOT SE 3,H336 44 625-9 Skin-Rabbit LD50• OSHA HCS 2012: Flam. Liq.2; Repr.2;Acute 14100 pUkg Tox.4(Oral);STOT SE 3:Narc.;Asp.Tox. 1; STOT RE 2(CNS) CAS:64741-84- EU DSD/DPD: Annex I:Carc.Cat.2; R45;Muta. Solvent-refined 0 25% Cat.2;R46;Xn;R65 light petroleum EC TO NDA EU CLP: Annex VI:Carc. 1 B, H350; Muta. 1 B, NDA naphtha Number:265- 35% H340;Asp.Tox. 1, H304 086-6 OSHA HCS 2012: Data lacking EU DSDIDPD: Not Classified-Classification criteria not met Polymers NDA 5%TO O NDA EU CLP: Not Classified-Classification criteria not NDA 15% met OSHA HCS 2012: Not Classified-Classification criteria not met EU DSDIDPD: Not Classified-Classification criteria not met 1,3-Butadiene,2- CAS:9010-98-4 <12% Ingestion/Oral-Rat EU CLP: Not Classified-Classification criteria not NDA chloro-,polymers LD50•>40 g/kg met OSHA HCS 2012: Not Classified-Classification criteria not met CAS:67-64-1 Ingestion/Oral-Rat EU DSDIDPD: Annex I:F,R11,Xi;R36;R66;R67 EC 5%TO LD50•5800 mg/kg EU CLP: Annex VI:Flam. Liq.2, H226;Eye Init.2, Acetone H319;STOT SE 3,H336 NDA Number:200- 10% Inhalation-Rat LC50• OSHA HCS 2012: Flam.Liq.2;Eye brit.2A,STOT 662-2 50100 mg/m3 SE 3:Resp. lrrit.&Narc.;Repr.2 Ingestion/Oral-Rat CAS:1330 20 7 LD50.4300 mg/kg EU DSDIDPD: Annex I: R10,Xn;R20/21,Xi;R38 EC Inhalation-Rat LC50• Xylene EU CLP: Annex VI: Flam.Liq.3, H226;Acute Tox. <1% 4*,H312;Acute Tox.4*,H332;Skin brit.2,H315 NDA Number:215 5000 ppm 4 Hour(s) OSHA HCS 2012: Acute Tox 4(Skin); Eye brit. 535-7 Skin-Rabbit LD50• 2A;Skin brit.2; Repr.2 >1700 mg/kg CAS:100-42-5 Ingestion/Oral-Rat EU DSDIDPD: Annex I:R10 Xn; R20 Xi;R36/38 EC o LD50.2650 mg/kg EU CLP: Annex VI: Flam. Liq.3, H226;Acute Tox. Styrene <1% 4*,H332;Eye brit.2,H319;Skin brit.2,H315 NDA Number:202- Inhalation-Rat LC50• OSHA HCS 2012: Eye Irrit.2;Acute Tox.4;Carc. 851-5 2770 ppm 4 Hour(s) 2 CAS:1309 48 4 EU DSDIDPD: Self Classified:Xi, R36/37 EC EU CLP: Self Classified:Eye brit.2, H319;STOT Magnesium oxide <1% NDA SE 3, H335 NDA Number:215- OSHA HCS 2012: Eye Irrit.2;STOT SE 3:Resp. 171-9 brit. CAS:1314-13-2 - EU DSDIDPD: Annex I:N;R50-53 EC <0.3% NDA EU CLP: Annex VI:Aquatic Acute 1, H400; NDA Zinc oxide Number:215- Aquatic Chronic 1, H410 222-5 OSHA HCS 2012: Not Classified Preparation Date: 07/February/2013 —� Format EU CLP/REACH Language:English(US) Revision Date: 30/December/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 5 of 16 UltraPly Bonding Adhesive See Section 11 for Toxicological Information. Section 4 - First Aid Measures 4.1 Description of first aid measures Inhalation • IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Administer oxygen if breathing is difficult. Give artificial respiration if victim is not breathing. Get medical attention immediately if symptoms occur. Skin • In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Remove and isolate contaminated clothing and shoes. If skin irritation occurs: Get medical advice/attention. Eye • In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. If eye irritation persists: Get medical advice/attention. Ingestion • If swallowed, rinse mouth with water (only if the person is conscious) Do NOT induce vomiting. Do not give anything by mouth to an unconscious person. Get medical attention immediately if symptoms occur. 4.2 Most important symptoms and effects, both acute and delayed • Refer to Section 11 - Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician • All treatments should be based on observed signs and symptoms of distress in the patient. Consideration should be given to the possibility that overexposure to materials other than this product may have occurred. Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media • CAUTION: For mixtures containing a high percentage of an alcohol or polar solvent, alcohol-resistant foam may be more effective. LARGE FIRES: Water spray, fog or alcohol-resistant foam. SMALL FIRES: Dry chemical, CO2, water spray or alcohol-resistant foam. Unsuitable Extinguishing • Do not use a direct stream of water. Media 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion • Containers may explode when heated. Hazards Vapor explosion hazard indoors, outdoors or in sewers. HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Many liquids are lighter than water. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Runoff to sewer may create fire or explosion hazard. Those substances designated with a "P" may polymerize explosively when heated or involved in a fire. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Hazardous Combustion • Oxides of carbon, oxides of nitrogen, hydrochloric acid. Products 5.3 Advice for firefighters • Structural firefighters' protective clothing will only provide limited protection. Wear positive pressure self-contained breathing apparatus (SCBA). Move containers from fire area if you can do it without risk. LARGE FIRES: Cool containers with flooding quantities of water until well after fire is out. Preparation Date: 07/February/2013 Format:EU CLP/REACH Language:English(US) Revision Date: 30/December/2014Page 6 or 16 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 UltraPly Bonding Adhesive Section 6 - Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions • CAUTION: Victim may be a source of contamination. Do not touch or walk through spilled material. Emergency Procedures • As an immediate precautionary measure, isolate spill or leak area for at least 50 meters (150 feet) in all directions. If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directions; also, consider initial evacuation for 800 meters (1/2 mile) in all directions. LARGE SPILL: Consider initial downwind evacuation for at least 300 meters (1000 feet) ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep unauthorized personnel away. Stay upwind. Keep out of low areas. Ventilate closed spaces before entering. 6.2 Environmental precautions . Prevent entry into waterways, sewers, basements or confined areas. 6.3 Methods and material for containment and cleaning up Containment/Clean-up • Stop leak if you can do it without risk. Measures Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material. A vapor suppressing foam may be used to reduce vapors. All equipment used when handling the product must be grounded. LARGE SPILLS: Dike far ahead of liquid spill for later disposal. LARGE SPILLS: Water spray may reduce vapor; but may not prevent ignition in closed spaces. 6.4 Reference to other sections . Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. Section 7 - Handling and Storage 7.1 Precautions for safe handling Handling • Do not use in areas without adequate ventilation. Handle and open container with care. Use good safety and industrial hygiene practices. 7.2 Conditions for safe storage, including any incompatibilities Storage . Keep away from fire. Store in a well-ventilated place. Keep container tightly closed. 7.3 Specific end use(s) . Refer to Section 1.2 - Relevant identified uses. Section 8 - Exposure Controls/Personal Protection 8.1 Control parameters Exposure Limits/Guidelines Result ACGIH Canada Ontario Canada Quebec China Europe STELs Not established Not established Not established 100 mg/m3 STEL 100 ppm STEL, 384 Toluene mg/m3 STEL (108-88-3) 50 ppm TWAEV; 188 50 ppm TWA; 192 TWAs 20 ppm TWA 20 ppm TWA 50 mg/m3 TWA mg/m3 TWAEV mg/m3 TWA Exposure Limits/Guidelines (Cont.) Result Germany DFG German TRGS NIOSH OSHA Preparation Date: 07/February/2013 Format:EU CLP/REACH Language:English(US) revision Date: 30/December/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 UltraPly Bonding Adhesive Ceilings 200 ppm Peak;760 Not established Not established 300 ppm Ceiling mg/m3 Peak 50 ppm TWA AGW (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, TWAs Not established exposure factor 4); 100 ppm TWA;375 200 ppm TWA Toluene 190 mg/m3 TWA AGW mg/m3 TWA (108-88-3) (The risk of damage to the embryo or fetus can be excluded when AGW and BGW values are observed, exposure factor 4) STELs Not established Not established 150 ppm STEL;560 Not established mg/m3 STEL MAKS 50 ppm TWA MAK; 190 Not established Not established Not established mg/m3 TWA MAK Exposure Control Notations China *Toluene(108-88-3):Skin:(Skin notation) *Styrene(100-42-5):Skin: (Skin notation) Canada Quebec *Toluene(108-88-3):Skin: (Skin designation) *Styrene(100-42-5):Carcinogens: (C3 carcinogen-effect detected in animals)I Skin:(Skin designation) ACGIH *Toluene(108-88-3):Carcinogens:(A4-Not Classifiable as a Human Carcinogen) *Acetone(67-64-1):Carcinogens:(A4-Not Classifiable as a Human Carcinogen) •Xylene(1330-20-7): Carcinogens:(A4-Not Classifiable as a Human Carcinogen) *Magnesium oxide(1309-48-4): Carcinogens:(A4-Not Classifiable as a Human Carcinogen) •Styrene(100-42-5): Carcinogens: (A4-Not Classifiable as a Human Carcinogen) Germany TRGS •Toluene(108-88-3):Skin:(skin notation) •Xylene(1330-20-7):Skin:(skin notation(all isomers)) Germany DFG 'Toluene(108-88-3): Pregnancy:(no risk to embryo/fetus if exposure limits adhered to)I Skin:(skin notation) •Acetone(67-64-1): Pregnancy:(classification not yet possible) •Xylene(1330-20-7):Pregnancy:(classification not yet possible(all isomers))I Skin:(skin notation(all isomers)) •Magnesium oxide(1309-48-4):Pregnancy:(no risk to embryo/fetus if exposure limits adhered to(respirable fraction); inhalable fraction) •Styrene(100-42-5): Carcinogens:(Category 5(low carcinogenic potency))I Pregnancy:(no risk to embryo/fetus if exposure limits adhered to) Exposure Limits Supplemental ACGIH *Toluene(108-88-3): BEIs:(0.02 mg/L Medium:blood Time:prior to last shift of workweek Parameter:Toluene;0.03 mg/L Medium:urine Time:end of shift Parameter:Toluene;0.3 mg/g creatinine Medium: urine Time:end of shift Parameter:o-Cresol with hydrolysis(background))I TLV Basis- Critical Effects:(female reproductive;pregnancy loss;visual impairment) *Acetone(67-64-1): BEIs:(50 mg/L Medium: urine Time:end of shift Parameter:Acetone(nonspecific)) TLV Basis-Critical Effects:(CNS impairment;eye and upper respiratory tract irritation;hematologic effects)I Notice of Intended Changes(TLVs):(200 ppm TWA;500 ppm STEL;BEI;TLV basis:CNS impairment,upper respiratory tract irritation) •Xylene(1330-20-7): BEls:(1.5 g/g creatinine Medium: urine Time:end of shift Parameter: Methylhippuric acids)I TLV Basis-Critical Effects: (CNS impairment;eye and upper respiratory tract irritation) *Zinc oxide(1314-13-2):TLV Basis-Critical Effects:(metal fume fever) •Styrene(100-42-5): BEIs:(400 mg/g creatinine Medium:urine Time:end of shift Parameter:Mandelic acid plus phenylglyoxylic acid(nonspecific); Preparation Date: 07/February/2013 sf y Yw - Format EU CLP/REACH Language:English(US) Revision Date: 30/December/2014 Page 8 of 16 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 UltraPly Bonding Adhesive 0.2 mg/L Medium:venous blood Time: end of shift Parameter: Styrene(semi-quantitative)) I TLV Basis-Critical Effects: (CNS impairment; peripheral neuropathy; upper respiratory tract irritation) 8.2 Exposure controls Engineering . This adhesive is designed to be used outdoors, in roofing applications. Good general Measures/Controls ventilation should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Personal Protective Equipment Respiratory . Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH or European Standard EN 149 approved respirator if exposure limits are exceeded or symptoms are experienced. Eye/Face . Wear chemical splash safety goggles. Skin/Body . Wear appropriate chemical resistant gloves. Environmental Exposure . In case of spills, keep product clear of sewers, waterways or land areas. Dispose of Controls waste product in accordance with national and local laws and regulations. Section 9 - Physical and Chemical Properties 9.1 Information on Physical and Chemical Properties Material Description _ Physical Form Liquid Appearance/Description Yellow amber liquid with strong aromatic odor. Color Yellow amber. Odor Aromatic Odor Threshold Data lacking General Properties _ Boiling Point 55 to 142 F(12.7778 to 61.1111 C) Melting Point Data lacking Decomposition Temperature Data lacking pH Data lacking Specific Gravity/Relative Density 0.844 Water=1 Water Solubility Insoluble Viscosity Not relevant Explosive Properties Explosion hazard. Oxidizing Properties: Static hazard. Volatility Vapor Pressure C)t5 o 185 mmHg(torr)@ 68 F(20 Vapor Density >3 Air=1 Evaporation Rate 1.9 to 9.5 n-Butyl Acetate= 1 VOC(Vol.) 633 g/L Volatiles(Vol.) 76.4% Flammability Flash Point -18 C(-0.4 F) UEL 7.5% LEL 1.1 % Autoignition Data lacking Flammability(solid,gas) Not relevant. Environmental Octanol/Water Partition coefficient I Data lacking 9.2 Other Information • No additional physical and chemical parameters noted. Section 10: Stability and Reactivity 10.1 Reactivity • No dangerous reaction known under conditions of normal use. Preparation Date: 07/February/2013 Format:EU CLP/REACH Language:English(US) Revision Date: 30/December/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Pace 9 of 16 UltraPly Bonding Adhesive 10.2 Chemical stability . Stable under normal temperatures and pressures. 10.3 Possibility of hazardous reactions . Hazardous polymerization will not occur. 10.4 Conditions to avoid • Avoid flames, sparks, and other sources of ignition. Avoid contact with combustible materials. Avoid contact with incompatible materials. 10.5 Incompatible materials . Acids, bases, combustible materials, oxidizing materials. 10.6 Hazardous decomposition products • Thermal decomposition could produce CO, CO2, and Oxides of Nitrogen. Section 11 -Toxicological Information 11.1 Information on toxicological effects Components Acute Toxicity: Ingestion/Oral-Rat LD50•636 mg/kg;Inhalation-Rat LC50•49 g/m3 4 Hour(s);Skin-Rabbit LD50•14100 Toluene NL/kg; (34%TO 108- Irritation: Eye-Rabbit• 100 mg 30 Second(s)-Rinse•Mild irritation;Skin-Rabbit•435 mg•Mild irritation; %) 88-3 Reproductive: Inhalation-Rat TCLo•1500 ppm(7-20D preg);Reproductive Effects:Specific Developmental 44 Abnormalities:Central nervous system;Reproductive Effects:Effects on Newbom:Growth statistics(e.g., reduced weight gain);Reproductive Effects:Effects on Newbom:Biochemical and metabolic GHS Properties Classification EUICLP•Classification criteria not met Acute toxicity OSHA HCS 2012•Acute Toxicity-Oral 4 EUICLP•Classification criteria not met Aspiration Hazard OSHA HCS 2012•Classification criteria not met EUICLP•Classification criteria not met Carcinogenicity OSHA HCS 2012•Carcinogenicity 2 EU/CLP•Classification criteria not met Germ Cell Mutagenicity OSHA HCS 2012•Classification criteria not met EU/CLP•Skin Irritation 2 Skin corrosion/Irritation OSHA HCS 2012•Skin Irritation 2 EU/CLP•Classification criteria not met Skin sensitization OSHA HCS 2012•Classification criteria not met EU/CLP•Specific Target Organ Toxicity Repeated Exposure 2 STOT-RE OSHA HCS 2012•Specific Target Organ Toxicity Repeated Exposure 2 EU/CLP•Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects STOT-SE OSHA HCS 2012•Specific Target Organ Toxicity Single Exposure 3: Narcotic Effects EU/CLP•H361d-Suspected of damaging the unborn child;Toxic to Reproduction 2 Toxicity for Reproduction OSHA HCS 2012•Toxic to Reproduction 2 EU/CLP•Classification criteria not met Respiratory sensitization OSHA HCS 2012•Classification criteria not met Preparation Date: 07/February/2013 Format:EU CLP/REACH Language:English(US) Revision Date: 30/December/2014 Page 10 of 16 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 :1irsPly Bonding Adhesive EUICLP•Eye Irritation 2 I Serious eye damage/Irritation OSHA HCS 2012.Eye Irritation 2A Route(s) of entry/exposure • Inhalation, Skin, Eye, Ingestion/Oral Potential Health Effects Inhalation Acute (Immediate) • May be harmful. May affect the central nervous system. Symptoms may include dizziness, drowsiness, lethargy, coma and death. Chronic (Delayed) • Repeated and prolonged exposure may cause Central Nervous System (CNS) effects. Skin Acute (Immediate) • Causes skin irritation. Chronic (Delayed) • No data available. Eye Acute (Immediate) • Causes serious eye irritation. Chronic (Delayed) . No data available. Ingestion Acute (Immediate) . May be harmful. Chronic (Delayed) • No data available. Carcinogenic Effects CAS IARC NTP Toluene 108-88-3 Group 3-Not Classifiable Evidence of Carcinogenicity Reproductive Effects • Repeated and prolonged exposure may cause reproductive effects. Section 12 - Ecological Information 12.1 Toxicity UltraPly Bonding Adhesive Dosage Species Duration Results Exposure Conditions Comments 6.8 mg/L Water Flea: Daphnia magna 48 Hour(s) EC50 NDA Toluene 28 mg/L Water Flea: Daphnia magna 48 Hour(s) NOEC NDA Toluene 0.00025 Fish: Fathead Minnow 96 Hour(s) LC50 NDA Hexane mg/L • This material may be toxic to aquatic organisms and cause long-term adverse effects in the aquatic environment. 12.2 Persistence and degradability • No information available for the product. 12.3 Bioaccumulative potential . No information available for the product. 12.4 Mobility in Soil • No information available for the product. 12.5 Results of PBT and vPvB assessment • PBT and vPvB assessment has not been carried out. 12.6 Other adverse effects . No studies have been found. Preparation Date: 07/February/2013 Format:EU CLP/REACH Language:English(US) Revision Date: 30/December/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Pe:ge i'i di 16 UItraPIy Bonding Adhesive I Section 13 - Disposal Considerations I 13.1 Waste treatment methods Product waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste • Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 -Transport Information I I14.1 UN 14.2 UN proper 14.3 Transport hazard 14.4 Packing 14.5 Environmental number shipping name class(es) group hazards DOT UN1133 Adhesives 3 II NDA TDG UN1133 ADHESIVES 3 II NDA IMO/IMDG UN1133 ADHESIVES 3 II NDA ADN UN1133 ADHESIVES 3 II NDA ADR/RID UN1133 ADHESIVES 3 I II NDA IATA/ICAO UN1133 Adhesives 3 1 ii NDA 14.6 Special precautions for • None known. user 14.7 Transport in bulk • Not relevant. according to Annex II of MARPOL 73/78 and the IBC Code 14.8 Other information DOT• Toluene has a reportable quantity of 1000 lbs (454 kg) as listed in Appendix A to 49 CFR 172.101. Hexane has a reportable quantity of 5000 lbs (2270 kg) as listed in Appendix A to 49 CFR 172.101. Cyclohexane has a reportable quantity of 1000Ibs (454kg) as listed in Appendix A to 49 CFR 172.101. Section 15 - Regulatory Information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture SARA Hazard Classifications • Acute, Chronic, Fire State Right To Know Component CAS MA NJ PA Toluene 108-88-3 Yes Yes Yes Inventory Component CAS Canada DSL Canada NDSL China EU EINECS EU ELNICS Toluene 108-88-3 Yes No Yes Yes No Inventory (Con't.) Component CAS Japan ENCS Korea KECL TSCA Toluene 108-88-3 Yes Yes Yes Preparation Date: 07/February/2013 Format:EU CLP/REACH Language:English(US) 1Revision Date: 30/December/2014 Page 12 of 18 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 'Firestone TECHNICAL INFORMATION SHEET BUILDING PRODUCTS ISO 95TM GL Insulation Item Description Flat and Tapered Polyiso Boards Cellulosic Glass Reinforced Facer Flat Boards: 4'x 4' (1.22 m x 1.22 m) 4'x8' (1.22mx2.44m) Tapered Boards: 4'x 4' (1.22 m x 1.22 m) r Slope range: 1/16" per foot(.5%)to 1/2" per foot(4%) Thickness range: 0.5" (12.7 mm)to 4.5" (114.3 mm) '°" Meets or exceeds •erformance re•uirements of ASTM C 1289, T •e II, Class 1 Foam Core Product Information Description: Firestone ISO 95+ GL flat and tapered roof insulation consists of a closed-cell polyiso foam core laminated to a black glass reinforced mat facer on both major surfaces. Flat and tapered ISO 95+ GL insulation provides outstanding thermal performance on commercial roofing applications, while providing positive rooftop drainage to help eliminate ponding water when tapered ISO 95+ GL insulation is used. All Firestone polyisocyanurate insulations use EPA accepted blowing agents. Firestone ISO 95+ GL incorporates a HCFC- free blowing agent that does not contribute to the depletion of the ozone layer(ODP-free). Method of Application: 1. Insulation shall be neatly fitted to all roof penetrations, projections and nailers. 2. No more insulation shall be installed than can be covered with membrane and completed before the end of each day's work or before the onset of inclement weather. 3. Firestone ISO 95+ GL board may be installed using: • Firestone fasteners and plates NOTE: For ballasted systems, the top layer of Firestone insulation may not be mechanically attached. • Hot asphalt(requires a cover board) • Firestone approved insulation adhesives • I.S.O. Twin PackTM • I.S.Q. StickTM • I.S.O. SprayTM R • I.S.O. FIXTM II Acceptable Immediate Substrates: • 3,000 psi Structural concrete (must be clean, dry, and properly cured) • Steel deck(min 22 ga) • Plywood and OSB (min 1/2") ®�^ • Lightweight concrete 1< • Gypsum deck (min 2") NOTE: Please consult the Design Guides and QuickSpecs online at www.firestonebpco.com to revi fic information regarding the assembly. Storage: 1", • Keep insulation dry at all times • Elevate insulation above the deck or ground • Cover insulation with waterproof tarps Firestone Building Products I Sales:(800)428-44421 Technical(800)428-4511 I www.firestonebpco.com TIS#901 10/05/2017 Page 1 of 3 'Firestone TECHNICAL INFORMATION SHEET BUILDING PRODUCTS ISO 95+TM GL Insulation Precautions: • Polyiso foam will burn if exposed to a flame of sufficient heat and intensity. Keep away from heat, sparks, and open flames. • Protect against dust that may be generated during installation. • Refer to Safety Data Sheet(SDS)for additional information. • Take care when transporting and handling Firestone insulation to avoid physical damage. Specification Compliance: �pSsIF,F ASTM C1289, Type II, Class 1 ® o. PI411‘tyMark' UL Classified—UL1256 C IJS FM Class 1 Approved APPROVED Manufactured in an ISO 9001 Registered Facility CAN/ULC-S704, Type 1, Class 3 MIAMIOADECOUNTr CCMC 13274-L APPRCVED LEED® Information: See Recycled Content in table below. Manufacturing Locations: Florence, KY Corsicana, TX Bristol, Ct De Forest, WI Salt Lake City, UT Youngwood, PA Jacksonville, FL NOTE: Miami Dade Classified polyiso is only produced in the Jacksonville, FL and Youngwood, PA facilities. Typical Properties (Meets ASTM C 1289, Type II, Class 1) Property ASTM Test Method Firestone Typical Performance Compressive Strength: D1621 Grade 2: 20 psi (138 kPa) Grade 3: 25 psi (172 kPa)* Density: D1622 2 pcf(32 kg/m3) Dimensional Stability: D2126 <2% Moisture Vapor Transmission: E96 <1 perm (<57.5 ng/(Pa•s•m2)) Water Absorption: C209 <1% by volume Service Temperature: ---- -100 to 250 °F (-73 to 121 °C) Flame Spread: E84 Index 50 Smoke Development: E84 Index 160- 180 *25 psi(172 kPa)available upon request. Firestone Building Products I Sales:(800)428-4442 I Technical(800)428-4511 I www.firestonebpco.com TIS#901 10/05/2017 Page 2 of 3 ISO 95+TM GL(Flat and Tapered),ISO 95+TM CAN Safety Data Sheet Firestone Building Products Company Section 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1 Product identifier Product Name • ISO 95+TM GL (Flat and Tapered), ISO 95+TM CAN 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified use(s) . Construction 1.3 Details of the supplier of the safety data sheet Manufacturer . Firestone Building Products Company 250 West 96th Street Indianapolis, IN 46260 United States firestonemsds( bfdo.com Telephone (General) . 800-428-4442 1.4 Emergency telephone number Manufacturer . (800) 424-9300 - CHEMTREC Manufacturer . (703) 527-3887 - CHEMTREC - International Section 2: Hazards Identification EU/EEC According to Regulation (EC) No 1272/2008 (CLP)/REACH 1907/2006 [amended by 453/2010] According to EU Directive 67/548/EEC (DSD) or 1999/45/EC (DPD) 2.1 Classification of the substance or mixture CLP . Not classified DSD/DPD . Not classified 2.2 Label Elements CLP Hazard statements . No label element(s) required DSD/DPD Risk phrases . No label element(s) required 2.3 Other Hazards CLP . According to Regulation (EC) No. 1272/2008 (CLP) this material is not considered hazardous. DSD/DPD . According to European Directive 1999/45/EC this preparation is not considered dangerous. United States (US) According to OSHA 29 CFR 1910.1200 HCS Preparation Date: 19/ApriV2011 Format:EU CLP/REACH Language:English(US) Revision Date: 17/February/2014 Page 1 of 14 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 ISO 95+Ti GL(Flat and Tapered),ISO 95+n CAN 2.1 Classification of the substance or mixture OSHA HCS 2012 . Not classified 2.2 Label elements OSHA HCS 2012 Hazard statements . No label elements(s) required 2.3 Other hazards OSHA HCS 2012 . This product is not considered hazardous under the U.S. OSHA 29 CFR 1910.1200 Hazard Communication Standard. Canada According to WHMIS 2.1 Classification of the substance or mixture WHMIS . Not classified 2.2 Label elements WHMIS . No label element(s) required 2.3 Other hazards WHMIS . In Canada, the product mentioned above is not considered hazardous under the Workplace Hazardous Materials Information System (WHMIS). Section 3 -Composition/Information on Ingredients 3.1 Substances . Material does not meet the criteria of a substance in accordance with Regulation (EC) No 1272/2008. 3.2 Mixtures Composition Chemical Name Identifiers % LD50/LC50 Classifications According to Comments Regulation/Directive CAS:65997-17- Glass, oxide, 3 EU DSD/DPD: Not Classified EC <11% NDA EU CLP: Not Classified NDA chemicals Number:266- OSHA HCS 2012: Not Classified 046-0 EU DSD/DPD:Annex I: F+; R12 N; R51-53 Xn; R65 R66 R67 CAS:78-78-4 EU CLP: Annex VI: Flam. Liq. 1, H224;Asp. Inhalation-Rat LC50• 2-Methylbutane EC 4.5%TO 280000 mg/m'4 Hour Tox. 1, H304;STOT SE 3, H336;Aquatic NDA Number:201- 9.9% Chronic 2, H411;EUH066 142-8 (s) OSHA HCS 2012: Flam Liq 1; Eye brit.2A; Skin Irrit.2;STOT SE 3: Resp. brit.&Narc., Asp.Tox. 1 Preparation Date: 19/ApriV2011 Format:EU CLP/REACH Language:English(US) Revision Date: 17/February/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 2 of 14 ISO 95+TM GL(Flat and Tapered),ISO 95+TM CAN EU DSDIDPD:Annex I: F+; R12 N;R51-53 Xn; CAS:109-66-0 Inhalation-Rat LC50• R65 R66 R67 EC 0.05% 364 g/m3 4 Hour(s) EU CLP: Annex VI: Flam. Liq.2, H225;Asp. Pentane ° Tox. 1, H304; STOT SE 3: Narc., H336;Aquatic NDA Number:203- TO 5.5% Ingestion/Oral-Rat Chronic 2, H411; EUH066 692-4 LD50•>2000 mg/kg OSHA HCS 2012: Flam. Liq. 1;Asp.Tox. 1. Eye Irrit.2, Skin Irrit.2, STOT SE 3: Narc. CAS:13674-84- 2-Propanol, 1- 5 EU DSDIDPD: Self Classified:Xn, R22 chloro-,2,2',2"- EC <5% Ingestion/Oral-Rat EU CLP: Self Classified:Acute Tox.4, H302 NDA phosphate Number:237- LD50• 1500 mg/kg OSHA HCS 2012: Acute Tox.4(Oral) 158-7 See Section 11 for Toxicological Information. See Section 16 for full text of H-statements and R-phrases. Section 4 - First Aid Measures 4.1 Description of first aid measures Inhalation . Move victim to fresh air. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Skin . In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Eye . In case of contact with substance, immediately flush eyes with running water for at least 20 minutes. Ingestion . Rinse mouth. Do not give anything by mouth to an unconscious person. 4.2 Most important symptoms and effects, both acute and delayed . Refer to Section 11 - Toxicological Information. 4.3 Indication of any immediate medical attention and special treatment needed Notes to Physician . No specific actions or treatments recommended related to exposure to this material. Section 5 - Firefighting Measures 5.1 Extinguishing media Suitable Extinguishing Media . LARGE FIRE: Water spray, fog or regular foam. SMALL FIRES: Dry chemical, CO2, water spray or regular foam. Unsuitable Extinguishing . No data available. Media 5.2 Special hazards arising from the substance or mixture Unusual Fire and Explosion . Burning of this product will produce thick black smoke. Hazards Toxic fumes and vapors may be produced. Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Isopentane and n-pentane, highly flammable materials, may be present within this product. Hazardous Combustion . Carbon dioxide and carbon monoxide, phosphorus oxides, and phosphoric acid. Products 5.3 Advice for firefighters . Wear positive pressure self-contained breathing apparatus (SCBA). Structural firefighters' protective clothing will only provide limited protection. Fire fighters should wear complete protective clothing including self-contained breathing apparatus. Preparation Date: 19/Apri1/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 17/February/2014 Page 3 of 14 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 ISO 95+*) GL(Flat and Tapered),ISO 95+"'CAN Section 6 -Accidental Release Measures 6.1 Personal precautions, protective equipment and emergency procedures Personal Precautions . Not applicable. Emergency Procedures . Not applicable. 6.2 Environmental precautions . No special precautions necessary. 6.3 Methods and material for containment and cleaning up Containment/Clean-up . Avoid generating dust. Measures Pick up large pieces. Sweep and scoop up material and put into a suitable container for disposal as a non-hazardous waste. 6.4 Reference to other sections . Refer to Section 8 - Exposure Controls/Personal Protection and Section 13 - Disposal Considerations. Section 7 - Handling and Storage 7.1 Precautions for safe handling Handling . Use only in well ventilated areas. Wear appropriate personal protective equipment. Protect against dust that may be generated by reprocessing, altering or applying this product. Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Wash thoroughly with soap and water after handling and before eating, drinking, or using tobacco. 7.2 Conditions for safe storage, including any incompatibilities Storage . Keep away from heat, sparks and flame. Store in a cool, dry place. 7.3 Specific end use(s) . Refer to Section 1.2 - Relevant identified uses. Section 8 - Exposure Controls/Personal Protection 8.1 Control parameters Exposure Limits/Guidelines Canada British Canada New Result ACGIH Canada Alberta Canada Ontario Columbia Brunswick 600 ppm TWA(listed 600 ppm TWA; 1770 600 ppm TWA(listed 600 ppm TWA; 1770 Pentane TWAs under Pentane,all mg/m3 TWA under Pentane,all mg/m3 TWA 600 ppm TWA isomers) isomers) (109-66-0) STELs Not established Not established Not established 750 ppm STEL, 2210 Not established mg/m3 STEL 600 ppm TWA(listed 600 ppm TWA(listed 600 ppm TWA(listed 2-Methylbutane TWAs under Pentane,all 600 ppm TWA, 1770 under Pentane,all Not established under Pentane, all (78-78-4) mg/m3 TWA isomers) isomers) isomers) 1 fibre/cm3 TWA 1 fiber/cm3 TWA 1 fibre/cm3 TWA (fibres>5 pm in (respirable fibers: (fibres>5 pm,with length and an aspect length>5 pm,aspect an aspect ratio of ratio>=3:1 as ratio>=3:1, as >=3:1, as determined determined by the Preparation Date: 19/April/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 17/February/2014 Page 4 of 14 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 ISO 954-Th'GL(Flat and Tapered),ISO 95+1N CAN determined by the by the membrane membrane filter 1 fibre/cm3 TWA membrane filter filter method at 400- method at 400-450 (fibres>5 pm with a Glass,oxide, method at 400-450X 1 fibre/cm3 TWA 450 times times magnification chemicals as Glass TWAs magnification[4-mm magnification(4 mm diameter<3 pm, (4-mm objective), wool fiber objective], using as Glass wool fiber objective), using aspect ratio>5:1) using phase-contrast phase-contrast phase-contrast as Glass wool fiber illumination, illumination,listed illumination, listed respirable, listed under Synthetic under Synthetic under Synthetic vitreous fibers) vitreous fibres) Vitreous Fibres(Man Made Mineral Fibres)) as Glass wool fiber as Glass wool fiber as Glass wool fiber Ex•osure Limits/Guidelines (Con't.) Result Canada Quebec Canada Yukon Europe NIOSH OSHA TWAs 120 ppm TWAEV; 600 ppm TWA; 1800 1000 ppm TWA;3000 120 ppm TWA; 350 1000 ppm TWA;2950 350 mg/m3 TWAEV mg/m3 TWA mg/m3 TWA mg/m3 TWA mg/m3 TWA Pentane STELs Not established 750 ppm STEL;2250 Not established Not established Not established (109-66-0) mg/m3 STEL 610 ppm Ceiling(15 Ceilings Not established Not established Not established min); 1800 mg/m3 Not established Ceiling(15 min) 2-Methylbutane TWAs Not established Not established 1000 ppm TWA;3000 Not established Not established (78-78-4) mg/m3 TWA 2 fibre/cm3 TWAEV 3 fiber/cm3 TWA (respirable, listed 30 mppcf TWA; 10 (fibers<=3.5 pm in Glass,oxide, under Fibres- mg/m3 TWA diameter and>= 10 chemicals as Glass TWAs Artificial Vitreous (respirable mass) Not established pm in length); 5 Not established wool fiber Mineral Fibres) mg/m3 TWA(total) as Glass wool fiber as Glass wool fiber as Glass wool fiber 8.2 Exposure controls Engineering . No special controls are expected to be needed. Measures/Controls Personal Protective Equipment Respiratory . Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH or European Standard EN 149 approved respirator if exposure limits are exceeded or symptoms are experienced. Eye/Face . Wear safety goggles. Hands • Wear appropriate gloves. Skin/Body . Wear long sleeves and/or protective coveralls if determined to be needed by the end- user. Environmental Exposure . Follow best practice for site management and disposal of waste. Controls Key to abbreviations ACGIH=American Conference of Governmental Industrial Hygiene STEL =Short Term Exposure Limits are based on 15-minute exposures NIOSH=National Institute of Occupational Safety and Health TWAEV=Time-Weighted Average Exposure Value OSHA =Occupational Safety and Health Administration TWA =Time-Weighted Averages are based on 8h/day,40h/week exposures Section 9 - Physical and Chemical Properties 9.1 Information on Physical and Chemical Properties Preparation Date: 19/Apri1/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 17/February/2014 Page 5 of 14 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 ISO 95+TM GL(Flat and Tapered),ISO 95+Ths CAN Material Description Physical Form Solid Appearance/Description White rigid cellular sheets with no odor. Color White Odor Odorless Odor Threshold Data lacking General Properties Boiling Point Data lacking Melting Point Data lacking Decomposition Temperature Data lacking pH Data lacking Specific Gravity/Relative Density Data lacking Water Solubility Insoluble Viscosity Data lacking Explosive Properties Not explosive. Oxidizing Properties: Not an oxidizer. Volatility Vapor Pressure Data lacking Vapor Density Data lacking Evaporation Rate Data lacking Flammability Flash Point Data lacking UEL Data lacking LEL Data lacking Autoignition Data lacking Flammability(solid,gas) Not flammable. Environmental Octanol/Water Partition coefficient 'Data lacking I I 9.2 Other Information . No additional physical and chemical parameters noted. Section 10: Stability and Reactivity 10.1 Reactivity . No dangerous reaction known under conditions of normal use. 10.2 Chemical stability . Stable under normal temperatures and pressures. 10.3 Possibility of hazardous reactions . Hazardous polymerization not indicated. 10.4 Conditions to avoid . No data available. 10.5 Incompatible materials . No data available. 10.6 Hazardous decomposition products . No data available. Section 11 -Toxicological Information 11.1 Information on toxicological effects Component Name CAS Data Pentane(0.05%TO 5.5%) 109-66-0 Acute Toxicity: orl-rat LD50:>2000 mg/kg; ihl-rat LC50:364 gm/m3/4H 2-Methylbutane(4.5%TO 9.9%) 78-78-4 Acute Toxicity: ihl-rat LC50:280000 mg/m3/4H Preparation Date: 19/ApriV2011 Format:EU CLP/REACH Language:English(US) Revision Date: 17/February/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 6 of 14 ISO 95+n GL(Rat and Tapered),ISO 95+n CAN 2-Propanol, 1-chloro-, 2,2',2"-phosphate(<5%) I13674-84-5 !Acute Toxicity: orl-rat LD50:1500 mg/kg L GHS Properties Classification EU/CLP•Classification criteria not met Acute toxicity OSHA HCS 2012•Classification criteria not met EU/CLP•Classification criteria not met Aspiration Hazard OSHA HCS 2012•Classification criteria not met EU/CLP•Classification criteria not met Carcinogenicity OSHA HCS 2012•Classification criteria not met EU/CLP•Classification criteria not met Germ Cell Mutagenicity OSHA HCS 2012•Classification criteria not met EU/CLP•Classification criteria not met Skin corrosion/Irritation OSHA HCS 2012.Classification criteria not met EU/CLP•Classification criteria not met Skin sensitization OSHA HCS 2012•Classification criteria not met EU/CLP•Classification criteria not met STOT-RE OSHA HCS 2012.Classification criteria not met EU/CLP•Classification criteria not met STOT-SE OSHA HCS 2012.Classification criteria not met EU/CLP•Classification criteria not met Toxicity for Reproduction OSHA HCS 2012.Classification criteria not met EU/CLP•Classification criteria not met Respiratory sensitization OSHA HCS 2012.Classification criteria not met EU/CLP•Classification criteria not met Serious eye damage/Irritation OSHA HCS 2012.Classification criteria not met Route(s) of entry/exposure . Inhalation, Skin, Eye, Ingestion Medical Conditions . Disorders of the lungs. Aggravated by Exposure Potential Health Effects Inhalation Acute (Immediate) . Exposure to dust may cause irritation. Processes such as cutting, grinding, crushing, or impact may result in generation of excessive amounts of airborne dusts in the workplace. Nuisance dust may affect the lungs but reactions are typically reversible. Chronic (Delayed) . No data available Skin Acute (Immediate) • Exposure to dust may cause mechanical irritation. Chronic (Delayed) . No data available. Eye Acute (Immediate) • Exposure to dust may cause mechanical irritation. Excessive concentrations of nuisance dust in the workplace may reduce visibility and may cause unpleasant deposits in eyes. Chronic (Delayed) . No data available. Ingestion Acute (Immediate) . Excessive concentrations of nuisance dust in the workplace may cause mechanical irritation to mucous membranes. Chronic (Delayed) . No data available. Key to abbreviations Preparation Date: 19/Apri1/2011 Format:EU CLP/REACH Language:English(US) Revision Date: 17/February/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 7 of 14 ISO 95+n GL(Flat and Tapered),ISO 95+n CAN LC=Lethal Concentration LD=Lethal Dose Section 12 - Ecological Information 12.1 Toxicity . Material data lacking. 12.2 Persistence and degradability . Material data lacking. 12.3 Bioaccumulative potential . Material data lacking. 12.4 Mobility in Soil . Material data lacking. 12.5 Results of PBT and vPvB assessment . No PBT and vPvB assessment has been conducted. 12.6 Other adverse effects . No studies have been found. Section 13 - Disposal Considerations 13.1 Waste treatment methods Product waste . Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Packaging waste . Dispose of content and/or container in accordance with local, regional, national, and/or international regulations. Section 14 -Transport Information 14.1 UN 14.2 UN proper 14.3 Transport hazard 14.4 Packing 14.5 Environmental number shipping name class(es) group hazards DOT NDA Not regulated NDA NDA NDA TDG NDA Not regulated NDA NDA NDA IMO/IMDG NDA Not regulated NDA NDA NDA ADN NDA Not regulated NDA NDA NDA ADR/RID NDA Not regulated NDA NDA NDA IATA/ICAO NDA Not regulated NDA NDA NDA 14.6 Special precautions for . None known. user 14.7 Transport in bulk . Not relevant. according to Annex II of MARPOL 73/78 and the IBC Code Preparation Date: 19/ApriV2011 Format:EU CLP/REACH Language:English(US) Revision Date: 17/February/2014 WHMIS,EU CLP,EU DSD/DPD,OSHA HCS 2012 Page 8 of 14