0 Lily Street - Limited Phase II Environmental Site Assessment ReportBLACKLEDGE
GROUP
August 2, 2021
via email c/o: bdurden(a�llw-law.com
Mr. Shane Corbin
City Manager
City of Atlantic Beach
800 Seminole Road
Atlantic Beach, Florida 32233
RE: Limited Phase II Environmental Site Assessment Report
0 Lily Street
2.1 Acres Unimproved Land
Atlantic Beach, Duval County, Florida 32233
RE# 170977-0000
Dear Mr. Corbin:
The Blackledge Group, Inc. (TBG) is pleased to present the results of this Limited Phase II Environmental
Site Assessment (ESA) performed on July 13, 2021. The subject site is comprised of approximately 2.12
acres of unimproved property located east of the Intracoastal Waterway. Based the recomtnendations of
the Phase I ESA report prepared by TBG, dated June 23, 2021, further assessment was recommended to
investigate the use of the subject site as a historical dump site. The scope of work included excavating
exploratory trenches and collecting a groundwater sample for laboratory analysis to determine if solid waste
was present on the subject site and to evaluate groundwater quality in the area of an on-site pit observed
during the Phase I ESA. The background of the site, a description of the scope of services performed as
part of this Limited Phase 11 ESA, and the results of the investigation are provided herein.
1.0 BACKGROUND
A Phase 1 ESA was performed by TBG, in June of 2021. According to the Phase I ESA the subject site
was comprised of a single parcel of land located at 0 Lily Street, Atlantic Beach, Duval County, Florida;
and identified by the Duval County Property Appraiser as RE # 170977-0000. The subject site was
undeveloped and wooded waterfront property and was heavily vegetated in the central and northern portions
of the property. An 8 -to 10 -foot -high soil mound and berm was observed along the western edge of the
central and northern portions of the site. A pit filled with standing water was observed in the central portion
of the site. A Street Site Location Map and Topographic Site Location Map are included as Figure 1 and
Figure 2, respectively.
During Phase I ESA field activities and historical records reviews, a recognized environmental condition
(REC) was identified. Evidence of the presence of solid waste, including tires and metal debris, was
observed in the central area of the site in the vicinity of the pit. The subject site and an adjacent property
to the east appeared to have been used as a dump site during the late 1960s and early 1970s. Interviews
conducted with people knowledgeable about the past history of the subject site indicated that the site was
used for dumping of unknown materials in the late 1960s and early 1970s. It was also reported that during
heavy storm and high-water events plastic materials, tires, etc. had been observed floating in the pit. Based
on a review of aerial photographs from 1960 to 1970 the northern section of the subject site had been cleared
1450 Flaglcr Avenue Unit #32. • Jacksonville, Florida 32207 • 800-241-6831
Mr. Shane Corbin
August 2, 2021
Page 2
and surficial soil had been disturbed. Additionally, evidence of historical excavation and filling activities
were observed during the site inspection and was observed on the aerial photographs reviewed.
As requested by the Client, TBG performed this limited Phase II ESA, which included the collection of a
groundwater sample to evaluate groundwater quality in the area of the pit, and the excavation of exploratory
trenches to investigate the presence of buried solid waste in the central and northern areas of the site.
2.0 SCOPE OF SERVICES
TBG proposed the following scope of work to evaluate the environmental concerns identified in the
referenced Phase I ESA: excavate up to six (6) exploratory trenches approximately 10 foot long by 3 foot
wide to a depth just below land surface (bls), estimated to be at 2-3 feet, in the central and northern portions
of the site; install one temporary wellpoint in the area of the pit; collect a groundwater sample from the
wellpoint for laboratory analysis of the parameters listed EPA Method 8260 Priority Pollutant Volatile
Organics Aromatics and Halocarbons, EPA Method 8270 Priority Pollutant Semi -Volatiles, EPA Method
8081 Organochlorine and Organophosphorus Pesticides, EPA Method 8082 PCBs, and 8 RCRA metals;
and prepared a letter report summarizing the results of the investigation.
3.0 METHODS OF INVESTIGATION
On July 13, 2021, TBG conducted limited Phase II ESA field activities in accordance with the scope of
work outlined above and provided to the Client prior to initiating the project. A description and summary
of the investigations is presented in the following section:
3.1 Exploratory Trench Excavations
TBG mobilized a mini excavator to the site and excavated fifteen (15) exploratory trenches approximately
5 to 10 foot long by 3 foot wide and to a depth of approximately 4 to 6 feet bls, and 2 to 3 feet into the
groundwater table which on the average was 2 to 3 feet bls. Exploratory trench excavations were conducted
in the central and northern portions of the site in areas that were accessible to the excavator. Excavated
soils and solid waste were returned to each excavation trench. The materials encountered were recorded at
each excavation trench.
Excavation locations are depicted in Figures 3 and 4. A summary of exploratory trench excavation
observations is included in Table 1.
3.2 Temporary Wellpoint Installation and Development
On July 13, 20201, TBG installed one temporary shallow wellpoint (TMW-1) to evaluate groundwater
quality in central area of the site. TMW-1 was installed due east of the middle of the eastern edge of the
pit located in the center of the subject site.
The temporary well point was installed by hand using a stainless-steel hand auger. The wellpoint was
installed to a depth of 6 feet bls, and approximately 4 feet below the groundwater table. TBG was unable
to advance the boring further due to the borehole collapsing. The temporary well was constructed using 5
feet of 2 -inch diameter, 0.010 -inch slotted polyvinyl chloride (PVC) well screen threaded to a sufficient
length of two-inch PVC casing to complete the well above grade. A 20/30 graded sand pack was installed
around the well screen.
Mr. Shane Corbin
August 2, 2021
Page 3
The wellpoint was developed after installation to ensure hydraulic communication with the aquifer.
Dedicated high-density polyethylene tubing was inserted into the top of the well casing and positioned in
the area of the well screen in order to develop the well and obtain a groundwater sample. Wellpoint
development was accomplished using an adjustable -flow peristaltic pump. Upon completion of the field
activities, the wellpoint was removed, the borehole backfilled to land surface, and the surface restored to
its existing condition. The location of the wellpoint is depicted on Figure 4, and GPS location coordinates
are included in Table 1.
3.3 Groundwater Sample Collection and Laboratory Analyses
TBG collected a groundwater sample from TMW-1 using a peristaltic pump with disposable high-density
polyethylene tubing. Samples were collected after approximately one hour of well development and as
most fine sediments were removed, and the groundwater showed a minimal amount of turbidity. The
groundwater sample was collected in laboratory -supplied containers, placed on ice in a shipping cooler,
and transported to Advance Environmental Laboratories (AEL) for analysis. The groundwater sample was
submitted for laboratory analyses of the parameters listed EPA Method 8260 Priority Pollutant Volatile
Organics Aromatics and Halocarbons, EPA Method 8270 Priority Pollutant Semi -Volatiles, EPA Method
8081 Organochlorine and Organophosphorus Pesticides, EPA Method 8082 PCBs, and 8 RCRA metals.
Groundwater laboratory results are discussed in Section 4.2 and the laboratory analytical report is included
in Appendix B.
4.0 RESULTS OF INVESTIGATION
4.1 Exploratory Trench Excavation Results
Results of the exploratory trench excavations found various types of household solid waste, trash, and debris
within the pit located in the center of the site; and household solid waste and construction debris in three
trenches excavated across the northern area of the site. Solid waste was encountered to a depth of
approximately eight feet bls in the pit; and from four to five feet bls in the northern area. The overall depth
of solid waste was not determined. A summary of the excavation observations, trench locations, excavation
depths, and GPS coordinates for the (15) fifteen exploratory trenches are provided in Table 1. Pictures of
the excavation trenches and their contents are included in the Appendix A.
Based on the results of the excavations, it appears that the pit was used for the disposal of various types of
household garbage, trash and debris. No evidence of the presence of hazardous waste or hazardous
materials was observed. The solid waste encountered in the center of the site was contained within the
boundaries of the pit and immediate area (EX -4, EX -5, EX -7, EX -8 and EX -1 1). The three exploratory
trenches located south of the pit (EX -1, EX -2 and EX -3) did not contain solid waste. Solid waste was not
observed in exploratory trenches located to the east and north of the pit (EX -6, EX -9 and EX -10).
Based on the historical aerial photographs reviewed and the presence of solid waste in three exploratory
trenches excavated in the northern section of the site (EX -13, EX -14 and EX -15) it appears that northern
portion of the site was used as a dump and primary disposal area. The solid waste encountered consisted
of household garbage to include plastic, bottles, and trash, as well as wood, metal and concrete debris.
Excavation trench EX -14, located in a depression in the vicinity of northwest corner of the site, appeared
to be the most impacted area. Solid waste was encountered from the surface to the termination of the
excavation four to five feet bls. The groundwater and soil in this area was stained black, and an odor
indicative of decaying material detected.
Mr. Shane Corbin
August 2, 2021
Page 4
4.2 Groundwater Laboratory Analyses
The results of the groundwater analyses for TMW-1 showed no analytes above either their laboratory
Method Detection Limit (MDLs) or respective Groundwater Cleanup Target Level (GCTLs) for EPA
Method 8260 Priority Pollutant Volatile Organics Aromatics and Halocarbons, EPA Method 8270 Priority
Pollutant Semi -Volatiles, EPA Method 8081 Organochlorine and Organophosphorus Pesticides, and EPA
Method 8082 PCB. Four of the eight RCRA metals (Barium 0.12 mg/1, Chromium 0.010 mg/1, Lead 0.0059
mg/1 and Mercury 0.00012 mg/1) exceeded their laboratory MDL but were below their respective GCTL.
The laboratory analytical report and the associated chain of custody are included in Appendix B.
5.0 LIMITATIONS
TBG has prepared this Limited Phase II ESA for The City of Atlantic Beach, hereafter referred to as the
Client. No Phase II ESA can eliminate all uncertainty. Furthermore, any sample, either surface or
subsurface, taken for chemical analysis may or may not be representative of a larger population. Chemical
testing methods have inherent uncertainties and limitations. Professional judgment and interpretation are
inherent in the process, and uncertainty is inevitable. Additional assessment may be able to reduce the
uncertainty. Even when soil and groundwater sampling is executed with an appropriate site-specific
standard of care, certain conditions present especially difficult detection problems. Such conditions may
include, but are not limited to, complex geological settings, the fate and transport characteristics of certain
hazardous substances and petroleum products, the distribution of existing contamination, physical
limitations imposed by site conditions, location of utilities and other man-made objects, and the limitations
of assessment technologies.
Measurements and sampling data only represent the site conditions at the time of the data collection. While
TBG has used reasonable care to avoid reliance upon data and information that is inaccurate, TBG is not
able to verify the accuracy or completeness of all data and information available during the investigation.
Some of the conclusions in this report would be different if the information upon which they are based is
determined to be false, inaccurate or incomplete.
TBG makes no legal representations whatsoever concerning any matter including, but not limited to,
ownership of any property or the interpretation of any law. TBG further disclaims any obligations to update
the report for events taking place after the time during which the assessment was conducted.
This report is not a comprehensive site characterization and should not be construed as such. The opinions
presented in this report are based upon the findings derived from limited soil excavation and groundwater
sampling. The scope of work performed herein was limited to groundwater sample collection and
laboratory analysis of one sample. TBG has endeavored to meet what it believes is the applicable standard
of care, and, in doing so, is obliged to advise the Clients of the limitations. TBG believes that providing
information about limitations is essential to help the Clients identify and thereby manage their risks.
Through additional testing, these risks can be mitigated - but they cannot be eliminated. TBG will, upon
request, advise the Clients of the additional research opportunities available, their impact, and their cost.
As noted above, the limited Phase II ESA conducted at the referenced site, and this report, was prepared
for the use solely by the Clients. This report shall not be relied upon by or transferred to any other party
without the express written authorization of TBG.
Mr. Shane Corbin
August 2, 2021
Page 5
6.0 CONCLUSIONS AND RECOMMENDATIONS
The results of limited groundwater analyses showed no tested analytes above their respective GCTLs in the
sample collected from TMW-1.
Review of historical aerial photographs, performed as part of the Phase I ESA, indicated that the subject
site had been cleared and surficial soils disturbed in the 1960 to 1970 photos. In the 1970 photo, the surface
of the northern section of the site appeared to be graded and heavily disturbed. Based on the type, quantity
and depth of solid waste encountered in the exploratory trenches, it appears that this section of the site was
utilized as solid waste dump site. It also appears that the pit located in the central portion of the site was
used for the disposal of solid waste.
Exploratory trenching was not performed in the southern area of the subject site. Also, groundwater
sampling was not performed in the northern portion of the subject site, which appeared to be the most
heavily impacted area based on the results of exploratory trenching. TBG was not tasked with detennining
the type, total volume, depth, and boundaries of the solid waste disposal areas throughout the subject site
as part of this limited Phase II ESA. Further assessment may be warranted if additional data is needed to
further delineate the exact location, depth and volume of solid waste and to evaluate groundwater quality
in the disposal area located in the northern section of the site. If the site is to be developed or disposal areas
disturbed TBG recommends that that the procedures outlined in FDEP Guidance for Disturbance and Use
of Old Closed Landfills or Waste Disposal Areas in Florida dated April 2, 2019, be followed.
TBG appreciates the opportunity to provide you with our services. if you have any questions, please do
not hesitate to contact the undersigned or K. Dawn Blackledge, P.G. at (800) 241-6831.
Sincerely,
THE BLACKLEDGE GROUP, INC.
Philip E. Elson
Sr. Program Manager
FIGURES
ATLANTIC BEACH, DUVAL COUNTY, FLORIDA
REFERENCE: OPEN MAPS ATLANTIC BEACH, FLORIDA
BLACKLEDGEL.
GROUP
UI
WC5t A(dia S[
FIGURE 1. STREET SITE LOCATION MAP
LIMITED PHASE II ENVIRONMENTAL
SITE ASSESSMENT
0 LILY STREET 2.1 ACRES UNIMPROVED
PROPERTY
ATLANTIC BEACH, DUVAL COUNTY, FL
SITE LOCATION
JOB: 21-015-03
DATE: JULY 13, 2021
MAP NAME: Jacksonville Beach
SCALE:
1 : 24000
SUBJECT QUAD:
MAP YEAR: 2021
Part
1
REVISION YEAR: N/R
trying
C►irid
Isrcnd
REFERENCE: US GEOLOGICAL SURVEY
FIGURE 2. TOPOGRAPHIC SITE LOCATION MAP
BLACKLEDGE
cAoue
LIMITED PHASE II ENVIRONMENTAL
SITE ASSESSMENT
0 LILY STREET 2.1 ACRES UNIMPROVED
PROPERTY
ATLANTIC BEACH, DUVAL COUNTY , FL
JOB: 21-015-03
JULY 13, 2021
ATLANTIC BEACH, DUVAL COUNTY, FLORIDA
RE# 179074-0000
REFERENCE: DUVAL COUNTY PROERTY MAP DCPAO MAPS.COJ.NET
FIGURE 3. EXPLORATORY TRENCH LOCATIONS
5BLACKLEDGE
GROUP
LIMITED PHASE II ENVIRONMENTAL
SITE ASSESSMENT
0 LILY STREET 2.1 ACRES UNIMPROVED
PROPERTY
ATLANTIC BEACH, DUVAL COUNTY, FL
0 LILY STREET
JOB: 21-015-03
JULY 13, 2021
•
0
LEGEND
APPROXIMATE SITE BOUNDARY
PROPERTY BOUNDARY
TEMPORARY MONITORING WELL
APPROXIMATE LOCATION OF
BURIED TRASH AND DEBRIS
APPROXIMATE LOCATION OF
EXCAVATION TRENCH
RED=TRASH ENCOUNTERED
BLACK=NO TRASH ENCOUNTERED
ISLAND
i
,/ SALT MARSH
DEPRESSION
13.
12
WOODED
SOIL MOUND
WATER
SALT MARSH
PIT
•TMW-1
ABANDONED
SEPTIC
TANK VAULT
ABANDONED
HOUSE
FOUNDATION
UPLAND
SCRUB
0
WOODED
15
/IA
SINGLE
FAMILY
HOME
>-
WATER
WATER
-I-
SINGLE -
FAMILY
HOME
WEST PLAZA
SINGLE
FAMILY
HOME
-r
FIGURE 4: SITE PLAN AND LOCATION OF BURIED TRASH
:BLACKLEDGE
GROUP
PHASE II ENV SITE ASSESSMENT
0 LILY STREET -2.1 ACRES UNIMPROVED PROPERTY
ATLANTIC BEACH, DUVAL COUNTY, FLORIDA
RE#0170977 0000
JOB: 21-015-03
DATE: JULY 2021
REVIEWED: P. ELSON
TABLES
Trench
Number
EX -1
EX -2
EX -3
EX -4
EX -5
EX -6
EX -7
EX -8
EX -9
EX -10
EX- I 1
TABLE 1
EXPLORATORY TRENCH EXCAVATION OBSERVATIONS
0 LILY STREET
ATLANTIC BEACH, DUVAL COUNTY BEACH, FLORIDA
Description
sandy silt soil
sandy silt soil
primarily sandy silt, with dark staining,
small ainount of trash encountered on the
north end of the excavation
southern end of pit, primarily solid waste
to the termination of the excavation, 15
buckets excavated
eastern side of pit, first two buckets silty
soil, then solid waste to 6 feet bls, 15
buckets excavated
sandy soil, 12 buckets excavated
Solid Waste Present
NO
NO
brick and plastic
household trash, plastic,
wood, piping, misc.
debris
household trash, plastic,
bottles, bike tire, no
demolition debris
NO
northern end of pit, solid waste
encountered to termination of excavation, household trash, bottles,
10 buckets excavated etc.
Primarily sandy soils, with scattered solid
waste to depth
silty sandy soil
sandy soil
metal debris, washing
machine parts, trash,
concrete
Latitude
N 30°19.974'
N 30°19.975'
N 30°19.979'
Longitude
W -81°25.653'
W -81°25.658'
General Location
southeast of pit
due south of the pit
W 81 °25.660'
just south of the southwest
corner of pit
N 30°19.982' W -81°25.660' southern end of pit
N 30°19.987' W -81°25.655' middle of the eastern edge
of pit
N 30°19.992' W -81°25.648' just east of the middle of the
eastern edge of pit
N 30°19.993' W -81°25.654' northern end of pit
N 30°19.994' W -81°25.656'
NO N 30°19.999' W -81°25.648'
NO N 30°19.994' W -81°25.649'
W -81°25.650'
wet sandy soil, small amount of solid waste
encountered metal debris and piping N 30°19.994'
EX - Exploratory Trench
TMW - Temporary Monitoring Well
BLS - Below Land Surface
Sampling Date July 13, 2021
10 feet north of the north
edge of pit
north of the northeastern
corner of pit
northeast of pit, southeast of
EX -9 and northeast of EX -
11
northeast of the northeast
corner of pit
Depth BLS
4 feet
4 feet
3 feet
8 feet
6 feet
4 feet
4 feet
4 feet
4 feet
4 feet
4 feet
Page 1 of 2
Trench
Number
EX -12
TABLE 1
EXPLORATORY TRENCH EXCAVATION OBSERVATIONS
0 LILY STREET
ATLANTIC BEACH, DUVAL COUNTY BEACH, FLORIDA
Description
sandy soil
fill encountered first foot, followed by
EX -13 solid waste until refusal, soil and water
heavily stained black with strong odor
primarily solid waste encountered to the
EX -14 termination of the excavation, black
groundwater and strong odor encountered
EX -15
TMW-1
sandy soil with intermittent solid waste,
groundwater tannic in color, no odor
temporary monitoring wellpoint
EX - Exploratory Trench
TMW - Temporary Monitoring Well
BLS - Below Land Surface
Solid Waste Present
NO
plastic, bottles, metal,
wood, concrete,
household garbage and
trash
plastic, trash
NO
Latitude Longitude General Location
N 30°20.004'
N 30°20.015'
N 30°20.023'
N 30°20.011'
N 30°19.988'
Sampling Date July 13, 2021
W -81°25.647'
W -81°25.655'
W -81°25.653'
W -81°25.651'
W -81°25.652'
northern portion of the site,
just west of Lily St.
northern portion of site,
north of EX -12 in the
central area of site
northeastern comer of the
depression located in the
site's northwest corner
east southeast of EX -13
adjacent to the eastern site
boundary along Lily St.
due east of middle of the
eastern edge of the pit, in
the center of the site
Depth BLS
3 - 4 feet
6 feet
4 - 5 feet
4 feet
6 feet
Page 2 of 2
APPENDIX A
PHOTOGRAPHIC DOCUMENTAION
EX -1 - Located southeast of the central pit, sandy silt with a top layer of organic material, no solid waste.
EX -2 - Located due south of the central pit, sandy silt, no solid waste.
EX-3 - Located just south of the southwest cornerof the central pit, primarily sandy silt with dark
staining. Small amount of trash encountered on the north end of the trench closest to the pit.
EX -4 SmaIl amount of trash from the northern end of the excavation closestto the pit. Plastic and one
brick observed.
EX -4 - Looking north-northwest towards the southern end of the central pit. Exploratory excavation
conducted in the southern end of the pit.
EX -4 - Trash and debris located to the bottom of the excavation 8 feet bls.
EX -4 - Solid waste from the southern end of the pit, solid waste was still present at the termination of
the excavation, 8 feet bls.
EX -5 - Looking northwest towards the middle of the eastern edge of the pit at the location of EX -5.
EX -5 - Solid waste from eastern side of the pit. Bottles, household trash, plastic, bike tire. Demolition
debris was not encountered.
EX-5 - Solid waste from eastern side of the pit.
EX -6 - Excavation located just east of the middle of the eastern edge of the pit. Sandy soils, no solid
waste encountered.
EX -7 - Northern end of the pit, household trash and debris encountered to the termination of the
excavation 4 feet bis.
EX-8 - Located north of the northern edge of the pit, 10 feet north of EX-7. Primarily sandy soil with
intermittent household garbage and debris to the termination of the excavation.
EX -8 - Primarily sandy soil with intermittent household garbage.
EX-9 - Located north of the northeast corner of the pit. Silty sand to 4 feet bis, no solid waste
encountered.
EX-9 - Soil from the excavation.
EX -10 - Located northeast of the pit, and just southeast of EX -9. Sandy soil, no solid waste encountered.
EX -10 SoiI from the excavation.
EX-11 - Located 25 feet north of the northeast corner of the pit. Sandy soil, metal debris was
encountered.
EX-11 - Sandy soil with some metal debris and piping.
EX -12 - Located in the northern portion of the site just west of Lily Street.
EX-12 - Sandy soil from the excavation.
EX -13 - Located north of EX -12 in the central section of the site, half -way between the center of the site
to the west and Lily Street to the east. First foot was soil, followed by solid waste until refusal was
encountered at 6 feet bls. Black colored water and sulfur like odor.
EX -13 Looking northwest towards the trench and solid waste from the excavation.
EX -13 - Looking southwest towards the excavation and solid waste removed from the trench.
EX-14 - Looking west towards the backfilled excavation in a surface depression located in the northwest
corner of the site.
EX -14 - Looking towards the excavation trench and the solid waste encountered. Solid waste was still
present at the termination of the excavation 5 feet bls.
EX -15 - Located east southeast of EX -13 adjacent to the eastern edge of the site along Lily Street. Sandy
soil with intermittent solid waste.
APPENDIX B
LABORATORY ANALYTICAL REPORT
July 23, 2021
Dawn Blackledge
The Blackledge Group
1450 Flagler Ave
Unit 32
Jacksonville, FL 32207
dvanced
nvironmental Laboratories, Inc.
RE: Workorder: J2109343 Lily Street
Dear Dawn Blackledge:
Advanced Environmental Laboratories, Inc
6681 Southpoint Pkwy Jacksonville, FL 32216
Payments: P.O. Box 551580 Jacksonville, FL 32255-1580
Phone: (904)363-9350
Fax: (904)363-9354
Enclosed are the analytical results for sample(s) received by the laboratory on Wednesday, July 14, 2021. Results reported herein
conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. The analytical results
for the samples contained in this report were submitted for analysis as outlined by the Chain of Custody and results pertain only to these
samples.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Paul Gunsaulies - Project Manager
PGunsauliesdAELLab.com
Enclosures
Report ID: 1069634 -1179367
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Advanced Environmental Laboratories, Inc.
NELAP Accredited E82574
Page 1 of 15
3004.1.0.0
clvance
nvironm n al Laboratories, Inc.
SAMPLE SUMMARY
Advanced Environmental Laboratories, Inc
6681 Southpoint Pkwy Jacksonville, FL 32216
Payments: P.O. Box 551580 Jacksonville, FL 32255-1580
Phone: (904)363-9350
Fax: (904)363-9354
Workorder: J2109343 Lily Street
Lab ID Sample ID Matrix Date Collected Date Received
J2109343001 GW -1 Water 7/13/2021 13:40 7/14/2021 10:23
Report ID: 1069634 - 1179367 Page 2 of 15
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Advanced Environmental Laboratories, Inc.
NELAP Accredited E82574
3004.1.0.0
dvanced
nvironmental Laboratories, Inc.
Workorder: J2109343 Lily Street
Lab ID: J2109343001
Advanced Environmental Laboratories, Inc
6681 Southpoint Pkwy Jacksonville, FL 32216
Payments: P.O. Box 551580 Jacksonville, FL 32255-1580
Phone: (904)363-9350
Fax: (904)363-9354
ANALYTICAL RESULTS
Date Received: 07/14/21 10:23 Matrix: Water
Sample ID: GW -1 Date Collected: 07/13/21 13:40
Sample Description: Location:
Adjusted Adjusted
Parameters Results Qual Units DF PQL MDL Analyzed Lab
METALS
Analysis Desc: SW846 6010B Preparation Method: SW -846 3010A
Analysis,Water
Analytical Method: SW -846 6010
Arsenic 0.0080 U mg/L 1 0.032 0.0080 7/20/2021 14:50 J
Barium 0.12 mg/L 1 0.012 0.0030 7/20/2021 14:50 J
Cadmium 0.00050 U mg/L 1 0.0020 0.00050 7/20/2021 14:50 J
Chromium 0.010 I mg/L 1 0.020 0.0050 7/20/2021 14:50 J
Lead 0.0059 I mg/L 1 0.012 0.0030 7/20/2021 14:50 J
Selenium 0.040 U mg/L 1 0.16 0.040 7/20/2021 14:50 J
Silver 0.0080 U mg/L 1 0.032 0.0080 7/20/2021 14:50 J
Analysis Desc: SW846 7470A
Analysis,Water
Mercury
SEMIVOLATILES
Analysis Desc: 8081 B Pesticide
Analysis, Water
Preparation Method: SW -846 7470A
Analytical Method: SW -846 7470A
0.00012 mg/L 1
Preparation Method: SW -846 3510C
Analytical Method: EPA 8081
4,4' -DDD 0.0016 U ug/L 1 0.020 0.0016 7/21/2021 13:59 J
4,4' -DDE 0.0037 U ug/L 1 0.020 0.0037 7/21/2021 13:59 J
4,4' -DDT 0.0021 U ug/L 1 0.020 0.0021 7/21/2021 13:59 J
Aldrin 0.0019 U ug/L 1 0.020 0.0019 7/21/2021 13:59 J
Chlordane (technical) 0.053 U ug/L 1 0.20 0.053 7/21/2021 13:59 J
Dieldrin 0.0011 U ug/L 1 0.020 0.0011 7/21/2021 13:59 J
Endosulfan I 0.0031 U ug/L 1 0.020 0.0031 7/21/2021 13:59 J
Endosulfan II 0.0026 U ug/L 1 0.020 0.0026 7/21/2021 13:59 J
Endosulfan Sulfate 0.0032 U ug/L 1 0.020 0.0032 7/21/2021 13:59 J
Endrin 0.0017 U ug/L 1 0.020 0.0017 7/21/2021 13:59 J
Endrin Aldehyde 0.0025 U ug/L 1 0.020 0.0025 7/21/2021 13:59 J
Heptachlor 0.0035 U ug/L 1 0.020 0.0035 7/21/2021 13:59 J
Heptachlor Epoxide 0.0017 U ug/L 1 0.020 0.0017 7/21/2021 13:59 J
Methoxychlor 0.0058 U ug/L 1 0.020 0.0058 7/21/2021 13:59 J
Toxaphene 0.12 U ug/L 1 0.20 0.12 7/21/2021 13:59 J
alpha -BHC 0.0030 U ug/L 1 0.020 0.0030 7/21/2021 13:59 J
beta -BHC 0.0019 U ug/L 1 0.020 0.0019 7/21/2021 13:59 J
delta -BHC 0.00086 U ug/L 1 0.020 0.00086 7/21/2021 13:59 J
gamma -BHC (Lindane) 0.0018 U ug/L 1 0.020 0.0018 7/21/2021 13:59 J
Tetrachloro-m-xylene (S) 21 J4 % 1 44-124 7/21/2021 13:59
0.00010 0.000011 7/21/2021 11:20 J
Report ID: 1069634 - 1179367 Page 3 of 15
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ANALYTICAL RESULTS
Date Received: 07/14/21 10:23 Matrix: Water
Sample ID: GW -1 Date Collected: 07/13/21 13:40
Sample Description: Location:
Adjusted Adjusted
Parameters Results Qual Units DF PQL MDL Analyzed Lab
Decachlorobiphenyl (S) 26 J4 % 1 48-137 7/21/2021 13:59
Analysis Desc: 8082A PCB Analysis, Preparation Method: SW -846 3510C
Water
Analytical Method: SW -846 8082A
Aroclor 1016 (PCB -1016) 0.12 U ug/L 1 0.50 0.12 7/21/2021 13:59 J
Aroclor 1221 (PCB -1221) 0.12 U ug/L 1 0.50 0.12 7/21/2021 13:59 J
Aroclor 1232 (PCB -1232) 0.12 U ug/L 1 0.50 0.12 7/21/2021 13:59 J
Aroclor 1242 (PCB -1242) 0.12 U ug/L 1 0.50 0.12 7/21/2021 13:59 J
Aroclor 1248 (PCB -1248) 0.12 U ug/L 1 0.50 0.12 7/21/2021 13:59 J
Aroclor 1254 (PCB -1254) 0.12 U ug/L 1 0.50 0.12 7/21/2021 13:59 J
Aroclor 1260 (PCB -1260) 0.12 U ug/L 1 0.50 0.12 7/21/2021 13:59 J
Tetrachloro-m-xylene (S) 21 J4 % 1 61-119 7/21/2021 13:59
Decachlorobiphenyl (S) 26 J4 % 1 44-136 7/21/2021 13:59
Analysis Desc: 8270C Analysis, Water Preparation Method: SW -846 3510C
Analytical Method: SW -846 8270C
1,2,4-Trichlorobenzene 6.9 U ug/L 10 50 6.9 7/20/2021 02:15 J
1,2 -Dichlorobenzene 14 U ug/L 10 50 14 7/20/2021 02:15 J
1,2-Diphenylhydrazine 9.6 U ug/L 10 50 9.6 7/20/2021 02:15 J
1,3 -Dichlorobenzene 10 U ug/L 10 50 10 7/20/2021 02:15 J
1,4 -Dichlorobenzene 20 U ug/L 10 50 20 7/20/2021 02:15 J
1 -Methylnaphthalene 0.50 U ug/L 10 2.0 0.50 7/20/2021 02:15 J
2,4,6 -Trichlorophenol 14 U ug/L 10 50 14 7/20/2021 02:15 J
2,4-Dichlorophenol 9.0 U ug/L 10 50 9.0 7/20/2021 02:15 J
2,4 -Dimethylphenol 26 U ug/L 10 50 26 7/20/2021 02:15 J
2,4-Dinitrophenol 11 U ug/L 10 100 11 7/20/2021 02:15 J
2,4-Dinitrotoluene (2,4-DNT) 18 U ug/L 10 50 18 7/20/2021 02:15 J
2,6-Dinitrotoluene (2,6-DNT) 20 U ug/L 10 50 20 7/20/2021 02:15 J
2-Chloronaphthalene 17 U ug/L 10 50 17 7/20/2021 02:15 J
2 -Chlorophenol 15 U ug/L 10 50 15 7/20/2021 02:15 J
2-Methyl-4,6-dinitrophenol 12 U ug/L 10 50 12 7/20/2021 02:15 J
2 -Methylnaphthalene 0.49 U ug/L 10 2.0 0.49 7/20/2021 02:15 J
2-Nitrophenol 6.3 U ug/L 10 50 6.3 7/20/2021 02:15 J
3,3'-Dichlorobenzidine 13 U ug/L 10 50 13 7/20/2021 02:15 J
4-Bromophenyl Phenyl Ether 11 U ug/L 10 50 11 7/20/2021 02:15 J
4-Chloro-3-methylphenol 6.3 U ug/L 10 50 6.3 7/20/2021 02:15 J
4-Chlorophenyl Phenyl Ether 16 U ug/L 10 50 16 7/20/2021 02:15 J
4-Nitrophenol 29 U ug/L 10 50 29 7/20/2021 02:15 J
Acenaphthene 0.40 U ug/L 10 2.0 0.40 7/20/2021 02:15 J
Acenaphthylene 0.42 U ug/L 10 2.0 0.42 7/20/2021 02:15 J
Report ID: 1069634 - 1179367 Page 4 of 15
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ANALYTICAL RESULTS
Date Received: 07/14/21 10:23 Matrix: Water
Sample ID: GW -1 Date Collected: 07/13/21 13:40
Sample Description: Location:
Adjusted Adjusted
Parameters Results Qual Units DF PQL MDL Analyzed Lab
Anthracene 0.35 U ug/L 10 2.0 0.35 7/20/2021 02:15 J
Benzidine 12 U ug/L 10 50 12 7/20/2021 02:15 J
Benzo[a]anthracene 0.12 U ug/L 10 2.0 0.12 7/20/2021 02:15 J
Benzo[a]pyrene 0.37 U ug/L 10 2.0 0.37 7/20/2021 02:15 J
Benzo[b]fluoranthene 0.12 U ug/L 10 1.0 0.12 7/20/2021 02:15 J
Benzo[g,h,i]perylene 0.48 U ug/L 10 2.0 0.48 7/20/2021 02:15 J
Benzo[k]fluoranthene 0.48 U ug/L 10 2.0 0.48 7/20/2021 02:15 J
Butyl benzyl phthalate 11 U ug/L 10 50 11 7/20/2021 02:15 J
Chrysene 0.33 U ug/L 10 2.0 0.33 7/20/2021 02:15 J
Di -n -Butyl Phthalate 8.8 U ug/L 10 50 8.8 7/20/2021 02:15 J
Di-n-octyl Phthalate 12 U ug/L 10 50 12 7/20/2021 02:15 J
Dibenzo[a,h]anthracene 0.24 U ug/L 10 2.0 0.24 7/20/2021 02:15 J
Diethyl phthalate 21 U ug/L 10 50 21 7/20/2021 02:15 J
Dimethyl phthalate 18 U ug/L 10 100 18 7/20/2021 02:15 J
Fluoranthene 0.37 U ug/L 10 2.0 0.37 7/20/2021 02:15 J
Fluorene 0.38 U ug/L 10 2.0 0.38 7/20/2021 02:15 J
Hexachlorobenzene 9.9 U ug/L 10 50 9.9 7/20/2021 02:15 J
Hexachlorobutadiene 13 U ug/L 10 50 13 7/20/2021 02:15 J
Hexachlorocyclopentadiene 10 U ug/L 10 50 10 7/20/2021 02:15 J
Hexachloroethane 12 U ug/L 10 50 12 7/20/2021 02:15 J
Indeno(1,2,3-cd)pyrene 0.11 U ug/L 10 2.0 0.11 7/20/2021 02:15 J
Isophorone 11 U ug/L 10 50 11 7/20/2021 02:15 J
N-Nitrosodi-n-propylamine 22 U ug/L 10 50 22 7/20/2021 02:15 J
N-Nitrosodimethylamine 9.3 U ug/L 10 50 9.3 7/20/2021 02:15 J
N-Nitrosodiphenylamine 21 U ug/L 10 50 21 7/20/2021 02:15 J
Naphthalene 0.48 U ug/L 10 2.0 0.48 7/20/2021 02:15 J
Nitrobenzene 11 U ug/L 10 50 11 7/20/2021 02:15 J
Pentachlorophenol 9.5 U ug/L 10 50 9.5 7/20/2021 02:15 J
Phenanthrene 0.40 U ug/L 10 2.0 0.40 7/20/2021 02:15 J
Phenol 5.4 U ug/L 10 50 5.4 7/20/2021 02:15 J
Pyrene 0.36 U ug/L 10 2.0 0.36 7/20/2021 02:15 J
bis(2-Chloroethoxy)methane 12 U ug/L 10 50 12 7/20/2021 02:15 J
bis(2-Chloroethyl)Ether 15 U ug/L 10 50 15 7/20/2021 02:15 J
bis(2-Chloroisopropyl) Ether 14 U ug/L 10 50 14 7/20/2021 02:15 J
bis(2-Ethylhexyl) phthalate 20 U ug/L 10 50 20 7/20/2021 02:15 J
2-Fluorophenol (S) 0 1 % 10 31-134 7/20/2021 02:15
Phenol -d6 (S) 0 1 % 10 24-120 7/20/2021 02:15
Nitrobenzene -d5 (S) 0 1 % 10 38-139 7/20/2021 02:15
2-Fluorobiphenyl (S) 0 1 % 10 42-138 7/20/2021 02:15
2,4,6-Tribromophenol (S) 0 1 % 10 48-147 7/20/2021 02:15
Report ID: 1069634 - 1179367 Page 5 of 15
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ANALYTICAL RESULTS
Date Received: 07/14/21 10:23 Matrix: Water
Sample ID: GW -1 Date Collected: 07/13/21 13:40
Sample Description: Location:
Adjusted Adjusted
Parameters Results Qual Units DF PQL MDL Analyzed Lab
p-Terphenyl-d14 (S) 0 1 % 10 61-154 7/20/2021 02:15
VOLATILES
Analysis Desc: 8260B VOCs Analysis,
Water
Preparation Method: SW -846 5030B
Analytical Method: SW -846 8260B
1,1,1 -Trichloroethane 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
1,1,2,2 -Tetrachloroethane 0.20 U ug/L 1 1.0 0.20 7/15/2021 15:15 J
1,1,2 -Trichloroethane 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
1,1-Dichloroethane 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
1,1-Dichloroethylene 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
1,2 -Dichlorobenzene 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
1,2-Dichloroethane 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
1,2-Dichloropropane 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
1,3 -Dichlorobenzene 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
1,4 -Dichlorobenzene 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
2-Chloroethyl Vinyl Ether 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
Acrolein (Propene!) 1.5 U ug/L 1 5.0 1.5 7/15/2021 15:15 J
Acrylonitrile 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
Benzene 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
Bromodichloromethane 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
Bromoform 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
Bromomethane 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
Carbon Tetrachloride 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
Chlorobenzene 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
Chloroethane 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
Chloroform 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
Chloromethane 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
Dibromochloromethane 0.20 U ug/L 1 1.0 0.20 7/15/2021 15:15 J
Dichlorodifluoromethane 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
Ethylbenzene 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
Methylene Chloride 1.2 U ug/L 1 5.0 1.2 7/15/2021 15:15 J
Tetrachloroethylene (PCE) 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
Toluene 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
Trichloroethene 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
Trichlorofluoromethane 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
Vinyl Chloride 0.25 U ug/L 1 1.0 0.25 7/15/2021 15:15 J
Xylene (Total) 0.75 U ug/L 1 3.0 0.75 7/15/2021 15:15 J
cis-1,2-Dichloroethylene 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
cis-1,3-Dichloropropene 0.20 U ug/L 1 1.0 0.20 7/15/2021 15:15 J
Report ID: 1069634 - 1179367 Page 6 of 15
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Phone: (904)363-9350
Fax: (904)363-9354
ANALYTICAL RESULTS
Date Received: 07/14/21 10:23 Matrix: Water
Sample ID: GW -1 Date Collected: 07/13/21 13:40
Sample Description: Location:
Adjusted Adjusted
Parameters Results Qual Units DF PQL MDL Analyzed Lab
trans-1,2-Dichloroethylene 0.50 U ug/L 1 2.0 0.50 7/15/2021 15:15 J
trans-1,3-Dichloropropylene 0.20 U ug/L 1 1.0 0.20 7/15/2021 15:15 J
1,2-Dichloroethane-d4 (S) 105 % 1 70-128 7/15/2021 15:15
Toluene -d8 (S) 99 % 1 77-119 7/15/2021 15:15
Bromofluorobenzene (S) 108 % 1 86-123 7/15/2021 15:15
Report ID: 1069634 - 1179367 Page 7 of 15
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ANALYTICAL RESULTS QUALIFIERS
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PARAMETER QUALIFIERS
U The compound was analyzed for but not detected.
The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit.
J4 Estimated Result
[1] Surrogate diluted out
LAB QUALIFIERS
J DOH Certification #E82574(AEL-JAX)(FL NELAC Certification)
Report ID: 1069634 - 1179367 Page 8 of 15
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QC Batch: MSVj/2021
QC Batch Method: SW -846 5030B
Associated Lab Samples: J2109343001
METHOD BLANK: 3957867
Parameter
QUALITY CONTROL DATA
Advanced Environmental Laboratories, Inc
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Analysis Method: SW -846 8260B
Prepared: 07/15/2021 11:27
Blank Reporting
Units Result Limit Qualifiers
VOLATILES
Dichlorodifluoromethane ug/L 0.50 0.50 U
Chloromethane ug/L 0.25 0.25 U
Vinyl Chloride ug/L 0.25 0.25 U
Bromomethane ug/L 0.50 0.50 U
Chloroethane ug/L 0.50 0.50 U
Trichlorofluoromethane ug/L 0.50 0.50 U
Acrolein (Propenal) ug/L 1.5 1.5 U
1,1-Dichloroethylene ug/L 0.50 0.50 U
Acrylonitrile ug/L 0.50 0.50 U
Methylene Chloride ug/L 1.2 1.2 U
trans-1,2-Dichloroethylene ug/L 0.50 0.50 U
1,1-Dichloroethane ug/L 0.25 0.25 U
cis-1,2-Dichloroethylene ug/L 0.50 0.50 U
Chloroform ug/L 0.50 0.50 U
1,2-Dichloroethane ug/L 0.25 0.25 U
1,1,1 -Trichloroethane ug/L 0.50 0.50 U
Carbon Tetrachloride ug/L 0.25 0.25 U
Benzene ug/L 0.25 0.25 U
1,2-Dichloropropane ug/L 0.25 0.25 U
Trichloroethene ug/L 0.25 0.25 U
Bromodichloromethane ug/L 0.50 0.50 U
2-Chloroethyl Vinyl Ether ug/L 0.50 0.50 U
cis-1,3-Dichloropropene ug/L 0.20 0.20 U
trans-1,3-Dichloropropylene ug/L 0.20 0.20 U
1,1,2 -Trichloroethane ug/L 0.25 0.25 U
Toluene ug/L 0.25 0.25 U
Dibromochloromethane ug/L 0.20 0.20 U
Tetrachloroethylene (PCE) ug/L 0.25 0.25 U
Chlorobenzene ug/L 0.50 0.50 U
Ethylbenzene ug/L 0.25 0.25 U
Bromoform ug/L 0.25 0.25 U
1,1,2,2 -Tetrachloroethane ug/L 0.20 0.20 U
1,3 -Dichlorobenzene ug/L 0.50 0.50 U
1,4 -Dichlorobenzene ug/L 0.50 0.50 U
1,2 -Dichlorobenzene ug/L 0.50 0.50 U
Xylene (Total) ug/L 0.75 0.75 U
1,2-Dichloroethane-d4 (S) % 101 70-128
Toluene -d8 (S) % 96 77-119
Bromofluorobenzene (S) % 106 86-123
Report ID: 1069634 - 1179367 Page 9 of 15
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QC Batch: EXTj/2156
QC Batch Method: SW -846 3510C
Associated Lab Samples: J2109343001
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QUALITY CONTROL DATA
Advanced Environmental Laboratories, Inc
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Payments: P.O. Box 551580 Jacksonville, FL 32255-1580
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Analysis Method: SW -846 8270C
Prepared: 07/16/2021 17:30
Blank Reporting
Units Result Limit Qualifiers
SEMIVOLATILES
Phenol ug/L 0.54 0.54 U
2 -Chlorophenol ug/L 1.5 1.5 U
2-Nitrophenol ug/L 0.63 0.63 U
2,4 -Dimethylphenol ug/L 2.6 2.6 U
2,4-Dichlorophenol ug/L 0.90 0.90 U
4-Chloro-3-methylphenol ug/L 0.63 0.63 U
2,4,6 -Trichlorophenol ug/L 1.4 1.4 U
2,4-Dinitrophenol ug/L 1.1 1.1 U
4-Nitrophenol ug/L 2.9 2.9 U
2-Methyl-4,6-dinitrophenol ug/L 1.2 1.2 U
Pentachlorophenol ug/L 0.95 0.95 U
N-Nitrosodimethylamine ug/L 0.93 0.93 U
bis(2-Chloroethyl)Ether ug/L 1.5 1.5 U
1,3 -Dichlorobenzene ug/L 1.0 1.0 U
1,4 -Dichlorobenzene ug/L 2.0 2.0 U
1,2 -Dichlorobenzene ug/L 1.4 1.4 U
bis(2-Chloroisopropyl) Ether ug/L 1.4 1.4 U
N-Nitrosodi-n-propylamine ug/L 2.2 2.2 U
Hexachloroethane ug/L 1.2 1.2 U
Nitrobenzene ug/L 1.1 1.1 U
Isophorone ug/L 1.1 1.1 U
bis(2-Chloroethoxy)methane ug/L 1.2 1.2 U
1,2,4-Trichlorobenzene ug/L 0.69 0.69 U
Naphthalene ug/L 0.048 0.048 U
Hexachlorobutadiene ug/L 1.3 1.3 U
2 -Methylnaphthalene ug/L 0.049 0.049 U
1 -Methylnaphthalene ug/L 0.050 0.050 U
Hexachlorocyclopentadiene ug/L 1.0 1.0 U
2-Chloronaphthalene ug/L 1.7 1.7 U
Dimethyl phthalate ug/L 1.8 1.8 U
2,6-Dinitrotoluene (2,6-DNT) ug/L 2.0 2.0 U
Acenaphthylene ug/L 0.042 0.042 U
Acenaphthene ug/L 0.040 0.040 U
2,4-Dinitrotoluene (2,4-DNT) ug/L 1.8 1.8 U
Diethyl phthalate ug/L 2.1 2.1 U
Fluorene ug/L 0.038 0.038 U
4-Chlorophenyl Phenyl Ether ug/L 1.6 1.6 U
1,2-Diphenylhydrazine ug/L 0.96 0.96 U
4-Bromophenyl Phenyl Ether ug/L 1.1 1.1 U
Report ID: 1069634 - 1179367 Page 10 of 15
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Parameter Units Result Limit Qualifiers
Hexachlorobenzene ug/L 0.99 0.99 U
Phenanthrene ug/L 0.040 0.040 U
Anthracene ug/L 0.035 0.035 U
Di -n -Butyl Phthalate ug/L 0.88 0.88 U
Fluoranthene ug/L 0.037 0.037 U
Benzidine ug/L 1.2 1.2 U
Pyrene ug/L 0.036 0.036 U
Butyl benzyl phthalate ug/L 1.1 1.1 U
Benzo[a]anthracene ug/L 0.012 0.012 U
3,3'-Dichlorobenzidine ug/L 1.3 1.3 U
Chrysene ug/L 0.033 0.033 U
bis(2-Ethylhexyl) phthalate ug/L 2.0 2.0 U
Di-n-octyl Phthalate ug/L 1.2 1.2 U
Benzo[b]fluoranthene ug/L 0.012 0.012 U
Benzo[k]fluoranthene ug/L 0.048 0.048 U
Benzo[a]pyrene ug/L 0.037 0.037 U
Indeno(1,2,3-cd)pyrene ug/L 0.011 0.011 U
Dibenzo[a,h]anthracene ug/L 0.024 0.024 U
Benzo[g,h,i]perylene ug/L 0.048 0.048 U
N-Nitrosodiphenylamine ug/L 2.1 2.1 U
2-Fluorophenol (S) % 89 31-134
Phenol -d6 (S) % 77 24-120
Nitrobenzene -d5 (S) % 94 38-139
2-Fluorobiphenyl (S) % 90 42-138
2,4,6-Tribromophenol (S) % 89 48-147
p-Terphenyl-d14 (5) % 99 61-154
Advanced Environmental Laboratories, Inc
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QC Batch: EXTj/2161 Analysis Method: EPA 8081
QC Batch Method: SW -846 3510C Prepared: 07/19/2021 14:00
Associated Lab Samples: J2109343001
METHOD BLANK: 3959748
Blank Reporting
Parameter Units Result Limit Qualifiers
SEMIVOLATILES
alpha -BHC ug/L 0.0030 0.0030 U
gamma -BHC (Lindane) ug/L 0.0018 0.0018 U
beta -BHC ug/L 0.0019 0.0019 U
delta -BHC ug/L 0.00086 0.00086 U
Heptachlor ug/L 0.0035 0.0035 U
Aldrin ug/L 0.0019 0.0019 U
Heptachlor Epoxide ug/L 0.0017 0.0017 U
Report ID: 1069634 - 1179367 Page 11 of 15
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QUALITY CONTROL DATA
Workorder: J2109343 Lily Street
METHOD BLANK: 3959748
Blank Reporting
Parameter Units Result Limit Qualifiers
Endosulfan I ug/L 0.0031 0.0031 U
4,4' -DDE ug/L 0.0037 0.0037 U
Dieldrin ug/L 0.0011 0.0011 U
Endrin ug/L 0.0017 0.0017 U
4,4' -DDD ug/L 0.0016 0.0016 U
Endosulfan II ug/L 0.0026 0.0026 U
Endrin Aldehyde ug/L 0.0025 0.0025 U
4,4' -DDT ug/L 0.0021 0.0021 U
Endosulfan Sulfate ug/L 0.0032 0.0032 U
Methoxychlor ug/L 0.0058 0.0058 U
Chlordane (technical) ug/L 0.053 0.053 U
Toxaphene ug/L 0.12 0.12 U
Tetrachloro-m-xylene (S) % 97 44-124
Decachlorobiphenyl (S) % 104 48-137
Advanced Environmental Laboratories, Inc
6681 Southpoint Pkwy Jacksonville, FL 32216
Payments: P.O. Box 551580 Jacksonville, FL 32255-1580
Phone: (904)363-9350
Fax: (904)363-9354
QC Batch: EXTj/2163 Analysis Method: SW -846 8082A
QC Batch Method: SW -846 3510C Prepared: 07/19/2021 07:00
Associated Lab Samples: J2109343001
METHOD BLANK: 3959754
Blank Reporting
Parameter Units Result Limit Qualifiers
SEMIVOLATILES
Aroclor 1016 (PCB -1016) ug/L 0.12 0.12 U
Aroclor 1221 (PCB -1221) ug/L 0.12 0.12 U
Aroclor 1232 (PCB -1232) ug/L 0.12 0.12 U
Aroclor 1242 (PCB -1242) ug/L 0.12 0.12 U
Aroclor 1248 (PCB -1248) ug/L 0.12 0.12 U
Aroclor 1254 (PCB -1254) ug/L 0.12 0.12 U
Aroclor 1260 (PCB -1260) ug/L 0.12 0.12 U
Tetrachloro-m-xylene (S) % 93 61-119
Decachlorobiphenyl (S) % 106 44-136
QC Batch: DGMj/1846 Analysis Method: SW -846 6010
QC Batch Method: SW -846 3010A Prepared: 07/20/2021 04:53
Associated Lab Samples: J2109343001
Report ID: 1069634 - 1179367 Page 12 of 15
CERTIFICATE OF ANALYSIS
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without the written consent of Advanced Environmental Laboratories, Inc.
NELAP Accredited E82574
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dvanced
nvironmental Laboratories, Inc.
QUALITY CONTROL DATA
Workorder: J2109343 Lily Street
METHOD BLANK: 3959837
Blank Reporting
Parameter Units Result Limit Qualifiers
METALS
Silver mg/L 0.0080 0.0080 U
Arsenic mg/L 0.0080 0.0080 U
Barium mg/L 0.0030 0.0030 U
Cadmium mg/L 0.00050 0.00050 U
Chromium mg/L 0.0050 0.0050 U
Lead mg/L 0.0030 0.0030 U
Selenium mg/L 0.040 0.040 U
Advanced Environmental Laboratories, Inc
6681 Southpoint Pkwy Jacksonville, FL 32216
Payments: P.O. Box 551580 Jacksonville, FL 32255-1580
Phone: (904)363-9350
Fax: (904)363-9354
QC Batch: DGMj/1864 Analysis Method: SW -846 7470A
QC Batch Method: SW -846 7470A Prepared: 07/21/2021 11:20
Associated Lab Samples: J2109343001
METHOD BLANK: 3962408
Blank Reporting
Parameter Units Result Limit Qualifiers
METALS
Mercury mg/L 0.000011 0.000011 U
Report ID: 1069634 - 1179367 Page 13 of 15
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Advanced Environmental Laboratories, Inc.
NELAP Accredited E82574
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dvanced
nvironmental Laboratories, Inc.
Workorder: J2109343 Lily Street
Advanced Environmental Laboratories, Inc
6681 Southpoint Pkwy Jacksonville, FL 32216
Payments: P.O. Box 551580 Jacksonville, FL 32255-1580
Phone: (904)363-9350
Fax: (904)363-9354
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Analysis
Lab ID Sample ID Prep Method Prep Batch Analysis Method Batch
J2109343001 GW -1 SW -846 5030B MSVj/2021 SW -846 8260B MSVj/2022
J2109343001 GW -1 SW -846 3510C EXTj/2156 SW -846 8270C MSSj/1407
J2109343001 GW -1 SW -846 3510C EXTj/2161 EPA 8081 GCSj/1841
J2109343001 GW -1 SW -846 3510C EXTj/2163 SW -846 8082A GCSj/1842
J2109343001 GW -1 SW -846 3010A DGMj/1846 SW -846 6010 ICPj/1333
J2109343001 GW -1 SW -846 7470A DGMj/1864 SW -846 7470A CVAj/1199
Report ID: 1069634 - 1179367 Page 14 of 15
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3004.1.0.0
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